Economic growth,CO2 emissions,and energy consumption in the five ASEAN countries

This paper investigates the relationship between economic growth, carbon dioxide (CO₂) emissions, and energy consumption with an aim to test the validity of the Environmental Kuznets Curve (EKC) hypothesis in five ASEAN (Association of South East Asian Nations) countries (Indonesia, Malaysia, Philippines, Singapore, and Thailand) by applying the panel smooth transition regression (PSTR) model as a new econometric technique. The PSTR model is more flexible and appropriate for describing cross-country heterogeneity and time instability. Our empirical results strongly rejected the null hypothesis of linearity, and the test for no remaining nonlinearity indicated a model with one transition function and two threshold parameters. The first regime (levels of GDP per capita below 4686 USD) showed that environmental degradation increases with economic growth while the trend was reversed in the second regime (GDP per capita above 4686 USD). The results also showed that energy consumption with either the first or the second regime lead to increase CO₂. The overall results support the validity of the EKC hypothesis in the ASEAN countries.     

Evolving an Accurate Decision Tree-Based Model for Predicting Carbon Dioxide Solubility in Polymers

Solubility is one of the most indispensable physicochemical properties determining the compatibility of components of a blending system. Research has been focused on the solubility of carbon dioxide in polymers as a significant application of green chemistry. To replace costly and time-consuming experiments, a novel solubility prediction model based on a decision tree, called the stochastic gradient boosting algorithm, was proposed to predict CO₂ solubility in 13 different polymers, based on 515 published experimental data lines. The results indicate that the proposed ensemble model is an effective method for predicting the CO₂ solubility in various polymers, with highly satisfactory performance and high efficiency. It produces more accurate outputs than other methods such as machine learning schemes and an equation of state approach.     

Synthesis of manganese titanate and its precursors from xerogel

An overview of research on the synthesis of manganese titanates is presented. The xerogel of Mn–Ti–O–C–H composition was synthesized from manganese acetate and titanium tetrabutylate via liquid-phase method using organic solvents. The calcination of xerogel in air at 450 °C and 700 °C yielded manganese titanate precursors in the form of a nanostructured mixture of Mn₂O₃ and TiO₂. Annealing at 1000 °C, manganese metatitanate MnTiO₃ was obtained. Reference experiments with initial reagents included, separately, thermal decomposition of Mn(CH₃COO)₂×4H₂O and the product of Ti(OC₄H₉)₄ hydrolysis. The composition, structure, and properties of the products were studied using X-ray diffraction, scanning electron microscopy, elemental analysis, diffuse reflectance IR Fourier spectroscopy, thermogravimetry, and by measuring specific surface area. The data presented by these different techniques are basically consistent with each other (with an increase in the annealing temperature, an increase in globule size and decrease in specific surface area are observed; structuring occurs within the long- and short-range order; the size of the crystallites does not exceed that of the globules; elemental composition correlates with phase composition; the endothermic character of the reaction of MnTiO₃ formation at 900 °C is confirmed by a thermodynamic calculation). Nevertheless, some unexpected effects were revealed (based on the FTIR diffuse reflection spectra, mixed oxide Mn–Ti–O is formed in the surface layer of particles already at 450 °C and 700 °C; etc.). Application of the proposed technique for modifying Al₂O₃ powders, with the aim of implementing low-temperature sintering of corundum ceramics, is discussed.     

Dye removal by polymer derived ceramic nanobeads

Emulsion processed polymer derived ceramic (PDC) nanobeads are used for Methylene Blue dye removal from aqueous solutions. The PDC nanobeads, produced at 600 °C and 1200 °C pyrolysis, are subsequently coated with titania (anatase). Titania-coated nanobeads show less than 35%, i.e., limited dye adsorption capability in dark. Instead, enhanced total removal efficiency (∼97%) is obtained when the initial adsorption is succeeded by photodegradation under UV. Direct reusability tests show that even after the third cycle, very high regeneration efficiencies being above 92% are observed for titania-coated nanobeads.     

Hydrogen production from thermal decomposition of ammonia-contaminated acid gas using a detailed reaction mechanism

The increase in the production of acid gas consisting of H₂S, CO₂, and associated impurities such as ammonia and hydrocarbons from oil and gas plants and gasification facilities has stimulated the interest in the development of alternative means of acid gas utilization to produce hydrogen and sulfur, simultaneously. The present literature lacks a detailed reaction mechanism that can reliably predict the thermal destruction of NH₃ and its blend with H₂S and CO₂ to facilitate process optimization and commercialization. In this paper, a detailed mechanism of NH₃ pyrolysis is developed and is merged with the reactions of NH₃ oxidation and H₂S/CO₂ thermal decomposition from our previous works. The mechanism is validated successfully using different sets of experimental data on the pyrolysis and oxidation of NH₃, H₂S, and CO₂. The proposed mechanism predicts the experimental data on NH₃ pyrolysis remarkably better than the existing mechanisms in the literature. The mechanism is used to investigate the effects of NH₃ concentration (0–20%) and reactor temperature (1000–1800 K) on the thermal decomposition of H₂S and CO₂. A synergistic effect is observed in the simultaneous decomposition of NH₃ and CO₂, i.e., NH₃ conversion is improved in the presence of CO₂ and the decomposition CO₂ to CO is enhanced in the presence of NH₃. The presence of H₂S suppressed NH₃ conversion, while the conversion of H₂S remained unchanged with increasing NH₃ concentration at temperature below 1400 K due to the low conversion of NH₃ (up to 18%). At temperature above 1400 K, NH₃ conversion increased rapidly and it triggered a decrease in H₂S conversion as well as the yields of H₂ and S₂. The major reactions involved in the decomposition of H₂S, CO₂, and NH₃ and the production of major products such as H₂, S₂, and CO are identified. The detailed reaction mechanism can facilitate the design and optimization of acid gas thermal decomposition to produce hydrogen and sulfur, simultaneously.     

Fully renewable limonene‐derived polycarbonate as a high‐performance alkyd resin

Limonene‐derived polycarbonate‐based alkyd resins (ARs) have been prepared by copolymerization of limonene dioxide with CO₂, catalysed by a β‐diiminate zinc–bis(trimethylsilyl)amido complex, and subsequent chemical modification with soybean oil fatty acids using triphenylethylphosphonium bromide as the catalyst. This quantitative partial modification was realized via epoxy–carboxylic acid chemistry, affording ARs with higher oil lengths, lower polydispersities and higher glass transition temperatures (T_g) in comparison to a conventional polyester AR based on phthalic acid, multifunctional polyol pentaerythritol and soybean fatty acid. The novel limonene polycarbonate AR and the conventional polyester AR were evaluated as coatings and both the physical drying (without the presence of the oxidative drying accelerator Borchi® Oxy Coat) and chemical curing (with Borchi® Oxy Coat) processes of these coatings were monitored by measuring the König hardness and complex modulus development with time. A better performance was obtained for the alkyd paint containing polycarbonates modified with fatty acids (FA‐PCs), which showed a faster chemical drying, a higher König hardness and a higher T_g in coating evaluation, demonstrating that the fully renewable FA‐PCs are promising resins for alkyd paint applications. © 2019 Society of Chemical Industry     

Preparation of highly crystalline titanium-based ceramic microfibers from polymer precursor blend by needle-less electrospinning

The aim of the present contribution is to study the influence of the post-spinning heat - treatment of single TiO₂/PVP precursor fibers on the properties and morphology of the final titanium-based microfibers. The post-spinning treatment conditions were: calcination in air at 450–600?°C and pyrolysis in argon at 1000–1700?°C. Calcination resulted in a production of anatase-rich and pure rutile fibers. The use of an alternative sintering method, the low-temperature plasma treatment, led to the crystallization of the composite Magnéli phases/polymer fibers. As a result of the same one precursor, pyrolysis at 1000?°C, the Carbon/TiO₂ composite fibers were obtained. Rising the treatment temperature in inert atmosphere led to the formation of the titanium carbide fibers. The formation process and all the obtained products were characterized by differential scanning calorimetry accompanied with thermogravimetric analysis (DSC/TGA), scanning and transmission electron microscopy (SEM, TEM), X-ray diffraction (XRD), and image analysis techniques.