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51.
Nanocrystalline Ni3Al was fabricated through mechanical alloying of elemental powders and spark plasma sintering. The nanocrystalline Ni3Al has a nearly full density after being sintered at 1223 K for 10 min under a pressure of 65 MPa. Isothermal and cyclic oxidations of nanocrystalline Ni3Al were tested at 1173–1373 K with intervals of 100 K. The results indicate that nanocrystalline Ni3Al exhibits excellent isothermal and cyclical oxidation resistance. The oxide scales consist primarily of dense and continuous -Al2O3. The grain refinement is beneficial for improving the oxidation resistance of Ni3Al by providing more nucleation centers for the Al2O3 formation, promoting the selective formation of Al2O3 and improving the adhesion of oxide scales to the matrix. 相似文献
52.
Laser beam weld-metal microstructure in a yttrium modified directionally solidified Ni3Al-base alloy
The microstructure of laser beam weld-metal of an yttrium doped directionally solidified alloy IC 6A, with chemical composition Ni–16Al–8.5Mo–0.12B–0.05C–0.03Y (at.%) was studied. The dendritic microsegregation observed within the fusion zone indicated that dendrite cores were slightly depleted in molybdenum and aluminum and the interdendritic regions were also considerably enriched in yttrium. Severe cracking in the weld-metal was observed and was found to be closely associated with interdendritic eutectic-type microconstituents identified as consisting of γ, γ′ and Ni–Mo phases. An yttrium-rich phase (Ni3Y) was observed in some interdendritic regions containing the eutectic γ, γ′ and Ni–Mo products. Their formation was discussed in relation to plausible microsegregation induced alteration of primary solidification path during cooling from welding temperatures. 相似文献
53.
Li Peng Ji Shengqin Zeng Xiaoyan Hu Qianwu Xiong Weihao 《International Journal of Machine Tools and Manufacture》2007,47(6):996-1002
Direct laser fabrication (DLF) is an advanced manufacturing technology, which can build full density metal parts directly from CAD files without using any modules or tools. The investigation on the fabrication of thin-walled parts of nickel alloy using open-loop DLF process is introduced in this paper. The experimental setup consisted of a CO2 laser, a 3-axis CNC table, a coaxial powder nozzle and a powder recycler. The 3D-CAD file of a thin-walled metal part was converted into the STL file format and imported into software HUST-RP to generate ‘pseudo-random’ scanning paths of laser beam. The influence of process parameters on the build height of thin-walled metal parts was studied by 1–10 layered single-bead stacks of nickel alloy. The result shows that the interference factors which affect the build height of thin-walled metal parts occur randomly during the process. For open-loop DLF process, thin-walled metal parts can achieve much better shape quality if the process parameters are suitable. Multilayer single-bead walls were built up with different scanning velocity to obtain the optimal process parameters of thin-walled parts of nickel alloy. It shows that thin walls of nickel alloy with uniform height can be built up layer by layer in a certain range of specific energy. However, it is difficult to control the build height of complex thin-walled metal parts in an accurate manner just using optimal parameters. A special coaxial powder nozzle was designed in this paper. In a certain range, the deposition thickness of the nozzle is nearly linearly increased with increase in the standoff distance between the powder focusing point of the nozzle and the deposition substrate. By means of the nozzle, a novel method to control the build height of thin-walled metal parts using open-loop DLF process was introduced. The difference in build height of a thin-walled part can be compensated automatically in one or several layers during the process. It is proved that the build height of a thin-walled metal part can be accurately controlled in theory using the nozzle. A complex single-bead part of nickel alloy whose geometry was designed to be the well-known Chinese ‘FU’ was fabricated and explained in this paper. The result shows that the shape quality of the sample is quite good, and actual build height of the sample is 53.54 mm while the designed value is 54 mm. 相似文献
54.
Duyao Zhang Shoujin Sun Dong Qiu Mark A. Gibson Matthew S. Dargusch Milan Brandt Ma Qian Mark Easton 《Advanced Engineering Materials》2018,20(5)
55.
Nam Gyu ChoAuthor Vitae In-Sung HwangAuthor VitaeHo-Gi KimAuthor Vitae Jong-Heun LeeAuthor VitaeIl-Doo KimAuthor Vitae 《Sensors and actuators. B, Chemical》2011,155(1):366-371
This work presents a simple and versatile route to produce macroporous p-type metal oxide thin films. Two-dimensional arrays of p-type NiO films with a hollow hemisphere structure were fabricated by colloidal templating and RF-sputtering followed by a subsequent heat treatment. The diameter and shell thickness of the NiO hemisphere were 800 nm and 20 nm, respectively. X-ray diffraction and high-resolution transmission electron microscopy analysis indicate that the pure NiO phase with grain size of 10 nm was obtained at calcination temperatures that exceeded 450 °C. Close-packed arrays of hollow NiO hemispheres were found to exhibit p-type gas sensing properties against (CO, H2, C3H8, CH4, NO2, and C2H5OH), leading to significantly enhanced responses to C2H5OH (Rgas/Rair = 5.0 at 200 ppm). 相似文献
56.
采用酸沉淀法制备大孔γ-Al2O3为载体,并用浸渍法制备Ni2P(25%)/γ-A12O3催化剂。BET、XRD、压汞法的分析结果显示:合成大孔γ-Al2O3载体晶型良好,且具有适宜比表面积和孔结构。催化剂经原位还原处理后,以柴油为原料在连续固定反应装置上,考察了催化剂的制备条件及反应条件对催化剂加氢脱硫活性的影响。结果表明:当载体合成温度为80℃,反应pH为8,反应条件为温度360℃、压力4.0MPa、空速1.0h-1、氢烃体积比500∶1时,催化剂的加氢脱硫活性最好,柴油的脱硫率可达98.2%。 相似文献
57.
Enrique Barrado Francisco PrietoFrancisco J. Garay Jesús MedinaMarisol Vega 《Electrochimica acta》2002,47(12):1959-1965
The efficiency of the ‘ferrite process’ for the purification of wastewater heavily contaminated with nickel is evaluated, and the solid residues formed are characterised. The efficiency of the purification process is always above 99.9% for Fe2+/Ni2+ ratios greater than 3. The tested Fe2+/Ni2+ molar ratios (15/1, 7/1 and 3/1) yielded three different nickel ferrites. Inductively-coupled plasma atomic emission spectroscopy (ICP-AES), potentiometric titration, X-ray fluorescence (XRF), X-ray diffractometry (XRD) and differential scanning calorimetry (DSC) yielded NixFe1−xIIFe2IIIO4 (x=0.18, 0.40 and 0.65, respectively) as the most probable stoichiometry, and inverse spinel as the most probable structure. Heating at 600 °C causes the transformation of the solids into a mixture of NiFe2O4, α-Fe2O3 and NiO. Electrochemical analysis of the solid nickel ferrites was performed using carbon paste electrodes (CPEs) in HClO4 and HCl media. In each case, the first cyclic voltammogram showed the participation of solid species in the electrochemical transformation process, since the shape of the redox peaks could be related to the structure and stoichiometry of the ferrites. In second and successive scans, the voltammograms indicated the redox couples Feads3++1e−⇔Feads2+ (0.525 V vs. Ag/AgCl) and Niads2++2e−⇔Ni(s) (−0.470 V) in HClO4, and FeCl2,ads++1e−⇔FeClads++Cl− (0.475 V) and NiClx,ads(x−2)−+2e−⇔Ni(s)+xCl− (−0.550 V) in HCl. 相似文献
58.
Particle-free silicon and nickel thin films were successfully fabricated by laser-ablating a melted section of their target surface, which gives a high evaporation pressure at the melting point. The influence of direct evaporation from a melted target was reduced negligibly by melting the target only locally with a focused electron beam (e-beam) and increasing the laser frequency. The silicon films fabricated by the present method, pulse laser deposition of a partially molten target, were able to firmly adhere to the substrates and withstood steel needle scratching, unlike e-beam-evaporated films. 相似文献
59.
Study on the reduction behavior of CoOOH during the storage of nickel/metal-hydride battery 总被引:1,自引:0,他引:1
Xiaofeng Li Tongchi Xia Huichao Dong Yanwei Wei 《Materials Chemistry and Physics》2006,100(2-3):486-489
The storage of nickel/metal-hydride (Ni-MH) battery with co-precipitated cobalt hydroxide and post-added cobalt compound as the additives for pasted Ni(OH)2 electrode is studied in this paper by using galvanostatic charge–discharge, cyclic voltammetry and X-ray diffraction (XRD). It is shown that (I) capacity loss occurs only on the battery with post-added cobalt compound during the storage; (II) CoOOH derived from co-precipitated cobalt hydroxide has a better stability than the one from post-added cobalt compound and an irreversible reduction of the latter is observed; and (III) an inactive Co + 3O(OH) is obtained from Ni(OH)2 electrode with post-added cobalt compound after the storage and should be responsible for the property deterioration of Ni-MH battery. Thus, it is important to increase the stability of CoOOH derived from post-added cobalt compound when Ni-MH battery suffers a long-term storage. 相似文献
60.
M. Unipan D.F.A. Winters A. Robin R. Morgenstern R. Hoekstra 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2005,230(1-4):356-360
The magnetism of Ni(1 1 0) and Fe(1 1 0) surfaces was investigated by electron capture spectroscopy. He+ and He2+ ions impinged on the Fe(1 1 0) and Ni(1 1 0) surfaces under grazing incidence, and the degree of polarization of the light emitted by the neutralized projectiles was analyzed. Our measurements show that in Ni(1 1 0) minority electrons have a higher density of states at the Fermi energy than majority electrons, opposed to the Fe(1 1 0) case. From a comparison of our measurements we estimate the ratio between captured minority and majority electrons in Ni(1 1 0) to be similar as the ratio between captured majority and minority electrons in Fe(1 1 0). 相似文献