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91.
Hydroprocessing of heavy petroleum feeds: Tutorial 总被引:1,自引:0,他引:1
92.
用粗C9合成深色C9石油树脂 总被引:3,自引:0,他引:3
粗C9馏份在2.0%的三氯化铝催化下于40℃聚合反应3h,得到软化点为146℃,得率为62.6%,色泽为17的深色C9石油树脂。 相似文献
93.
当前,社会发展进入十三五新时代,以人为本充分体现了对社会生产中劳动力的强烈关注,因此安全生产是企业得以发展的最基础保证。石油企业作为国民经济的支柱产业,但又是高危行业,安全形势十分严峻。因此安全管理成为石油企业急需深入探究的问题。文章分析了石油企业目前在安全管理方面存在的问题,提出了在安全管理上采取的一些方法和措施。 相似文献
94.
95.
The advanced courses of Separation Processes use to include some reference to the different types of distillation curves, such as the True Boiling Point (TBP) curves, in order to characterize crude petroleum or its derivatives. The concept of pseudocomponents as well as the way to extract them from a TBP curve can be easily understood by reading classical bibliographic references. Chemical process simulation software packages serve as a useful tool that, once the desired number of pseudocomponents to be considered has been specified, automatically generate them. Nevertheless, the lack of correspondence between cuts of a TBP curve and zones with slight temperature changes makes difficult to identify pseudocomponents and to decide on the adequate number of pseudocomponents to be defined. In this work, a very simple exercise is proposed to introduce the idea of TBP distillation curves in the classroom and to explore their characteristics through the analysis of the influence of the number of extracted pseudocomponents. 相似文献
96.
97.
T.J. Parks 《Carbon》1998,36(12):1729-1737
Samples of petroleum pitch, Ashland 240, were heated isothermally at 380, 400, 430 and 450°C and the hydrocarbon evolution and mesophase growth monitored simultaneously by the use of high temperature 1H-nuclear magnetic resonance (NMR) analysis. For all four temperatures the NMR signal indicated no mesophase formation until the signal intensity had dropped by 30%, which corresponded to 20% weight loss from the pitch. The correlation between the onset and increase in mesophase formation with signal intensity loss was found to be independent of temperature. This temperature independence for the petroleum pitch agrees with the work presented previously by Honda et al. (Carbon 1970, 8, 181). who compared weight loss with the growth of quinoline-insoluble material for a coal-derived pitch. Given the correlation between signal loss and mesophase formation, it is suggested that a relative measure of NMR signal intensity could be used to estimate mesophase content of petroleum pitch, during maturation. 相似文献
98.
A general modelling framework for optimization of multiphase flow networks with discrete decision variables is presented. The framework is expressed with the graph and special attention is given to the convexity properties of the mathematical programming formulation that follows. Nonlinear pressure and temperature relations are modelled using multivariate splines, resulting in a mixed-integer nonlinear programming (MINLP) formulation with spline constraints. A global solution method is devised by combining the framework with a spline-compatible MINLP solver, recently presented in the literature. The solver is able to globally solve the nonconvex optimization problems. The new solution method is benchmarked with several local optimization methods on a set of three realistic subsea production optimization cases provided by the oil company BP. 相似文献
99.
A two‐dimensional mathematical dynamics model is presented to predict coke formation due to thermal cracking inside the tubes of fired heaters on two types of petroleum fluid. The laminar and turbulent flows are analyzed for both petroleum fluids. The second‐order k‐? standard model is adopted to make this mathematical model more accurate than previous models of coke formation. The radial and axial variations for temperature, velocity, and concentration due to the high temperature gradients inside the tubes are considered in the model equations. The finite volume method is the numerical model used to discretize the conservation equations. The proposed model is suitable to predict coke formation inside heater tubes since it indicates operational conditions where coke formation is minimized. 相似文献
100.
Ziyafaddin H. Asadov Ravan A. Rahimov Khuraman A. Mammadova Atash V. Gurbanov Gulnara A. Ahmadova 《Journal of surfactants and detergents》2016,19(1):145-153
Dodecyl isopropylolamine has been synthesized on the basis of dodecylamine and propylene oxide. The structure of dodecyl isopropanolamine has been determined by X‐ray diffraction, elemental analysis, IR‐ and NMR‐spectroscopic methods. Ionic surfactants have been synthesized by interaction of dodecyl isopropylolamine with various acids (HCl, HBr, acetic and propionic) and alkyl halides (methyl iodide, ethyl bromide and n‐propyl bromide). Colloidal‐chemical parameters, petroleum‐collecting and petroleum dispersing capacities of the synthesized cationic surfactants have been studied. 相似文献