Sensitivity and uncertainty analysis of microstructure–property relationships for compacted powder metals

Abstract

In an earlier study, the authors presented a characterisation of the FC-0205 Ancorsteel powders containing 0·6 and 1·0% Acrawax to define the evolution of the failure line and cap surface of the modified Drucker/Prager cap model during compaction. Using the results of that study (i.e. FC-0205 material parameters), this paper presents sensitivity and uncertainty analysis of the microstructure–property relationships for powder metallurgy compaction. It is found for all of the responses of interest (the compressibility curve, the interparticle friction, the material cohesion, the cap eccentricity and the elastic modulus) that the most dominant parameter is the initial (or tap) density. It is also observed that the uncertainty in output parameters for the case of 1% wax is much larger than those for the case of 0·6% wax, due to the large uncertainty in the failure stress (in particular, the compressive failure stress).     

Effect of powder size on microstructure and mechanical properties of Ti(C,N) based cermets

Abstract

Effect of the particle size of TiC and TiN on the microstructure and mechanical properties of Ti(C,N) based cermets has been evaluated. Ti(C,N)–WC–Co cermets made from four groups of mixed raw powders of different sizes were manufactured by vacuum sintering. The microstructure and composition were studied using X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectrum (EDX). The result shows that the four samples have the typical microstructures of 'black core/grey rim'. The mechanical properties of the cermet manufactured from submicron TiC and nano TiN are the best among the four samples.     

Effect of niobium on electrical properties of Sr0.8Bi2.3(Ta1-xNbx)2O9+ thin films processed by sol–gel method

Abstract

Polycrystalline SBTN ferroelectric thin films were prepared by the sol–gel method with various Nb mole ratioson Pt/SiO₂/Si(100) substrates. The films were annealed at different temperatures and characterised in terms of phase and microstructure. A relatively well saturated hysteresis pattern was obtained at x=0.2 in Sr_0.8Bi_2.3(Ta_1-xNb_x)₂O_9+ thin films. At an applied voltage of 5 V, the dielectric constant ε _r and dissipation factor tan δ of a typical Sr_0.8Bi_2.3(Ta_1-xNb_x)₂O_9+ thin film (x=0.2) were about 236.2 and 0.034. Measured remanent polarisation 2P _r and coercive field E _c were 4.28 µC cm², and 38.88 kV cm¹ respectively. No fatigue was observed up to 6×10¹⁰ switching cycles at 5 V and the normalised polarisation reduced by a factor of only 4%.     

Modelling of transient temperature fields during filling stage of powder injection moulding

Abstract

Numerical simulation of the powder injection moulding of the stainless steel feedstock was performed using finite elements/finite differences method. Influence of the process parameters on the temperature development in the moulded part was estimated. Frictional heating between the layers of the feedstock with different viscosity may cause the temperature rise to a level dangerous for the integrity of the feedstock. Both process conditions and position of the gate affect the temperature distribution within the part. The temperature homogeneity can be improved by optimisation of the mould design and process conditions.     

Swelling during sintering of titanium alloys based on titanium hydride powder

Abstract

Compacts were prepared by pressing titanium and titanium hydride powders mixed with nickel powder and sintering under vacuum. Severe swelling was observed only for compacts based on TiH₂ powder. Pressure changes in the vacuum furnace, dilatometry results and mass loss data all indicate that dehydrogenation of TiH₂ powder compacts occurs at lower temperature than any significant sintering. Swelling appears to have been caused by a contaminant in the TiH₂ powder rather than hydrogen. The onset of severe swelling during heating was associated with the formation of liquid phase as the solidus was crossed. However, some swelling appears to take place under solid state sintering conditions. Various results indicate that the mechanism of swelling is high gas pressure within closed pores. Large pores appear to form by breakage of ligaments between small pores followed by opening of the pore. It appears that the use of (uncontaminated) TiH₂ powder in place of Ti powder would allow the benefit of lower green porosity to be retained during sintering to achieve low sintered porosity.     

Titanium–hydroxyapatite composite biomaterial for dental implants

Abstract

The objective of the present study was to investigate high velocity compaction of titanium powder and to prepare a dense composite biomaterial of titanium and hydroxyapatite with the purpose of forming dental components with improved early healing properties. A high purity titanium powder was compacted using high velocity compaction to study the density distribution. Then, a titanium–hydroxyapatite composite was prepared by mixing titanium powders and hydroxyapatite grains. Dental implant components were formed from the high velocity compacted specimens, exposing the hydroxyapatite grains at the component surface. The green density reached more than 98·5% after more than one impact. The composite was heated to 500°C, enough to bind the titanium grains, but to avoid observable reactions. Compacted pure titanium could be sintered to full density. The heated composite material reached 99% density, no reaction was observed between titanium and hydroxyapatite, and the composite material could be formed into dental implants.     

Optimisation of process conditions in powder injection moulding of microsystem components using robust design method Part 2 – Secondary design parameters

Abstract

Powder injection moulding (PIM) is a proper fabrication method for microsystem technology components. This paper studies the process control of PIM to create thin walled, high aspect ratio geometries, which can be easily found in microtechnology based electro chemical, mechanical and biological systems (MECS). The powder used in this study is gas atomised 316L stainless steel with a median particle size of 10 μm. The effects of reducing the thickness of high aspect ratio geometries on the secondary design parameters including the maximum wall shear stress, cooling time and standard deviations of the melt front velocity and areas are studied. The study shows process parameters including fill time, feedstock injection temperature, mould wall temperature and switchover position can be optimised using the Taguchi robust design method.     

Effect of Al2O3 and B4C particle additions on microstructure of PM copper based brake linings

Abstract

This paper highlights the effect of different ceramic particles on the structure of PM copper based brake linings. The copper based brake linings using a range of ceramic additives (1–6 wt-%) were prepared by powder metallurgy (PM). The optimum conditions for the production of brake linings were determined as compaction under 400 MPa and sintering at 805°C for 20 min in an argon atmosphere. The density of copper based brake linings decreased after sintering with the increase in ceramic powder contents for both Al₂O₃ and B₄C ceramic particles. The microstructural characterisation of produced samples showed that the lower boiling point elements in the as supplied powder vaporise during sintering from the structure and this leads to an increase in the porosity amount of the final component.     

Effects of strain aging on the structure and mechanical properties of PM 92·5W–5Ni–2·5Fe heavy alloys

Abstract

This paper describes the effects of strain aging on the mechanical properties and the microstructure of forged 92·5W–5Ni–2·5Fe and its heavy alloys microalloyed with cobalt. The investigation was performed on cold rotary forged rods deformed 15, 20 and 30% and strain aged at temperatures from 673 to 1273 K for 1·8–32·4 ks. The results show that for these alloys, there is a temperature range from 773 to 873 K in which maximum ultimate strength and hardness can be attained. Furthermore, the strain aged alloys have shown strength and hardness increase at a temperature of 973 K in a time period of 10·8 ks. The fracture analysis has shown the presence of predominant transgranular fracture of the tungsten phase and γ-phase in the strain-aged alloys in comparison with the forged alloys. The results indicate that interface and tungsten phase strengthening are predominant mechanisms of strain aging.     

Modelling molten flux layer thickness profiles in compact strip process moulds for continuous thin slab casting

Abstract

The important functions promoted by powdered flux added over the liquid steel surface in continuous casting moulds are strongly affected by the thickness of the liquid layer that forms as a result of the heat absorbed. The present work discusses the results of a three-dimensional steady state model, developed to represent the coupled fluid flow and heat transfer phenomena that determine thickness profiles of the liquid flux layer. Since the laminar flow of the liquid slag layer depends on the shearing imposed on it by the turbulent motion of the liquid steel beneath it, and since additionally this motion is strongly influenced by the flow characteristics of the steel stream poured into the mould through the submerged entry nozzle (SEN), separate turbulent flow models for the liquid steel in the SEN and the mould were also developed. The consistency among the models and their accuracy was judged by comparing thickness and temperature flux profiles measured in plant against predicted ones; the comparison showed good agreement. The effects of casting speed, mould width, and flux viscosity and heat of melting on the liquid layer thickness were investigated. The last variable was found to exert the most marked influence. Different from conventional casting moulds, where the liquid layer thickness increases with increasing casting speed, in compact strip process moulds the thickness remains almost constant with increasing casting speed. This difference is well accounted for by the model, which suggests that this behaviour stems from the different slag flow patterns generated in straight, wide moulds and in thin moulds having a central upper funnel shaped section.