Energy Transfer Induced by TADF Polymer Enables the Recycling of Excitons in Perovskite Solar Cells

Formamidinium lead triiodide (FAPbI₃) has been demonstrated as the most efficient perovskite system to date, due to its excellent thermal stability and an ideal bandgap approaching the Shockley-Queisser limit. Whereas, there are intrinsic quantum confinement effects in FAPbI₃, which lead to unwanted non-radiative recombination. Additionally, the black α-phase of FAPbI₃ is unstable under room temperature due to the significant residual tensile stress in the film. To simultaneously address the above issues, a thermally-activated delayed fluorescence polymer P1 is designed in the study to modify the FAPbI₃ film. Owing to the spectral overlap between the photoluminescence of P1 and absorption of the above-bandgap quantum wells of FAPbI₃, the Förster energy transfer occurs at the P1/FAPbI₃ interface, which further triggers the Dexter energy transfer within FAPbI₃. The exciton “recycling” can thus be realized, which reduces the non-radiative recombination losses in perovskite solar cells (PSCs). Moreover, P1 is found to introduce compressive stress into FAPbI₃, which relieves the tensile stress in perovskite. Consequently, the PSCs with P1 treatment achieve an outstanding power conversion efficiency (PCE) of 23.51%. Moreover, with the alleviation of stress in the perovskite film, flexible PSCs (f-PSCs) also deliver a high PCE of 21.40%.     

Modulation of Electron Structure and Dehydrogenation Kinetics of Nickel Phosphide for Hydrazine-Assisted Self-Powered Hydrogen Production in Seawater

The electrocatalytic production of hydrogen from seawater provides a low-cost way to realize energy conversion, but is restricted by high potential for seawater electrolysis and the chlorine oxidation reaction (ClOR) at the anode. Here, the self-growth of Mo-doped Ni₂P nanosheet arrays with rich P vacancies on molybdenum-nickel foam (MNF) (Mo-Ni₂P_v@MNF) is reported as bifunctional catalyst for Cl-free hydrogen production by coupling hydrogen evolution reaction (HER) with hydrazine oxidation reaction (HzOR) in seawater. Impressively, the Mo-Ni₂P_v@MNF electrode as bifunctional catalyst has an excellent activity for overall hydrazine splitting (OHzS) with an ultralow voltage of only 571 mV at 1000 mA cm⁻² and can maintain stability for an ultra-long time of 1000 h at 100 mA cm⁻². Moreover, integration of OHzS into self-assembled hydrazine fuel cells (DHzFC) or solar cells can enable the self-powered H₂ production. The industrial hydrazine sewage as feed for the above eletrolysis system can be degraded to ≈5 ppb rapidly. Density functional thoery calculations demonstrate that the electronic structure modulation induced by P vacancies and Mo doping can not only achieve thermoneutral ΔG_H* for hydrogen evolution reaction but also enhance dehydrogenation kinetics from *N₂H₄ to *NHNH₂ for HzOR, achieving enhanced dehydrogenation kinetics.     

A Universal Descriptor in Determining H2 Evolution Activity for Dilute Aqueous Zn Batteries

Large-scale energy storage with aqueous Zn batteries (AZBs) have bright future, but their practical application is impeded by H₂ evolution reaction (HER), which results in poor stability of Zn–metal anodes. Here, using linear sweep voltammetry in dilute salt aqueous electrolytes, it is discovered that as the salt concentration decreases, HER is gradually suppressed, which is contrary to prior beliefs. Combining calculations and experiments, it is demonstrated that HER derives predominantly from the sum of Zn²⁺-solvated water rather than the average amount of water in the Zn²⁺-solvation structural unit or free water without interaction with Zn²⁺, which answers the puzzle from above. This result, which differs fundamentally from the previous understandings, sheds new light on the mysterious role of water chemistry in controlling HER and contributes to a more rational design of advanced electrolytes for AZBs.     

基于WEB网上问卷调查系统研究

研究了基于WEB网上问卷调查系统,它采用Rational Rose2003工具进行系统UML建模,采用SQL Server 2008数据库进行后台数据库的设计与开发,采用TomCat进行系统运行服务器的搭建。本系统采用B/W/D的3层体系结构、使用Java Web开发框架中的Struts和Hibernate技术实现开发,实现了问卷创建、编辑、发布、统计,题目添加、删除、修改,友情连接管理等功能。本系统在实际中有一定的应用价值。     

基于改进DeepLabV3+的铣床碎屑图像分割方法

针对铣床碎屑形状不规则导致图像分割中碎屑轮廓不清晰、分割精度低的问题,本文提出一种改进的DeepLabV3+铣床碎屑分割算法。首先在DeepLabV3+的Xcepetion模块中嵌入通道与空间注意力机制(convolutional block attention module, CBAM)模型,优化通道的权重和位置信息,加强碎屑图像区域的特征学习;其次将DeepLabV3+的空洞空间卷积池化金字塔(atrous spatial pyramid pooling, ASPP)模块改为密集连接(dense conolutional network, DenseNet)方式,增大碎屑图像特征点的感受野,提升铣床碎屑图像特征的复用效率;最后在解码过程中采用多尺度自适应特征融合方法,聚合多尺度特征作为解码器的输入特征,提高碎屑图像分割的精度与鲁棒性。实验结果表明,本文算法优于其他分割算法,改进后算法相比DeepLabV3+,像素准确率提高0.026,平均交并比(mean intersection over union,MIOU)提高0.020,F₁值提高了0.013。     

Direct Freeform Laser Fabrication of 3D Conformable Electronics

3D conformable electronic devices on freeform surfaces show superior performance to the conventional, planar ones. They represent a trend of future electronics and have witnessed exponential growth in various applications. However, their potential is largely limited by a lack of sophisticated fabrication techniques. To tackle this challenge, a new direct freeform laser (DFL) fabrication method enabled by a 5-axis laser processing platform for directly fabricating 3D conformable electronics on targeted arbitrary surfaces is reported. Accordingly, representative laser-induced graphene (LIG), metals, and metal oxides are successfully fabricated as high-performance sensing and electrode materials from different material precursors on various types of substrates for applications in temperature/light/gas sensing, energy storage, and printed circuit board for circuit. Last but not the least, to demonstrate an application in smart homes, LIG-based conformable strain sensors are fabricated and distributed in designated locations of an artificial tree. The distributed sensors have the capability of monitoring the wind speed and direction with the assistance of well-trained machine-learning models. This novel process will pave a new and general route to fabricating 3D conformable electronic devices, thus creating new opportunities in robotics, biomedical sensing, structural health, environmental monitoring, and Internet of Things applications.     

Fast Ion Transport in Li-Rich Alloy Anode for High-Energy-Density All Solid-State Lithium Metal Batteries

All-solid-state Li batteries (ASSLBs) with solid-polymer electrolytes are considered promising battery systems to achieve improved safety and high energy density. However, Li dendrite formation at the Li anode under high charging current density/capacity has limited their development. To tackle the issue, Li-metal alloying has been proposed as an alternative strategy to suppress Li dendrite growth in ASSLBs. One drawback of alloying is the relatively lower operating cell voltages, which will inevitably lower energy density compared to cells with pure Li anode. Herein, a Li-rich Li₁₃In₃ alloy electrode (LiRLIA) is proposed, where the Li₁₃In₃ alloy scaffold guides Li nucleation and hinders Li dendrite formation. Meanwhile, the free Li can recover Li's potential and facilitate fast charge transfer kinetics to realize high-energy-density ASSLBs. Benefitting from the stronger adsorption energy and lower diffusion energy barrier of Li on a Li₁₃In₃ substrate, Li prefers to deposit in the 3D Li₁₃In₃ scaffold selectively. Therefore, the Li–Li symmetric cell constructed with LiRLIA can operate at a high current density/capacity of 5 mA cm⁻²/5 mAh cm⁻² for almost 1000 h.     

基于不同醇的醇水法制备纳米CeO2的研究

在四种醇水体系中,以HMT为缓释沉淀剂制备了纳米CeO2粉体。研究了醇的种类、醇水比例及煅烧温度对纳米CeO2颗粒尺寸的影响;并用XRD,BET,TEM,TGA/DSC等表征方法对其影响机理进行了探讨。结果表明:溶剂从甲醇到异丙醇变化时,颗粒逐渐增大;异丙醇到正丁醇时,颗粒尺寸略有降低,且煅烧前颗粒尺寸均介于10~20nm之间。     

BaSnO3陶瓷的制备及其电性能研究

以BaCO3、SnO2为原料,微量SiO2、Bi2O3、Sb2O3作烧结助剂,Ta2O5作施主,采用传统的固相反应法,制备出相对密度达97%~99%,平均粒径约为8μm的BaSnO3半导体陶瓷。采用Na2CO3或Li2CO3与Mn(NO3)2的组合作受主掺杂可有效增强BaSnO3陶瓷的晶界效应。当x(Mn(NO3)2)为1%时,BaSnO3陶瓷电阻率达3.3×106Ω.cm,晶粒电阻率为4.3Ω.cm,视在介电常数为1.9×104(1 kHz),经电导激活能测试,估算出晶界势垒约为0.5 eV。