Pilot-Scale Simulation of Landfill Bioreactor and Controlled Dumping of Fresh and Partially Stabilized Municipal Solid Waste in a Tropical Developing Country

Four pilot-scale lysimeters were used to study the benefits of landfill operation with and without leachate recirculation in tropical weather conditions. Young and old landfills were simulated by filling lysimeters with a segregated fraction of fresh municipal solid waste (MSW) and MSW mined from an open dump site, respectively, and periodically monitoring leachate quantity and quality and biogas quality. For each substrate, one lysimeter was operated as a bioreactor with leachate recirculation and another lysimeter was operated as a controlled dump, for a period of 10 months. Densities between 652 and 825??kg/m3 could be achieved with fresh and mined MSW. Despite such compaction during waste placement, bioreactor technology helps in leachate management, especially in the case of the young landfill lysimeter operated in tropical weather. The benefits of leachate recirculation in the young landfill lysimeter were evident from the significant decrease in chemical oxygen demand (COD) (86%), biochemical oxygen demand (BOD) (82%), dissolved organic carbon (DOC) (85%), and volatile solids (75%) in leachates. However, ammonia nitrogen (amm-N) and chlorides in the leachates accumulated in bioreactor landfills. Operating an old landfill lysimeter as a bioreactor seemed to have no exceptional advantage in the context of leachate management, although leachate recirculation enhanced the methane potential of both fresh and mined MSW.     

Computer simulation of gas generation and transport in landfills. V: Use of artificial neural network and the genetic algorithm for short- and long-term forecasting and planning

In the first four parts of this series a three-dimensional model was developed for transport and reaction of gaseous mixtures in a landfill. An optimization technique was also utilized in order to determine a landfill's spatial distributions of the permeability, porosity, the tortuosity factors, and the total gas generation potential of the wastes, given a limited amount of experimental data. In the present paper we develop an artificial neural network (ANN) in order to make accurate short-term predictions for several important quantities in a large landfill in southern California, including the temperature, and the CH₄, CO₂, and O₂ concentration profiles. The ANN that is developed utilizes a back-propagation algorithm. The results indicate that the ANN can be successfully trained by the experimental data, and provide accurate predictions for the important quantities in the sector of the landfill where the data had been collected. Thus, an ANN may be used by landfills' operators for short-term plannings. Moreover, we showed that a novel combination of the three-dimensional model of gas generation, flow, and transport in landfills developed in Parts I, II, and IV, the optimization technique described in Part III, and the ANN developed in the present paper is a powerful approach for developing an accurate model of a landfill for long-term predictions and planning.     

Interactions between Three Tropical Soils and Municipal Solid Waste Landfill Leachate

Three tropical soils from Ghana, West Africa, were investigated in the laboratory for their potential as liners for waste containment. The key characteristic evaluated was the impact of municipal solid waste landfill leachate on the geotechnical, mineralogical, sorptive and diffusive properties and hydraulic conductivity of the soils. The observed unique characteristics of the soils included their silica: sesquioxide ratios that allowed them to be classified as either lateritic (ratio of 1.33–2.0) or nonlateritic (ratio greater than 2.0). After 5–11 pore volumes of leachate permeation through the soils, the specific surface of each soil decreased due to mineralogical transformations, while the cation exchange capacity of the soils increased. Na+ and K+ present at the exchange sites of the soils increased at the expense of desorbed Ca2+. The effective diffusion coefficient, De, obtained for potassium was 1.3–2.0×10?10?m2/s while that of sodium was 7.3–14×10?10?m2/s. New minerals formed in the soils included hydroxyapatite, pyromorphite, ferrihydrite, hydroxypyromorphite, and strengite. The mineralogical transformations, however, did not adversely alter the hydraulic conductivity of the soils. This finding, along with the observed relatively low De values, suggests that the soils would be effective hydraulic barriers against the migration of potential contaminants in landfill leachate. The study also found that kaolinite and aluminum and iron oxyhydroxides with variable particle surface charge present in the soils allowed sorption of anions, such as, Cl?, that are generally considered conservative (nonreactive) in liner-leachate compatibility studies on soils from temperate regions.     

Comparison of Metals Leaching from CCA- and ACQ-Treated Wood in Simulated Construction and Demolition Debris Landfills

Pressure-treated wood is often disposed of in landfills in the United States, very frequently in construction and demolition (C&D) debris landfills. C&D debris landfills in many states are not equipped with liner systems to protect groundwater. With the voluntary withdrawal of chromated copper arsenate (CCA) treated wood for most residential applications in January 2004, copper-based wood preservatives, including alkaline copper quaternary (ACQ), are more widely used. To evaluate the impact of metal losses from ACQ-treated wood disposed in C&D debris landfills and compare to those of CCA-treated wood under similar conditions, leachates from three simulated C&D debris landfills (lysimeters) were collected and analyzed for over a period of one year. The wood component in one lysimeter (the control lysimeter) contained pallet wood; the second lysimeter contained CCA-treated wood, and the third contained ACQ-treated wood. Each lysimeter was buried in an active landfill for temperature control. Several batch leaching tests [including the standardized toxicity characteristic leaching procedure (TCLP) and the synthetic precipitation leaching procedure (SPLP)] were also conducted for comparison purposes. Although the two lysimeters containing treated wood had elevated copper concentrations within the waste matrix, the concentration in the leachate samples from these lysimeters was below detection for Cu (<4?μg/L) throughout the duration of the experiment, likely a result of precipitation as copper sulfide mineral in the reducing conditions of the simulated C&D landfills. As expected, the lysimeter containing CCA-treated wood showed elevated concentrations of arsenic and chromium, with maximum concentrations of 1.16 mg/L and 0.2 mg/L respectively. Greater amounts of boron (B) leached from ACQ-treated wood than CCA-treated wood or pallet wood debris. The results suggest that copper leaching will not be a major concern upon the disposal of ACQ-treated wood in C&D debris landfills. Arsenic leaching from CCA-treated wood remains a concern for unlined C&D debris landfills.     

Effectiveness of Scrap Tire Chips as Sorptive Drainage Material

Scrap tire disposal is a problem of growing concern. One solution to this problem is innovative methods for the reuse and recycling of scrap tires. Based on batch isotherm tests, scrap tire chips have been identified to be good sorbents of volatile organic compounds (VOCs) and could be used as leachate drainage layer material in solid waste landfills and in other similar applications. To demonstrate the effects of tire chips on the leachate they come in contact with in a drainage layer over a liner, large-scale tank tests simulating the drainage layer and the clay liner and also field tests were performed. Two cells were constructed in a landfill: one with scrap tire chips and the other with gravel leachate collection layer. According to the results of the large-scale tank tests and field tests, shredded tire chips have a significantly positive impact on the quality of the leachate with which they come in contact. The use of scrap tires in landfills would reduce the magnitude of the current tire disposal problem (a 1 ha landfill requires approximately 300,000 tires to fill 0.3 m of a leachate collection layer) and convert one waste into a beneficial construction material and simultaneously mitigate the problem of VOC transport from through landfill liners.     

Leachate from Land Disposed Residential Construction Waste

Solid waste from construction and demolition (C&D) activities is often disposed in unlined landfills. Leachate from unlined landfills poses a potential risk to groundwater quality. An understanding of the types of chemical constituents likely to be encountered in C&D waste landfill leachate and the concentrations at which they occur help assess this risk. An experiment was performed to characterize leachate from land-disposed residential construction waste. Four 54 m2 (580 ft2) test cells were excavated, lined, and filled with waste. Leachate samples were collected and analyzed for a number of water quality parameters over a 6 month period. No volatile or semivolatile organic compounds were detected at elevated constituent levels in the leachate. Inorganic ions were found to account for the bulk of the pollutant mass leached. Calcium and sulfate were the predominant ions in the leachate, resulting from the dissolution of gypsum drywall. The concentrations of several leachate constituents were found to exceed water quality standards. These constituents included aluminum, arsenic, copper, manganese, iron, sulfate, and total dissolved solids. Arsenic was the only primary water quality standard exceeded. The arsenic was concluded to result from chromated copper arsenate (CCA)-treated wood. The potential risk of impacting groundwater was examined by comparing the measured constituent concentrations with the water quality standards to assess the amount of dilution and attenuation needed in the groundwater so that a water quality standard would not be exceeded. The water quality standard exceeded by the greatest magnitude was manganese, followed by iron.     

Landfill Settlement with Decomposition and Gas Generation

A one-dimensional multiphase numerical model is developed to simulate the vertical settlement involving liquid and gas flows in a deformable (settling) municipal solid waste (MSW) landfill. MSW is represented by a chemical composition, and a global stoichiometric reaction is used to estimate the maximum yield of gas generation. Following the general assumption accepted in the literature, the gas generated by waste decomposition is assumed to comprise of methane (CH4) and carbon dioxide (CO2). The gas generation rate follows an exponentially decaying function of time. The gas generation model developed based on a first-order kinetic single-bioreactor approach includes the governing equations of gas migration, liquid flow, and landfill deformation. The Galerkin finite element method is used to solve the resulting equations. The model developed can be used to estimate the transient and ultimate settlements due to waste decomposition and gas generation in MSW landfills. The proposed model can estimate the waste porosity, gas pressure, liquid pressure, gas saturation, liquid saturation, and stress distributions in settling landfills. The results obtained for a deformable landfill are compared with a landfill having a rigid solid skeleton. Due to settlement, the depth of waste is 27% smaller in deformable landfills than that of the rigid ones.     

Fugitive Methane Emissions from Landfills: Field Comparison of Five Methods on a French Landfill

The study presented in this paper has been initiated by the Veolia Environment research center for waste management and supported by the French Environmental Agency. A comparison of five field-scale measurement methods for measuring fugitive methane emissions has been conducted on a French landfill site. The five methods evaluated consisted of a tracer gas technique, laser radial plume mapping, inverse modeling technique, differential absorption light detection and ranging (LiDAR), and helicopter-borne spectroscopy. These methods are evaluated on their abilities to measure emissions from a practical user-oriented aspect (metrological, technical, and economical criteria). High disparities in terms of quantitative results and applicability were observed from all methods. Techniques that used Gaussian dispersion modeling appeared less applicable to landfill sites due to topographic complexity and did not provide high confidence in the results. However, the method using optical remote sensing (radial plume mapping) methods showed that a spatially detailed analysis is achievable (cell level), and the LiDAR method showed very promising approach and technical performances.     

Physical Characterization of Municipal Solid Waste for Geotechnical Purposes

A procedure to characterize municipal solid waste (MSW) for geotechnical engineering purposes is developed based on experience with waste characterization and testing. Existing MSW classification systems are reviewed briefly, and the field and laboratory waste characterization programs of two important projects are presented. Findings on the influence of the waste’s physical composition on its mechanical response from these projects and recent studies of MSW are integrated to develop a waste characterization procedure for efficient collection of the relevant information on landfill operation and waste physical characteristics that are most likely to affect the geotechnical properties of MSW. A phased approach to implementation of this procedure is proposed as a best practice for the physical characterization of MSW for geotechnical purposes. The scope of the phased procedure can be adjusted to optimize the effort required to collect relevant information on a project-specific basis. The procedure includes a systematic evaluation of the moisture and organic content of MSW, because they are important factors in the geotechnical characterization of MSW.     

Estimation of Maximum Liquid Head over Landfill Barriers

To properly design a drainage layer for either landfill leachate collection systems or final covers, the designer must be able to estimate the maximum liquid head over the barrier for any proposed configuration. This paper presents four explicit formulas for estimating the maximum liquid head over an impervious sloping barrier. By means of numeric comparisons, McEnroe’s 1993 method is recommended for design of drainage layers for both bottom liners and final covers. Pipe slope is an important parameter that influences the maximum leachate head on the liner. Different combinations of base grade and pipe slope can directly affect the actual drainage behavior. If the pipe slope is steeper than the base grade, it will make a longer drainage distance and cause a high leachate head on the liner. A method for calculating the maximum liquid head in multilayered drainage media (e.g., geosynthetic and soil) is presented in the paper. The key consideration for this case is to determine the equivalent hydraulic conductivity of the combined drainage media under the phreatic surface under unconfined seepage conditions.