溶剂萃取分离锂同位素研究Ⅱ.苏丹Ⅰ-中性配位体协萃体系萃取分离锂同位素效应探讨

文章讨论了苏丹I-中性配位体协萃体系萃取分离锂同位素中螯合剂和协萃剂的结构效应。为了获得高的同位素分离效应,螯合剂必须是弱酸性的(PK_α>11),具有强的分子内氢键及易于形成六元螯合环。协萃剂结构不仅要求无空间位阻,而且具有强的配位基。α随配位基的碱性增大而相应提高。萃取络合物中螯合环的增多亦有利于体系α的提高。此外本文还讨论了一些萃取体系的同位素富集方向和萃锂体系用于分离同位素的前景。     

Two-tier architecture for unconstrained handwritten character recognition

In this paper, we propose an approach that combines the unsupervised and supervised learning techniques for unconstrained handwritten numeral recognition. This approach uses the Kohonen self-organizing neural network for data classification in the first stage and the learning vector quantization (LVQ) model in the second stage to improve classification accuracy. The combined architecture performs better than the Kohonen self-organizing map alone. In the proposed approach, the collection of centroids at different phases of training plays a vital role in the performance of the recognition system. Four experiments have been conducted and experimental results show that the collection of centroids in the middle of the training gives high performance in terms of speed and accuracy. The systems developed also resolve the confusion between handwritten numerals.     

镀液中SiC含量和粒径对Ni-P-SiC复合化学镀层性能的影响

采用化学镀方法制备了Ni P SiC复合镀层 ,系统研究了镀液中SiC含量和粒径对镀层结构及显微硬度的影响。结果表明 ,镀层中SiC析出量随镀液中SiC含量的增加而增加 ,在SiC含量一定的情况下 ,当SiC粒径为 7.0 μm时 ,析出量最大 ;镀液中SiC的含量和粒度对原始镀层的硬度影响不大 ,但对 4 0 0℃热处理后的镀层硬度有显著影响     

检测骨架图形特征点的新方法

端点、折点、歧点和交点是骨架图形的重要特点是，提出用快速查表法检测侯选特征点，再进行侯选特征点聚集，用局部结构分析，去除假特征点，判别真特征点的类型，并对折点给以大致的定量描述。实验结果表明，该方法能快速有效地找出骨架图形的特征点，在目标识别、字符识别等应用中起着关键作用。     

从催化裂化柴油中分离高纯度2,6-二甲基萘

以大庆石油化工总厂炼油厂催化柴油为原料 ,通过精馏分离得到二甲基萘 (DMN)窄馏分 (2 5 8～ 2 70℃ ) ,经糠醛溶剂抽提 ,减压蒸馏后 ,在 -10～ -2 5℃冷冻 2～ 5h ,离心分离制得纯度约 80 %的粗 2 ,6 DMN ,再经无水乙醇在 -10～ -2 5℃重结晶 ,得到纯度大于等于 98%的 2 ,6 DMN。     

丙烷脱沥青装置技术改造

对玉门炼油化工总厂 0 .2 5Mt/a丙烷脱沥青装置的技术改造情况进行了较为详细的介绍 ,对改造前后的操作参数、产品质量和经济技术指标进行了对比。改造后加工能力提高到 0 .30Mt/a ,装置的操作弹性大大提高 ,产品质量优良 ,溶剂单耗由 16 .1kg/t降至 1.6 7kg/t,能耗由 2 4 49.3MJ/t降至 1172 .3MJ/t,年经济效率达 30 0 0× 10 4RMB $。     

Solids Extraction of Cod Frame and Effects on Ultrafiltration of the Aqueous Extract

Grinding, pH adjustment, heat treatment and centrifugation were studied to recover solids from ground cod frames and to apply ultrafiltration (UF) to the resulting aqueous phase. Early heat treatment (90°C/20 min) dissolved collagen into aqueous phase resulting in a very low UF flux. A pH adjustment to 4.5 after grinding (～0.32 cm die), with no heat resulted in efficient separation after centrifuging. UF of the aqueous phase showed an increase in initial flux (23 L/hr m²). However, when the same aqueous material was heated and then centrifuged (1–2% solids removed), UF flux was further increased to 46 L/hr m²and this process gave highest solids recovery (90%).     

Sunflower Head Residue Pectin Extraction as Affected by Physical Conditions

Effects of extraction pH, temperature, and time on yield and quality of pectin from sunflower heads (Interstate cultivar) were investigated. The low-methoxyl pectin was extracted, using 0.75% sodium hexametaphosphate at pH 3, 4, and 5 and at 75, 85, and 95°for 20, 40, and 60 min, respectively. Yield, molecular mass, and firmness of jellies of the pectins were determined. Three-way statistical analysis on yield, molecular mass and gel firmness showed strong interactions among pH, temperature and time. Highest yields were obtained at pH 5, 95°for 20 min and pH 4, 85°for 40 min. Pectin extracted for 40 min at pH 3 and 4 and at 85°and 75°C, respectively, had the highest molecular mass. Gel firmness of sunflower pectin prepared at pH 5.4 was higher than that of a commercial citrus pectin.     

Modeling of a power electronic converter for EMC in the conduction emission frequency band

With the advancement of high‐frequency switching devices, electromagnetic interferences (EMI) have become problems in power electronic converter designs. It is necessary for an electromagnetic compatibility (EMC) design to prospect and consider its possible EMI levels. This paper describes how to compute effects from a power converter to an object point to reduce conduction EMI noises effectively by an appropriate design. Modeling techniques for converter elements are discussed for a model in the conduction emission frequency band by the parameter tuning method and for line constants by an analytical derivation. Then a derived model is simulated for harmonic distributions of loop currents and their magnetic fields. © 2002 Scripta Technica, Electr Eng Jpn, 139(1): 44–50, 2002: DOI 10.1002/eej.1145