Equilibrium and crystallographic measurements of the binary tetrahydrofuran and helium clathrate hydrates

Clathrate compounds are crystalline materials formed by a physical interaction between host and relatively light guest molecules. Various types of nano-sized cages surrounded by host frameworks exist in the highly unique crystalline structures and free guest molecules are entrapped in an open host-guest network. Recently, we reported two peculiar phenomena, swapping and tuning, naturally occurring in the hydrate cages. Helium, one of the smallest light guest molecules, must be the challengeable material in the sense of physics and moreover possesses versatile applications in the field of superconductivity technology and thermonuclear industry. In this regard, we attempted for the first time to synthesize helium hydrates at moderate temperature and pressure conditions. According to inclusion phenomena, helium itself normally cannot form clathrate hydrates due to being too small molecularly without the help of hydrate former molecules (sI, sII, and sH formers). In this study, the hydrate equilibria of the binary clathrate hydrate containing tetrahydrofuran, helium, and water were determined at 2, 3, 5.56 THF mol%. Direct volumetric measurements were also carried out to confirm the exact amount of helium captured in the hydrate cages. Finally, the crystalline structure of the formed mixed hydrates was identified by powder X-ray diffraction, resulting in structure II.     

柳钢混铁炉炉衬结构及运行管理的技改实践

针对混铁炉使用过程中出现的各种侵蚀状况，设计采用砖砌十浇注复合炉衬结构，特别对前墙拐角和后墙中段等侵蚀快的关键部位作了有针对性的技术改进；在运行管理上，制定推行全新的工艺操作规程，取得了显著的使用效果。     

WZ—C系列密封阀结构分析与改进

对W Z-C系列无料钟高炉炉顶布料设备上、下密封阀在涟钢3#高炉的使用情况进行了论述,分析了故障产生的机理,对密封阀的结构进行了改造并取得了相当可观的经济效益。     

CNC机床结构动态设计方法研究

提出机床结构动态设计基本原则。以某数控弧齿铣齿机为研究对象,应用相关的动态设计原则,通过变量化设计与有限元分析,对该机床进行结构动态设计。结果表明,应用该方法设计的机床结构具有良好的动静态特性。     

便携式多功能找星仪

找星仪是卫星地面站安装、调试、维修所必不可少的设备。旧的找星仪笨重、由于必须两人操作,很不方便。针对这些问题开发了便携式多功能找星仪。本文主要介绍了该设备的构成及其电路原理。     

精铸件结构优化设计实践

以6种典型的精密铸件为例，利用“6个千方百计”原则对产品结构进行优化设计，同时辅助有限元分析对优化结果进行再验证。通过减少大平面、避免深长孔、采用加强筋等优化措施，有效地避免了夹砂、鼓包、跑火、缩孔、裂纹等铸造缺陷，实现了少无切削和减轻铸件质量。     

气凝胶──一种结构可控的新型功能材料

气凝胶是一种结构可控的新型轻质纳米多孔性非晶固态材料，具有许多特殊性质，因而蕴藏着广阔的应用前景。本文综述了气凝胶材料的制备方法、结构控制原理、性质和各种可能的应用。     

Novel Fiberoptic Sensing Array an Fundamental Experiments

A suitable fiberoptic sensing array embedded in the smart structure to monitor quasi-distrbuted froces on the structrue in presented in this paper.Artificial neural networks are used in processing of fiberoptic sensing array signals.Fundamental experiments have been done and the results are also given.     

有机薄膜电致发光器件的结构

有机薄膜电致发光现象及其广阔的应用前景，激发了人们的研究兴趣。本文介绍了器件结构的研究现状。     

基于滑模观测器的永磁同步电机无位置传感器控制

本文提出了一种基于滑模变结构控制原理的无位置传感器控制方法。通过分析永磁同步电机的模型,应用滑模变结构控制原理,提出了一种针对永磁同步电机的无位置传感器控制策略。它利用电机中容易测得的定子电流、直流母线电压,通过滑模变结构控制原理来估算转子位置。利用Matlab／Simulink对系统进行了仿真,仿真结果表明,转子位置估算结果基本与实际位置一致。