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991.
采用内氧化法工艺制备了不含添加剂及分别含添加剂CuO或TeO2的3种AgSnO2In2O3触头材料。应用模拟继电器试验设备检测了这3种材料在AC230 V、25 A阻性负载条件下的电寿命、熔焊力、电弧能量、燃弧时间、质量侵蚀率等相关电性能参数,并对检测结果及试验后铆钉触头样品进行了分析。研究发现:与不含添加剂的AgSnO2In2O3材料相比,添加剂CuO对材料的电寿命影响不大,而添加剂TeO2明显提高了材料的电寿命;含添加剂的两种材料的熔焊力和电弧能量均有了不同程度的降低,但它们的质量侵蚀率却明显增加。 相似文献
992.
传统的静电纺丝法使用单一的毛细管状喷头喷丝,通常用于制备实心且表面光滑单一组分的纳米纤维,无法得到具有多种功能性结构的复合材料,应用范围较窄。以酞酸丁酯和尿素为原料,采用同轴静电纺丝法成功制备了TiO2/g-C3N4复合材料,并用X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、紫外可见漫反射光谱(UV-vis DRS)、场发射扫描电子显微镜(SEM)和Brunauer-Emmett-Teller (BET)分析对样品进行了表征,通过光催化降解亚甲基蓝溶液(MB)研究了不同g-C3N4添加量对TiO2/g-C3N4复合材料光催化性能的影响。实验结果表明,采用同轴静电纺丝法结合500℃煅烧工艺成功制备了大比表面积及高光催化性能的TiO2/g-C3N4复合材料。当g-C3N4添加量为0.15 g时,TiO2/g-C3N4复合材料对亚甲基蓝溶液(MB)的光催化降解效率可达93.8%,且经过5次重复实验后降解率仍可达80%以上。 相似文献
993.
994.
In the chemical looping with oxygen uncoupling (CLOU) process,CuO is a promising material due to the high oxygen carrier capacity and exothermic reaction in fuel reactor but limited by the low melting point.The combustion rate of carbon is faster than the decoupling rate of oxygen carrier (OC).Hence,high tem-perature tolerance and rapid oxygen release rate of CuO modified by three different ores were investi-gated in this study.The kinetics analysis of oxygen decoupling with Cu-based oxygen carriers was also evaluated.Results showed that CuO modified by chrysolite had faster oxygen release rate than that of CuO.Limestone showed obvious positive effect on the oxidization process.The selected OCs could keep stable in at least 20 cycles,for about 1200 min.Shrinking core model (SCM) fitted well for the decoupling process in the temperature range of 1123-1223 K.Reduction rate kinetic information may aid in the development of chemical looping with oxygen uncoupling (CLOU) technologies during reactor design and process modeling.Ternary doped copper oxide with chrysolite and limestone could improve the reactivity of CuO in decoupling and coupling process and also improve the high temperature tolerance. 相似文献
995.
Muhammad Khurram Tufail Niaz Ahmad Le Yang Lei Zhou Muhammad Adnan Naseer Renjie Chen Wen Yang 《中国化学工程学报》2021,39(11):16-36
The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm-1, and deformability, the sulfide-based Li7P3S11 solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li7P3S11 could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li7P3S11-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries. 相似文献
996.
997.
以磷酸二苯酯为催化剂,3-甲基吲哚类化合物与亚胺通过Friedel-Crafts加成反应一步合成了具有广泛药理活性的2-吲哚基甲烷胺类化合物,对反应条件进行优化。结果表明,当n(3-甲基吲哚类)∶n(亚胺)∶n(磷酸二苯酯)=1.0∶2.0∶0.1,其中,磷酸二苯酯0.0025 mmol,1 mL无水二氯甲烷作溶剂,室温下反应0.5 h时,即可得到高收率2-吲哚基甲烷胺类衍生物(85%~90%)。产物经 1HNMR、13CNMR 和 HRMS 进行了结构确定。 相似文献
998.
Daniel Nedvd Petr Hoek Petr Klíma Klra Hoyerov 《International journal of molecular sciences》2021,22(7)
Cytokinins are a class of phytohormones, signalling molecules specific to plants. They act as regulators of diverse physiological processes in complex signalling pathways. It is necessary for plants to continuously regulate cytokinin distribution among different organs, tissues, cells, and compartments. Such regulatory mechanisms include cytokinin biosynthesis, metabolic conversions and degradation, as well as cytokinin membrane transport. In our review, we aim to provide a thorough picture of the latter. We begin by summarizing cytokinin structures and physicochemical properties. Then, we revise the elementary thermodynamic and kinetic aspects of cytokinin membrane transport. Next, we review which membrane-bound carrier proteins and protein families recognize cytokinins as their substrates. Namely, we discuss the families of “equilibrative nucleoside transporters” and “purine permeases”, which translocate diverse purine-related compounds, and proteins AtPUP14, AtABCG14, AtAZG1, and AtAZG2, which are specific to cytokinins. We also address long-distance cytokinin transport. Putting all these pieces together, we finally discuss cytokinin distribution as a net result of these processes, diverse in their physicochemical nature but acting together to promote plant fitness. 相似文献
999.
1000.
Wei-Chieh Huang Kao-Chang Lin Chih-Wei Hsia Chih-Hsuan Hsia Ting-Yu Chen Periyakali Saravana Bhavan Joen-Rong Sheu Shaw-Min Hou 《International journal of molecular sciences》2021,22(7)
Platelets play a crucial role in the physiology of primary hemostasis and pathological processes such as arterial thrombosis; thus, developing a therapeutic target that prevents platelet activation can reduce arterial thrombosis. Pterostilbene (PTE) has remarkable pharmacological activities, including anticancer and neuroprotection. Few studies have reported the effects of pterostilbene on platelet activation. Thus, we examined the inhibitory mechanisms of pterostilbene in human platelets and its role in vascular thrombosis prevention in mice. At low concentrations (2–8 μM), pterostilbene strongly inhibited collagen-induced platelet aggregation. Furthermore, pterostilbene markedly diminished Lyn, Fyn, and Syk phosphorylation and hydroxyl radical formation stimulated by collagen. Moreover, PTE directly hindered integrin αIIbβ3 activation through interfering with PAC-1 binding stimulated by collagen. In addition, pterostilbene affected integrin αIIbβ3-mediated outside-in signaling, such as integrin β3, Src, and FAK phosphorylation, and reduced the number of adherent platelets and the single platelet spreading area on immobilized fibrinogen as well as thrombin-stimulated fibrin clot retraction. Furthermore, pterostilbene substantially prolonged the occlusion time of thrombotic platelet plug formation in mice. This study demonstrated that pterostilbene exhibits a strong activity against platelet activation through the inhibition of integrin αIIbβ3-mediated inside-out and outside-in signaling, suggesting that pterostilbene can serve as a therapeutic agent for thromboembolic disorders. 相似文献