Al_2O_3涂层对高温合金K38G热腐蚀的影响

用直流反应溅射方法在镍基高温合金K38G上制备了Al_2O_3涂层,研究了涂覆(Na、K)_2SO_4的试样在1123K空气中的热腐蚀行为。实验表明,Al_2O_3涂层具有良好的粘附性,能降低K38G合金的腐蚀速率并减小腐蚀深度。本文还讨论了Al_2O_3涂层对K38G热腐蚀影响的机制。     

碳对一种单晶镍基高温合金铸态组织的影响

研究了不同碳含量对一种单晶镍基高温合金的铸态组织的影响。结果表明:随着碳含量的增加,合金的初熔温度逐渐降低,合金中的共晶数量和尺寸也减少。随着碳含量的增加,合金中的碳化物数量逐渐增多,碳化物的形态从斑点状变为斑点状和骨架状相结合的网状结构。随着碳含量的增加,一次枝晶间距变化较大,但是二次枝晶间距变化不大,W和Al元素的偏析降低,Ta和Mo元素的偏析增大。     

对一种组合式钎料的试验分析

针对一种以固定牌号使用的俄罗斯组合式钎料ВПР11-40H进行了试验分析，结果表明，该钎料表现出不同于一般钎料的熔化特性，对不锈钢及高温合金薄壁件具有较弱的溶蚀作用，适用于不等间隙、较大间隙钎缝以及薄壁零件的钎焊，对采用该钎料钎焊GH3044和GH3039接头的性能测试结果表明，接头具有满意的室温和高温性能。     

THE CREEP─DAMAGE BEHAVIOUR FOR SINGLE CRYSTAL NICKEL-BASE SUPERALLOY

基于镍基单晶合金蠕变过程中的细、微观组织结构变化及损伤特点，本文建立了考虑材质劣化和空洞损伤的双参数蠕变损伤本构方程及寿命预测模型。利用ＤＤ３单晶材料〈００１〉晶体取向的７６０，８５０和１０００℃实验结果考核表明，所建模型可以比较准确地预测蠕变第二、第三阶段变形状态及破坏特征。第二阶段持续时间、第三阶段开始时间可以表示成蠕变应力的指数函数；随着温度的升高，材料劣化加剧，空洞损伤也增加。     

基于类等势场的粉末高温合金盘件等温锻造预成形设计

以体积成形工艺为例提出了一种新的预成形设计方法。通过静电场模拟选取适当的等势线作为预锻模型腔的基本形状，将选取的预成形形状通过频谱分析进行光顺处理，可以确定出六组预锻模型腔最终轮廓形状。利用有限元软件对粉末高温合金盘件两工步（预锻＋终锻）等温锻造过程进行模拟，进一步分析了相关场变量的分布，优选出预锻模型腔形状。分析表明，基于类等势场法的预成形设计和基于频谱分析的曲线曲面光顺处理方法适合体积成形工艺的预制坯设计。     

Ni-Cr-Al纳米晶合金在1000℃的高温氧化行为

研究了纳米晶Ni-Cr-Al合金的高温氧化行为，发现与 铸态合金不同，随成分不同纳米晶合金在1000℃氧化时，氧化物可分为四个区：A单一Al2O3区；B复杂氧化膜含一连续Al2O3内层区； C复杂氧化膜含内氧化物区；D Al2O3和NiAl2O4共生区.纳米晶化明显扩展了Al2O3生成区的成份范围.     

考虑热不协调性的镍基单晶合金细观力学分析SCIEI

基于镍基单晶合金的细观结构特征，本文建立两个微胞模型对热不协调性作了系统的模型计算和分析．微胞模型１是以一个γ和γ’为考察对象，微胞模型２是以多个γ和γ’为考察对象，详细的分析表明，这两个模型有一定的等效性，但模型２可分析边界条件更宽的情况．基于微胞模型，对两相合金的临界分切应力进行了分析，结果表明，宏观临界分切应力可用考虑热不协调性的有限元法来处理，所得结果还可推广到较大的γ’相体积分数ｆ的情况．考察了热不协调性对回火状态时γ’形状变化的影响，初步的定量分析表明，热内应力是γ’粗化的一个主要驱动力．     

FRACTAL ANALYSES OF DIRECTIONAL SOLIDIFICATION BEHAVIOR OF A Ni-BASE SUPERALLOY

The morphology of solid/liquid interface of a directionally solidification process is describedby means of fractal analysis,and the relations among the fractal dimension of the solid/liq-uid interface,solidification rate,dendrite arm space and the phosphorus content of the test al-loys have been given.It was found that the increase of the solidification rate and the phos-phorus content of the test alloy will lead to a increase,following the regularity of exponentialfunction,in the fractal dimension of solid/liquid interface.Furthermore,by combining thefractal theory and the thermodynamic principle with the measured results,it has been provedthat the fractal dimension is not only a kind of simple geometrical parameter used in des-cribing irregular geometry,but also a state function depending the change of solidificationparameters and chemical compositions.     

Joining alumina to inconel 600 and UMCo-50 superalloys using an Sn10Ag4Ti active filler metal

Alumina ceramics were brazed to Inconel 600 and UMCo-50 superalloys at 900 °C for 10 min using an Sn10Ag4Ti active filler metal. The brazing filler showed good wettability on alumina and superalloys. The flexural strengths were 69 and 57 MPa for alumina/Inconel 600 and alumina/UMCo-50 joints, respectively. In both cases, the brazed specimens fractured along the Sn10Ag4Ti/superalloy interfaces after four-point bending tests. Electron probe microanalysis (EPMA) elemental mapping revealed that the Ni of Inconel 600 and the Co of UMCo-50 dissolved into Sn10Ag4Ti filler metal, which serves to reinforce the weak Sn10Ag4Ti matrix.     

Studies on the hot corrosion of a nickel-base superalloy,Udimet 700

The hot corrosion of a nickel-base superalloy, Udimet 700, has been studied in the temperature range 900–950°C. The effect of the amount of Na ₂SO₄ on the corrosion kinetics was determined. Large weight gains and severe corrosion were associated with two different modes of degradation: (1) formation of large, interconnected sulfides beneath the external scale, and (2) formation of a Na₂MoO₄-MoO₃ melt. The corrosion due to formation of the Na₂MoO₄-MoO₃ melt occurred for all the salt-coating thicknesses, whereas, large sulfides were formed only for the heavier coatings of Na₂SO₄. The formation of Na₂MoO₄-MoO₃ melt required an induction period, and the length of the induction period was observed to be a function of the amount of Na₂SO₄ and of temperature.Work funded under NASA Grant NCC 3-43.