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61.
随着矿井深度的增加,对锚杆支护强韧性的要求越来越高,为了应对这一情况,需要研发出更高强度的锚杆钢。利用锚杆钢研究了轧制工艺、冷却工艺与珠光体、铁素体相比例,析出相析出行为及力学性能的关系。研究结果表明,在中轧后、精轧前采用适当水冷+回复段处理的复合工艺可使晶粒更细小、组织更均匀。对超高强度锚杆钢进行热压缩变形试验,由热模拟试验结果确定相转变温度为Ac1=737 ℃、Ac3=886 ℃。最终筛选出入精轧温度为810 ℃、回复段温度为800 ℃时,可获得的晶粒尺寸达4 μm,珠光体体积分数为66.8%,铁素体体积分数为33.2%,珠光体片层间距达200 nm;另外调整V、Cr、N等析出以提高锚杆钢的强韧性,较低的回复温度有利于细小、弥散、V(C/N)析出相的析出,V(C/N)的析出可进一步改善锚杆钢的力学性能。由该控轧控冷工艺轧制的锚杆钢屈服强度为780 MPa、抗拉强度为930 MPa、硬度为291HV、伸长率为20%。 相似文献
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The half-lives (t
1/2) for evaporative loss ofn-alkyl andn-alkenyl acetates from rubber septa were determined at temperatures varying from 15 to 35 °C. The changes int
1/2 with temperature gave high correlations with the equation, Int
1/2 = H/RT+y
o where H is the heat of vaporization,R is the gas constant,T is the absolute temperature, andy
o is a constant. Half-lives changed dramatically with temperature and the degree of change with temperature increased with increasing molecular weight. For mixtures, component ratios changed with temperature, but the degree was modest. At 20 °C there was a 7.5-fold ratio oft
1/2 between members of the homologousn-alkyl orn-alkenyl acetates differing by two carbon atoms. The large change int
1/2 with temperature and with number of carbon atoms is a consequence of the thermodynamic relationships and the temperature range of pheromone usage. Therefore, a similar degree of change inf
1/2 with temperature and number of carbon atoms will apply to other formulations of the same type (those in which the rate of evaporation is first order). The values oft
1/2 at 20 °C mainly agreed very well with those reported previously at room temperature. However, our previously reported values for pentadecyl and hexadecyl acetate were revised. Half-lives were shown to depend on the vapor pressure of a compound in the formulation substrate, but not on the vapor pressure of the pure compound.Mention of a commercial or proprietary product does not constitute an endorsement by the USDA. 相似文献
67.
John F. Quinn Author Vitae Author Vitae Leonie Barner Author Vitae Author Vitae 《Polymer》2007,48(22):6467-6480
Ionizing radiation, such as γ, ultraviolet, microwave and X-ray radiation, has long been used in polymer chemistry as a means of initiating polymerization, crosslinking gels and decomposing particular polymer components. More recently, ionizing radiation has found application in tandem with living radical polymerization to form novel polymeric materials with defined molecular weight and narrow molecular weight distribution. In particular, γ-rays and ultraviolet light both have shown promise as sources of initiation in reversible addition-fragmentation chain transfer (RAFT) polymerization. The ability to apply these sources of initiation at low temperatures is useful in applications where elevated temperature is likely to be detrimental to the system, for instance, in preparing protein-polymer conjugates. Similarly, the use of these initiating sources at low temperature is particularly suitable for some monomers, such as allyl compounds, which have not been synthesized using any other living radical approach. The current review examines the development of ionizing radiation as a tool in RAFT polymerization, with particular reference to the elucidation of the polymerization mechanism, the synthesis of high functionality polymers and probing the kinetic parameters of the RAFT process. 相似文献
68.
Sluijsmans and Kolenbrander developed a simple model to describe the availability of animal manure, assuming a readily available, an easily decomposable and a slowly decomposable N fraction. We tested this model on data from an experiment in which farmyard manure had been applied for eleven successive years to silage maize [Zea mays L.] grown on a light sandy soil. The residual effects of this FYM were then measured by growing Italian ryegrass [Lolium multiflorum Lamk.] in the 12th year. The measured uptake of N by the grass of the FYM residues was then compared with the computed values. The measured amounts of N taken up agreed fairly well with the calculated amounts for applications of 50 and 100 t FYM per ha per year.If the rates of manure application are adjusted to crop requirement, the model shows that the potential, long-term release of N from the residual N fraction of FYM will not exceed 20 kg N per ha. For cattle slurry with a smaller residual fraction, the release will be at most 10% of the total annual N application. 相似文献
69.
The chemical composition and quantitative molar ratios among all components of biodegradable polyphosphoester copolymers of DL ‐lactide and ethylphosphate were determined by a comprehensive set of NMR spectroscopic methods. The polyphosphoester copolymers studied were synthesized using condensation polymerization of oligomeric DL ‐lactide prepolymers and ethyl dichlorophosphate. Conclusive identification of the chemical shift patterns of all functional groups in the copolymers required additional NMR methods such as 31P‐NMR and two‐dimensional 1H–1H COSY NMR, in addition to the synthesis and comparative NMR analysis of model compounds possessing identical phosphoester linkages in the polyphosphoester copolymers. For the polymers synthesized using the bulk polycondensation process, 1H–1H COSY NMR analysis revealed the presence of a small amount of side products that were undetected by 1H‐NMR alone. These side reactions most likely occurred between the pendant ethoxy group of the phosphoesters and the hydrogen chloride gas generated in the bulk polycondensation process. 31P‐NMR spectra of the copolymers revealed a consistent triple‐peak pattern characteristic of phosphoesters linked to a racemic mixture of D,L ‐lactides. These results offered new insight into the side reactions occurring in bulk polymerization of polyphosphoesters and provided a powerful tool of characterizing complex biodegradable polymers. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 4021–4031, 2003 相似文献
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