太阳能电池多晶硅铸锭的凝固原理和方法浅谈

首先从定向凝固的原理讲起,其中涉及定向凝固的一些重要的工艺参数以及多晶硅铸锭的组织结构;其次,介绍了多晶硅铸锭的几种凝固方法,尤其着重讲了一下热交换法的应用;并在结尾提到了现在铸锭法中需要改进和解决的主要问题。     

The surface tension of liquid silicon at high temperature

The measurement of the surface tension of liquid silicon has a long history with many results but no general agreement between them. Two values at the melting temperature are cited in reviews (749 and 827 mN/m [N. Eustathopoulos, E. Ricci, B. Drevet, Note Technique DEM No. 97/58, CEA, 1997]) but there are few arguments to determine the correct one. In the present study, new data for the surface tension obtained with the analysis of characteristic frequencies of a levitating drop are presented. The effect of oxygen and nitrogen are also considered. These data are compared with former data obtained with contactless techniques. The most recent surface tension values obtained with drop weights ranging on two orders of magnitude and environments of different natures (argon, hydrogen and vacuum) show excellent agreement (within a 1.5% margin) at temperatures between 1350 K and 2400 K. The comparison of these data to others obtained with different techniques, reveal a good agreement, except those obtained with the sessile drop technique on some supports like BN, SiO₂ and MgO. However, these special cases may be connected with the reactivity of silicon with these supports.     

Effect of silicon content on microstructure and electrochemical behavior of hypoeutectic Al-Si alloys

The correlation of mechanical properties and corrosion behavior with microstructure parameters can be very useful for planning solidification conditions in order to achieve a desired level of final properties. The present study aims to investigate the influence of silicon content on the microstructural pattern, i.e., dendrite spacings and distribution of interdendritic phases on the corrosion behavior of Al-Si alloys castings. The corrosion resistance was analyzed by both the electrochemical impedance spectroscopy (EIS) technique and Tafel's plots carried out in a 0.5 M NaCl test solution at 25 °C. The increase on silicon content has provided a dendritic refinement and a more extensive redistribution of the eutectic mixture which has provoked a decrease on the corrosion resistance.     

Thermal analysis and solidification pathways of Mg–Al–Ca system alloys

Mg–Al–Ca alloys are creep resistant magnesium alloys with high application potentials. The solidification pathways and microstructure formation in this alloy system are still under discussion. In this paper, the solidification behavior of AZ91 and AM50 with Ca addition (AZC91x and AMC50x alloys) was investigated by a computer-aided cooling curve analysis (CA-CCA) system. Microstructure and phase identification were carried out by SEM and EDX analysis. The results show that the Ca-containing phase formation mainly depends on Ca content and Ca/Al ratio. With increasing the Ca/Al ratio these phases transform from Al₂Ca to (Mg, Al)₂Ca and Mg₂Ca. Moreover, Ca addition decreases the liquidus temperature of Mg–Al alloys, but influences the solidus temperature in a more complex way. Increasing the Ca content also decreases the solid fraction at which dendrite coherency occurs. The relationship between solidification interval, dendrite coherency point, formation of Ca-containing phases and hot tearing is also discussed.     

Effects of growth rate and temperature gradient on the microstructure parameters in the directionally solidified succinonitrile–7.5 wt.% carbon tetrabromide alloy

Succinonitrile (SCN)–7.5 wt.% carbon tetrabromide (CTB) alloy was unidirectionally solidified with a constant growth rate (V = 33 μm/s) at five different temperature gradients (G = 4.1–7.6 K/mm) and with a constant temperature gradient (G = 7.6 K/mm) at five different growth rates (V = 7.2–116.7 μm/s). The primary dendrite arm spacings, secondary dendrite arm spacings, dendrite tip radius and mushy zone depths were measured. Theoretical models for the microstructure parameters have been compared with the experimental observations, and a comparison of our results with the current theoretical models and previous experimental results have also been made.     

铁型覆砂球墨铸铁件凝固模拟及收缩缺陷预测

建立了铁型覆砂铸造凝固过程模拟的数学模型.采用动态膨胀收缩法(DECAM)和K*G/R判据预测球墨铸铁件的收缩缺陷,对球墨铸铁四缸曲轴新产品进行了模拟计算,根据模拟结果对原有工艺方案进行了改进,并在实际生产中得到了合格的铸件.结果表明,对铁型覆砂球墨铸铁件进行数值模拟和工艺优化,有助于提高铸件质量,缩短试制周期,降低工装费用.     

Thermal analysis and microstructural evaluation of conventional land developed high speed tool steels

Thermal analyses and microstructural evaluation were carried out for the conventional AISI M2 and M10 high speed steels as well as for alloys with varying Nb and/or Ti contents to assess their liquidus, solidus and other high temperature reactions. It has been found that the slope change of cooling curves marks the formation of MC type carbides, while the break is due to the crystallization of delta ferrite and much larger volume fraction of different type of carbides including M6C mostly by eutectic reactions. Results show that the formation of dendrites is the most basic characteristic of the solidification process for the AISI M2 and M10 alloys but for the steels containing niobium and/or titanium carbides, these primary carbides insert an inoculating effect and modify the coarse dendritic structure.     

An analytical and numerical study of coupled transient natural convection and solidification in a rectangular enclosure

The transient process of the solidification of a pure liquid phase-change material in the presence of natural convection in a rectangular enclosure is considered both analytically and numerically. One vertical boundary is held at a temperature below the melting-point of the material, the other above; the horizontal boundaries are both assumed adiabatic. A nondimensional analysis of the problem, principally in terms of the Rayleigh (Ra) and Stefan (St) numbers, indicates that some asymptotic simplification is possible for materials often considered in the literature (water, gallium, lauric acid). This observation suggests a way to simplify the full problem when Ra  1 and St  1, giving a conventional boundary value problem for the liquid phase and pointwise-in-space first-order ODEs for the evolution in time of the solidification front. The method is tested against full 2D finite-element-based transient numerical simulations of solidification. In addition, simpler approaches for determining the average thickness of the solid layer, based on boundary-layer and enclosure flow correlations, are also investigated.     

Shape rheocasting of unmodified Al-Si binary eutectic

It is demonstrated experimentally that by using the Council for Scientific and Industrial Research Rheo Casting System and high pressure die casting it is possible to semi-solid process and cast into a shape unmodified Al-Si binary eutectic without a solidification temperature range. Silicon leads the aluminium coupled crystal growth subjected to convection by induction during thermal arrest. The semi-solid structure during thermal arrest is captured after rheo-processing and casting.