In Situ Performance Testing of Deteriorating Water Tanks for Durability Assessment

Reports of failure of existing concrete structures due to a lack of durability, rather than a deficiency in structural strength, has made concrete technologists, engineers, and researchers focus research on the parameters influencing durability performance with respect to time. Systematic performance monitoring, with respect to chosen durability parameters of existing concrete structures, will decide the direction of future research in this area. Inferences based on laboratory simulations and testing need to be confirmed by in situ field measurements and studies. In situ condition rating and performance monitoring surveys have been conducted by many researchers, scientists, and professional associations, and reported in literature. Inferences of few such studies are summarized and discussed. Deterioration of concrete structures constructed in recent times is observed at relatively faster rates, and has been mainly attributed to cracking. Cracking is associated with the use of faster-hydrating portland cements with increased fineness and the tricalcium silicate (C3S) content to support the high speed of modern construction. In the present research, a case study of deteriorated water tank structures situated in the semitropical region of India is presented. Some selected parameters—such as concrete cover, carbonation depth, chloride concentration, compressive strength, etc. which influence long term durability of structures—have been measured.     

定向爆破拆除框架式水塔

高 2 7m的水塔建于 193 4年 ,其顶部水罐由 12根钢筋混凝土柱支撑。在倒向侧 7根立柱上形成不同高度的爆破切口 ,背向侧倾倒中心线上的一根立柱上形成小爆破切口 ,其余 4根立柱底部打贯通孔 ,使水塔准确定向倾倒。文中讨论了立柱切口高度的计算 ,爆破参数的确定 ,并介绍了所采用的安全措施。     

Inhibiting and deactivating effects of water on the selective catalytic reduction of nitric oxide with ammonia over MnOx/Al2O3

The effect of water on the selective catalytic reduction (SCR) of nitric oxide with ammonia over alumina supported with 2–15 wt.-% manganese oxide was investigated in the temperature range 385–600 K, with the emphasis on the low side of this temperature window. Studies on the effect of 1–5 vol.-% water vapour on the SCR reaction rate and selectivity were combined with TPD experiments to reveal the influence of water on the adsorption of the single SCR reactants. It turned out that the activity decrease due to water addition can be divided into a reversible inhibition and an irreversible deactivation. Inhibition is caused by molecular adsorption of water. TPD studies showed that water can adsorb competitively with both ammonia and nitric oxide. Additional kinetic experiments revealed that adsorbed ammonia is present in excess on the catalyst surface, even in the presence of water. Reduced nitric oxide adsorption is responsible for the observed reversible decrease in the reaction rate; the fractional reaction order changes from 0.79 in the absence of water to 1.07 in its presence. Deactivation is probably due to the dissociative adsorption of water, resulting in the formation of additional surface hydroxyls. As the amount of surface hydroxyls formed is limited to a saturation level, the deactivating effect on the catalyst is limited too. The additional hydroxyls condense and desorb in the temperature range 525–775 K, resulting in a lower degree of deactivation at higher temperature. A high temperature treatment at 775 K results in a complete regeneration. The amount of surface hydroxyls formed per unit surface area decreases at increasing MnO_x-loading. The selectivity to the production of nitrogen is enhanced significantly by the presence of gas phase water.     

Catalytic oxidation of sulphide ions to elementary sulphur in aqueous solutions over transition metal oxides

The catalytic activity of a wide range of transition metal oxides in oxidation of sulphide ions by air in aqueous medium was studied. Some specific features of the reaction mechanism on some of the studied oxides were considered. The transition metal oxides are promising catalysts for practical application. Some of these oxides will allow the preparation of catalysts possessing activity comparable to that of the cobalt phthalocyanine based catalysts, popular in industrial practice.     

水溶性涂料使用性能研究

本文通过试验对水溶性涂料的耐盐雾腐蚀性能，耐热性能，高低温冲击性能，耐油性能，涂膜与铁基体，面漆的给合力及涂膜表面电阻进行研究，同时指出了该涂料在军用电子产品上的应用前景。     

CDB含水率计产生非一致性响应的原因及改进

郭海敏.CDB 含水率计产生非一致性响应的原因及改进.测井技术,1993;17(2):154～160用微波传输线理论,简化 CDB 含水率计为集总参数电路。导出了这种含水率计的响应方程,给出了油气水混合电导率与持水率的非线性关系式,在此基础上认为这种含水率计的响应曲线呈 S型。导致响应出现非一致性现象的主要因素有:工作频率低,不能有效地消除地层水矿化度的影响;仪器外壁侧孔使信号向外辐射造成损耗;仪器与其它仪器相连,此时含水率计呈非纯容性。我们认为这些因素的影响使得 CDB 含水率计与传统的电容法含水率计在实质上没有明显差别。要消除非一致性现象,应从以上几点进行改进。     

李子溪流域水土流失及泥沙输移规律初步研究

为了探讨长江上游流域水土流失及泥沙输移规律，选取嘉陵江中游的支流李子溪为典型流域进行分析研究，在实地调查，野外测验及应用１９６０年－１９９１年实测降雨、径流、输沙资料的基础上，利用单因子相关分析和多因子回归分析，分别建立了输水利沙量、最大输沙率计算方程。在此基础上，参照径流瞬时单位线原理，以线性时不变系统为基础，建立输沙瞬时单位线模型。通过输沙单位线与时段净侵蚀量的卷积得到流域出口断面的输沙率过程     

企业施工定额的编制以及施工成本分析平台的应用

本文阐述了施工企业内部编制定额的必要性和成本分析平台的实用性,并根据多年的工作经验就建筑施工企业对施工成本的控制谈谈一自己的认识和看法.     

玻璃两面重叠手印拍摄机理

根据斯涅尔定律和菲涅尔公式阐述清水衬底法消除玻璃下界面手印或玻纹的影像，以及用偏振光，紫外线拍摄玻面痕迹的方法和机理。     

Evaporation and Evolution of Suspended Solution Droplets at Atmospheric and Reduced Pressures

Thermal history and solute precipitation behavior of suspended solution droplets of sodium chloride (NaCl), magnesium sulphate (MgSO₄), and zirconium hydroxychloride (ZrO(OH)Cl) evaporating at atmospheric and reduced pressures are studied. Experimental measurements on the variation of droplet diameter, solution concentration, and temperature during the evaporation period are presented and discussed. The results of solute precipitation behavior in solution droplets observed under an optical microscope are displayed and discussed. Results indicate that reducing the pressure (∼ 33 kPa) results in a change in the solution droplet evaporation rate, but the thermal histories of a particular solution droplet are similar at the atmospheric and reduced pressures. At atmospheric and reduced pressures used in this study, the d² law for solution droplets is valid at early stages of the evaporation and before the solute precipitation initiates. Drying of MgSO₄ and ZrO(OH)Cl solution droplets results in the formation of spherical particles, whereas drying of spherical NaCl solution droplets results in the formation of cubic particles.