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111.
便携式二氧化碳检测仪的设计 总被引:1,自引:1,他引:0
为了探测地震废墟狭小空间内幸存者的呼出气体,设计了便携式二氧化碳检测仪.检测仪采用红外二氧化碳传感器进行检测,通过单片机直接获取数字信号,并具有温度补偿功能.检测结果通过真空荧光显示屏显示,超过预设值触发声光报警.废墟实验表明:该检测仪适用于狭小空间内幸存者的搜索工作. 相似文献
112.
Thermal analysis of the cooling curves of small samples of uranium dioxide, laser heated in a high-pressure autoclave on a subsecond time scale to a temperature just below the melting point, reveals, in the case of nominally stoichiometric UO2.00, a significant -like heat capacity peak, indicating a premelting transition in this material. The results are discussed and a simple model is presented in terms of which the observed behavior can be described.Summary of a paper presented at the Third Workshop on Subsecond Thermophysics, September 17–18, 1992, Graz, Austria. Because of its length, the full paper was published in a regular issue of this journal (Vol. 14, No. 2, 1993). 相似文献
113.
Photocatalytic treatment of water-soluble pesticides by photo-Fenton and TiO2 using solar energy 总被引:1,自引:0,他引:1
S. Malato J. Blanco J. C ceres A. R. Fern ndez-Alba A. Agü era A. Rodrí guez 《Catalysis Today》2002,76(2-4):209-220
The technical feasibility and performance of photocatalytic degradation of four water-soluble pesticides (diuron, imidacloprid, formetanate and methomyl) have been studied at pilot scale in two well-defined systems of special interest because natural-solar UV light can be used: heterogeneous photocatalysis with titanium dioxide and homogeneous photocatalysis by photo-Fenton. The pilot plant is made up of compound parabolic collectors (CPCs) specially designed for solar photocatalytic applications. Experimental conditions allowed disappearance of pesticide and degree of mineralisation achieved in the two photocatalytic systems to be compared. In order to assure that the photocatalytic results are consistent, hydrolysis and photolysis tests have been performed with the four pesticides. The initial concentration tested with imidacloprid, formetanate and methomyl was 50 and 30 mg/l with diuron, and the catalyst concentrations were 200 mg/l and 0.05 mM with TiO2 and iron, respectively. Total disappearance of the parent compounds and 90% mineralisation have been attained with all pesticides tested, methomyl being the most difficult to be degraded with both treatments. First-order rate constants, initial rate, time necessary for mineralising 90% of the initial TOC and hydrogen peroxide consumption were calculated in all cases, enabling comparison both of treatments and of the selected pesticide reactivity. 相似文献
114.
Chengkun Xu Richard Killmeyer McMahan L. Gray Shahed U.M. Khan 《Applied catalysis. B, Environmental》2006,64(3-4):312-317
The present research focused on wet process synthesis of visible light active carbon-modified (CM)-n-TiO2 nanoparticles and their photocatalytic activity. The CM-n-TiO2 was synthesized by hydrolysis of TiCl4 in the presence of tetrabutylammonium hydroxide and also in the presence of glucose and sodium hydroxide. UV–vis spectra, X-ray diffraction (XRD), and FT-IR were used to characterize these photocatalysts. It was found that the CM-n-TiO2 nanoparticles synthesized by hydrolysis with tetrabutylammonium hydroxide or with sodium hydroxide and glucose when subjected to extended aging and subsequent calcinations absorb well into the visible to near infrared region up to 800 nm and exhibit enhanced visible light photocatalytic activity on degradation of 4-chlorophenol. CM-n-TiO2 synthesized using glucose as the carbon source generated 13-fold increase in the initial rate of photodegradation of 4-chlorophenol compared to those by regular n-TiO2, whereas, it increased only eight-fold when tetrabutylammonium hydroxide was used as the carbon source. 相似文献
115.
116.
利用固定体积可视高压釜测量出的在323K~353K温度范围内的CO2与2-丁醇二元体系在高压下的汽液相平衡数据,根据Krichevsky-Kasarnovsky方程建立了CO2在液相中的溶解度模型,得到了该二元体系在高压下的亨利系数和CO2在无限稀释溶液中的偏摩尔体积等性质。同时根据偏摩尔体积性质和Peng-Robinson状态方程及Van der Waals-2混合规则来计算该体系在平衡状态下的气、液相的偏摩尔体积。结果表明CO2在2-丁醇中的亨利系数和CO2在无限稀释溶液中的偏摩尔体积均为温度的函数,CO2在2-丁醇中的亨利系数随温度的升高而降低。CO2在无限稀释溶液中的偏摩尔体积∞1V在研究温度下均为负值,其中随温度升高,其绝对值下降。在平衡状态下的气、液相的偏摩尔体积计算结果表明:平衡状态下,液相中CO2与2-丁醇的偏摩尔体积均为正值。气相中不同温度下CO2的偏摩尔体积均为负值,且其绝对值随着压力的增加而越来越大,2-丁醇的偏摩尔体积均为正值。此研究为该体系超临界萃取条件的确立和指导工业化生产提供了理论依据。 相似文献
117.
118.
工艺参数对TiO2碳热还原合成Ti(C,N)粉末的影响 总被引:4,自引:0,他引:4
本文探讨了TiO2碳热还原法合成Ti(C,N)粉末过程中合成温度,保温时间,N2气流量,C/Ti比值等工艺参数的变化对粉末性状的影响,实验表明,N比C更易于Ti结合,改变工艺对数可调整Ti(C1-xNx)的x值。在1400~1700℃间可获得x值的0.6~0.85的Ti(C1-xNx)粉末。 相似文献
119.
Models representing the thermodynamic behavior of the CO2–H2O mixture have been developed. The single-phase model is based upon the thermodynamic property mixture model proposed by Lemmon and Jacobsen. The model represents the single-phase vapor states over the temperature range of 323–1074 K, up to a pressure of 100 MPa over the entire composition range. The experimental data used to develop these formulations include pressure–density–temperature-composition, second virial coefficients, and excess enthalpy. A nonlinear regression algorithm was used to determine the various adjustable parameters of the model. The model can be used to compute density values of the mixture to within ±0.1%. Due to a lack of single-phase liquid data for the mixture, the Peng–Robinson equation of state (PREOS) was used to predict the vapor–liquid equilibrium (VLE) properties of the mixture. Comparisons of values computed from the Peng–Robinson VLE predictions using standard binary interaction parameters to experimental data are presented to verify the accuracy of this calculation. The VLE calculation is shown to be accurate to within ±3 K in temperature over a temperature range of 323–624 K up to 20 MPa. The accuracy from 20 to 100 MPa is ±3 K up to ±30 K in temperature, being worse for higher pressures. Bubble-point mole fractions can be determined within ±0.05 for CO2. 相似文献
120.
KDONAr-10000/22000/370型空分设备因空冷塔液位计失效而发生分子筛吸附器进水故障。介绍了故障发生的经过和处理过程;最后得出了发现及处理分子筛吸附器进水故障的经验和教训。 相似文献