加强电炉钢短流程生产工艺研究与技术开发的建议

论述了加强电炉钢短流程生产工艺研究与技术开发的必要性和主要课题，并提出关于组织合金钢短流程生产工艺研究与技术开发“九五”国家科技攻关及提高高研究开发投资强度的建议。     

Diffusion and influence of Cu on properties of CdTe thin films and CdTe/CdS cells

The effective diffusion coefficients of Cu for thermal and photodiffusion in the CdTe films have been estimated from resistivity versus duration of thermal or photoannealing curves. In the temperature range 60–200°C the effective coefficient of thermal diffusion (D_t) and photodiffusion (D_ph) are described as D_t=7.3×10⁻⁷exp(−0.33/kT) and D_ph=4.7×10⁻⁸exp(−0.20/kT).It is found that the diffusion doping of CdTe thin films by Cu at 400°C results in a sharp decrease of resistivity up to 7 orders of magnitude of p-type material, depending on thickness of Cu film. The comparative study of performance of CdTe(Cu)/CdS and CdTe/CdS cells has been studied. It is shown that the diffusion doping of CdTe film by Cu increases efficiency of CdTe(Cu)/CdS cells from 0.9% to 6.8%. The degradation of photovoltaic parameters of CdTe(Cu)/CdS cell, during testing under forward and reverse bias at room temperature, proceeds at a larger rate than those of CdTe/CdS cell without Cu. The degradation of performance of CdTe(Cu)/CdS cells is tentatively assigned to electrodiffusion of Cu in CdTe, resulting in redistribution of concentration of Cu-related centers in CdTe film and heterojunction region.     

Corrosion behaviour of decorative and wear resistant coatings on steel deposited by reactive magnetron sputtering - Tests and improvements

Depositions of decorative and wear resistant single layer coatings like TiN, Ti(B,N), CrN, NbN, NbON, (Ti,Mg)N and multilayer coatings like Cr/CrN, Nb/NbN, CrN/NbN and NbN/Nb-C:H were performed using reactive magnetron sputtering. The corrosion behaviour of the coated high speed steel substrates was studied in sodium chloride containing media by open-circuit-potential measurements, potentiodynamic corrosion tests and salt spray tests. Up to now, the best improvements with respect to the corrosion resistance in salt spray tests could be obtained for the system (Ti,Mg)N/high speed steel.     

进一步降低钼精矿中铜、铅含量的生产实践

分析了钼精矿Cu、Pb含量高的主要原因 ,通过实施一系列措施 ,达到了降低钼精矿中Cu、Pb含量的目的     

超低碳奥氏体不锈钢00Cr18Ni10还原脱磷研究

在 2 5kg真空感应炉上用镁钙合金对超低碳奥氏体不锈钢 0 0Cr18Ni10进行了还原脱磷试验。通过充入工业纯氩使炉内压力为 6 6 .6 6kPa和精炼时的反应温度 14 5 0～ 15 0 0℃ ,加入镁钙合金 5 0kg t和助熔剂CaF2 11kg t,可使精炼后 0 0Cr18Ni10的磷含量进一步降低到 (5 0～ 6 0 )× 10 - 6 ,钢中氧、硫含量分别稳定降到(4～ 6 )× 10 - 6 和 15× 10 - 6 。     

SFG and DFG investigation of Au(111), Au(210), polycrystalline Au,Au–Cu and Au–Ag–Cu electrodes in contact with aqueous solutions containing KCN and 4-cyanopyridine

We report on potential-dependent in situ SFG and DFG spectroscopy carried out at Au(111), Au(210), polycrystalline Au, Au–Cu and Au–Ag–Cu electrodes in contact with aqueous solutions containing CN⁻ and 4-cyanopyridine (4CP). Spectroelectrochemical work was complemented by cyclic voltammetry. The chief stress has been placed on systematising and quantifying the interaction between 4CP and CN⁻ and the attending effects on the vibrational and electronic structures of the interface. The voltammetric behaviour of the investigated electrodes, modified by the addition of 4CP to the CN⁻ electrolyte, denote changes in the CN⁻ adsorption characteristics and effects of the adsorbed CN⁻ layer on the electrodic reactivity of 4CP. The differences among the investigated electrodes can be explained in terms of their respective degrees of atomic packing or with alloying effects on the stability of adsorbed CN⁻. The potential-dependent spectra have been analysed quantitatively with a model for the second order non linear susceptibility accounting for vibrational and electronic effects. The spectral changes induced by addition of 4CP denote interaction of the aromatic with the electrode through the CN⁻ monolayer. The non-resonant contribution yields information on the effects of 4CP on the fine structure of the bound electron density of states.     

Water management in the Flemish steel industry: the Arcelor Gent case

Steel production is an energy- and water-intensive process: large quantities of water are used for cooling, process and environmental-technical applications. In the mid-1990s, Arcelor Gent, a large integrated carbon steel producing company in Flanders (Belgium), started a number of water-related projects: the existing water infrastructure was adapted: the water from the coke plant was biologically treated; canal water was demineralised using reverse osmosis; waste water from the blast furnaces was neutralised with alkaline water from the steel plant. As a result of these projects, the quantity of discharged waste water was reduced by a factor of 2 (water recycling doubled from a factor of 10 to a factor of 20), and the discharge of pollutants decreased. Also resource consumption decreased: lime used in the steel plant, could be recovered to precipitate Zn in the waste water of the blast furnaces. Arcelor Gent obtained for these projects several Environmental Awards.     

钢包炉(LF)预熔精炼渣的研究

预熔精炼渣具有成分均匀，性能稳定，储存时不吸水等特点，钢包炉中使用预熔精炼渣时成渣均匀且速度快，具有较强的吸附钢中非金属夹杂的能力。综合脱硫率高等冶金效果。有显著净化钢液作用。     

Improvement of photon collection in Cu(In,Ga)Se2 solar cells and modules by fluorescent frequency conversion

Fluorescent photon down conversion for the improvement of the blue response of ZnO/CdS/Cu(In,Ga)Se₂ heterojunction solar cells and modules is investigated. Fluorescent dyes of the series Lumogen® F are analyzed by optical transmission and reflection as well as by photoluminescence measurements. A spectral transfer matrix formalism is introduced that allows to predict the suitability of a luminescent dye as a down-converter for a given solar cell from its absorption/emission properties. We find that Lumogen® F Violet 570 and Lumogen® F Yellow 083 as well as a combination of both yields improvements for Cu(In,Ga)Se₂ solar modules. Particularly, we find that the short circuit current density of a Cu(In,Ga)Se₂ mini-module is improved by 1.5 mA cm^− 2 when applying a varnish with a combination of Lumogen® F Violet and Yellow. About 0.5 mA cm^− 2 of this improvement is due to a reduced overall reflectance and an improvement of 1 mA cm^− 2 results from the frequency conversion by the dyes.     

Reversible changes of the fill factor in the ZnO/CdS/Cu(In,Ga)Se2 solar cells

The reversible persistent changes of the fill factor (FF) induced by the illumination and voltage bias along with changes in the electronic properties of the ZnO/CdS/Cu(In,Ga)Se₂ photovoltaic devices have been studied. Admittance spectroscopy and capacitance–voltage characterization reveal a correlation between the FF and the space charge distribution within the absorber. Our experiments provide evidence that a major source of FF loss in efficient devices is caused by excess negative charge close to the interface. We explain the persistent changes in the net acceptor concentration in the interface region by the relaxation effects due to compensating donors—the same mechanism, which leads to metastable changes of the doping level in the bulk of the absorber.