固铍处理几种工艺方法讨论

近年来,贵溪冶炼厂贫化电炉渣含铜呈逐年上升趋势,究其原因较多,其中在贫化电炉中处理固铍是主要原因之一.文章主要是时贵溪冶炼厂固铍处理生产现状进行介绍,对贵冶固铍处理的几种可能方法进行分析和讨论,并进行相应的技术经济比较.     

Study of Bi_2O_3-based Rare Earth Solid Electrolyte Used in Fuel Cell

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旋转固体火箭发动机统一流场计算

为了进一步研究旋转对固体火箭发动机工作的影响,采用RSM湍流模型对内孔燃烧、内孔与端面同时燃烧管状装药旋转固体火箭发动机统一流场进行了仿真。采用UDF编程给出质量入口边界,获得了旋转条件下发动机内流场结构参数特点,并给予理论说明。计算结果表明,内孔燃烧装药发动机切向速度流场类似于典型的Rankine涡,端面和内孔同时燃烧装药发动机切向速度流场呈现出Rankine涡和由端面燃烧引起的强迫涡的复杂组合涡;在发动机前封头和喷管喉部涡核切向速度峰值非常大,使燃烧室前封头和喷管喉部工作环境显著恶化;旋转使发动机燃烧室压力沿径向逐渐增大,强迫涡附近的压力梯度远大于推进剂表面的压力梯度。     

基于离散单元法的锥形双螺杆输送及混合机理分析

锥形双螺杆挤出机结构模型与其他普通螺杆挤出机相差很大且构成独特,近年来在聚合物加工行业中发挥了很大的作用。设计螺槽深度与螺杆半径比为1∶2、2∶5、1∶3的三种锥形双螺杆挤出机,通过离散单元法模拟了锥形双螺杆挤出机挤出LDPE、HDPE两种颗粒的过程,分析了锥形双螺杆挤出机螺槽内颗粒速度的变化,同时在不同参数下对三种锥形双螺杆挤出机的输送效率进行了比较。利用EDEM软件对LDPE和HDPE颗粒进行离散元分析,得出不同时刻两种颗粒在三种锥形双螺杆挤出机内的混合情况。结果表明,螺槽深度与螺杆半径比为1∶2的锥形双螺杆挤出机的混合效率优于螺槽深度与螺杆半径比为2∶5、1∶3的锥形双螺杆挤出机。     

固体火焰与燃烧合成的基本概念及应用

对固体火焰与燃烧合成的基本概念与应用进行了综合评述，尽可能对固体火焰与气体火焰的特点进行比较，并对燃烧合成与其它传统工艺进行了比较。     

模具装配过程的动态模拟及其应用

运用动画模拟软件Solid Works Animator制作了模具装配过程的动画。对于结构比较复杂的模具，实现模其装配过程的动态模拟可以更好地展示模具的内部结构，有助于客户直观感受模具设计模型，从而进一步完善模具设计，而且可以将此动画过程录制成AVI格式动画文件，从而能够在任何基于Windows的媒体播放器中进行播放，同时还可以将此动画应用于多媒体教学当中。     

Sensing, modeling and control for laser-based additive manufacturing

Laser-Based Additive Manufacturing (LBAM) is a promising manufacturing technology that can be widely applied to part preparation, surface modification, and Solid Freeform Fabrication (SFF). A large number of parameters govern the LBAM process. These parameters are sensitive to the environmental variations, and they also influence each other. This paper introduces the research work in RCAM on improving the performance of the LBAM process. Metal powder delivery real-time sensing and control is studied to achieve a controllable powder delivery for fabrication of functionally graded material. A closed-loop control system based on infrared image sensing is built for control of the heat input and size of the molten pool in the LBAM process. The closed-loop control results show a great improvement in the geometrical accuracy of the built features. A three-dimensional finite element model is also established to explore the thermal behavior of the molten pool in the closed-loop controlled LBAM process.     

聚丙烯固相法接枝改性

聚丙烯固相法接枝不饱和单体是一种简便易行的本体法技术。与其它接枝方法相比，具有成本低、接枝率高、时间短、无溶剂回收、不妨害接枝物的进一步应用等优点。本文介绍了聚丙烯固相法接枝不饱和单体的进展，并较详细地讨论了影响接枝反应的各种因素。     

Degree of crosslinking and mechanical properties of crosslinked poly(vinyl alcohol) beads for use in solid-phase organic synthesis

The limited swellability in polar media of the commonly used polystyrene/divinylbenzene (PS-DVB) support materials for solid-phase organic synthesis has led to the development of novel, highly swellable hydrophilic gels designed for use in aqueous or polar media. Poly(vinyl alcohol) beads crosslinked with epichlorohydrin (PVA-EP) were prepared by a two-step inverse-suspension polymerization method. While it is known that the morphology of the resulting beads can be controlled by the ratio of EP versus PVA as well as by the pre-crosslinking time, the actual degree of crosslinking of the beads and their mechanical properties remain unknown. It is therefore the purpose of this study to evaluate the actual degree of crosslinking of beads prepared with different quantities of crosslinker in the feed by spectroscopic (Raman, nuclear magnetic resonance) and chemical (functional group loading) methods. The mechanical properties of these swollen PVA-EP beads will be evaluated by single-bead unconfined compression in solvents such as water, N,N-dimethylformamide (DMF), and tetrahydrofuran (THF) and compared to model PS-DVB beads commonly used for solid phase synthesis.     

高掺量赤泥-粉煤灰微晶玻璃研究

赤泥是氧化铝生产中排放的碱性废渣,粉煤灰是燃煤电厂排放的高SiO2含量废渣.综合利用两种废渣制备高性能的微晶玻璃材料,控制SiO2含量在31%～44%,CaO含量在25%～31%,两种废渣总吃渣量能够达到90wt%以上,具有显著经济效益和环境效益.