基于CUDA的AES并行算法优化

为提升高级加密标准(AES)的加密性能,利用显卡的通用计算能力,在统一计算设备架构(CUDA)平台上实现AES的128位、192位和256位3个版本的GPU并行算法,并提出优化的AES并行算法。在考虑块内线程数量、共享存储器容量和总块数的基础上,根据分块最优值的经验数据指导AES算法在GPU上的最优分块。实验结果表明,与未优化的AES并行算法相比,该算法的3个版本在Nvidia Geforce G210显卡上的加密速度分别提高5.28%,14.55%和12.53%,而在Nvidia Geforce GTX460显卡上的加密速度分别提高12.48%,15.40%和15.84%,且能更好地对SSL数据进行加密。     

Structural significance of the alkyl substituent at the C-4 of (+)-trans-verbenyl acetate in sex pheromonal activity of the American cockroach

The significance of the alkyl group at the C-4 of (+)-trans-verbenyl acetate, which is the sex pheromone mimic of the American cockroach, was investigated. Seven alcohols possessing an ethyl, propyl, or dimethyl group at this position of the 6,6-dimethylbicyclo[3.1.1]heptane skeleton were synthesized and evaluated by behavioral assay. All of the alcohols were inactive, while three of four acetates of the 2-alcohols induced sexual behavior in male cockroaches at the 0.02 or 0.5 mg dosage level, either of which is many orders of magnitude higher than the threshold level of the natural sex pheromones (10^–8 mg). Among the acetates, the compounds with a methyl group or an -oriented ethyl group at C-4 showed the highest activity. The results are discussed in terms of spatial requirements of the molecules for interactions with the receptor.Studies on the sex pheromone mimic of the American cockroach, (+)-trans-verbenyl acetate. Part VIII. For Part VII, seeComp. Biochem. Physiol.,70A: 229–234 (1981).     

基于复合左右手传输线结构的新型微带天线

基于复合左右手传输线结构的零阶谐振理论,提出了一种新型双层结构的微带天线,仿真结果表明该天线具有比单层微带天线更小的尺寸。研究了天线各结构参数对天线特性的影响,并对各参数进行了优化仿真。仿真结果表明该天线具有全向辐射特性,与传统微带天线相比,该天线具有体积小的特点。     

Quantitative preparation of long chain thioethers from an oxo-trans-2-enoic ester and a 9,12-dioxo-trans-10-enoic acid

Branched-chain thioethers have been prepared from methyl 4-oxo-trans-2-hexadecenoate and 9,12-dioxo-trans-10-octadecenoic acid. The reagents involved in these preparations were mercaptoacetic and mercaptopropionic acids. The yields of these thioethers are almost quantitative.     

莫达非尼的绿色化学合成

采用[bm im]BF4离子液体作为反应溶剂,以二苯甲硫醇为原料,经醚化、氨解、氧化得到新型提神醒脑药物莫达非尼。讨论了不同的氯乙酸酯和反应温度对醚化反应收率的影响,讨论了不同的二苯甲硫乙酸酯对氨解反应收率的影响,及离子液体的回收使用。研究表明,采用氯乙酸甲酯作为醚化试剂,反应时间4 h,反应温度100℃,二苯甲硫醇∶氯乙酸甲酯=1∶1.5(摩尔比),室温下氨解反应20 h,二苯甲硫乙酰胺收率76%;采用过氧化氢作为氧化试剂,反应时间3 h,反应温度60℃,过氧化氢∶二苯甲硫乙酰胺=1∶1(摩尔比),莫达非尼收率79%,反应总收率可达48%。     

硫醇自组装膜的电化学研究进展

综述了在金电极上硫醇自组装膜的电化学表征方法，性质和应用，介绍了自组装膜上的电子传递机理，并进行了简要的展望。     

Specificity of the pheromone system ofAdoxophyes orana andClepsis spectrana

The pheromone system of the summer fruit tortrix mothAdoxophyes orana (Fischer von Röslerstamm) consists of a mixture ofcis-9- andcis-11-tetradecen-1-ol acetate (cis-9- andcis-11-TDA, respectively) in a ratio of 9:1. Substitution of one or both of these compounds by related unsaturated acetates reduced the attractancy. Onlycis-11-TDA could be replaced bycis-11-tridecen-1-ol acetate (cis-11-TriDA), although the 9:1 mixture ofcis-9-TDA andcis-11-TriDA was less attractive in the field than the pheromone system itself. The major component of the pheromone system of the leaf rollerClepsis spectrana (Treitschke)(cis-9-TDA:cis-11-TDA=1:9) could also be replaced bycis-11-TriDA, again with some reduction in attractancy.     

Field trapping of threeEpinotia species with (Z,Z)-7,9-dodecadienyl acetate (Lepidoptera: Tortricidae)

Field survey of the geometrical isomers of 7,9-dodecadienyl alcohol, acetate, and aldehyde has resulted in attractants and inhibitors for three species of tortricid moths.Epinotia silvertoniensis and an undescribedEpinotia sp. were all attracted to (Z,Z)-7,9-dodecadienyl acetate. AnotherEpinotia sp. was attracted to (Z,Z)-7,9-dodecadienyl acetate and (Z,Z)-7,9-dodecadien-1-ol. Electroantennogram data and inhibition patterns for one of theEpinotia sp. are also reported. In addition,E. criddleana was attracted to lures containing (E)-9-dodecenyl acetate.     

基于重标极差法和神经网络的隧道变形趋势判断

为准确、科学及全面地对隧道变形进行趋势判断和预测分析,将隧道的变形过程划分为中期阶段和长期阶段,利用R/S分析对其位移序列和速率序列进行趋势判断研究,再利用PSO-BP神经网络对各阶段的变形进行预测,将预测结果与R/S分析结果进行对比,验证两者的一致性。利用两个工程实例进行检验,得出各序列的Hurst指数均大于0.5,说明各序列均具有持续变形的长期性,且位移序列的趋势性均大于速率序列的趋势性;同时,变形预测结果也显示隧道后期变形将持续增加,验证了R/S分析的准确性。     

An economical synthesis of the major sex attractant of the oak leaf roller—cis-10-tetradecenyl acetate

The major sex attractant of the oak leaf roller (Archips semiferanus Walker),cis-10-tetradecenyl acetate (I), was synthesized in 55–62% overall yield by a highly economical route from inexpensive azelaic acid (II).Authorized as Paper No. 4779 in the Journal Series of the Pennsylvania Agricultural Experiment Station.