Atomic layer deposition of thin films of ZnSe—structural and optical characterization

Thin films of sphalerite-type ZnSe were grown by atomic layer deposition (ALD) from elemental Zn and Se precursors. These films, grown on various substrates, show bright blue ‘edge’ emission accompanied by donor-acceptor pair emissions in the blue, green and red spectral regions. Red, green and blue emissions mixed together give a white color, with a color temperature between 2400 and 4500 K depending on a layer thickness and temperature. ZnSe grown by ALD is in consequence a promising material for the fabrication of semiconductor-based white light emitting thin film electroluminescence displays.     

枪黑色Sn-Ni合金在NaOH溶液中的析氢电催化性能

为了降低电解制氢的电耗,提高经济效益.作者对枪黑色Sn-Ni合金在NaOH溶液中的析氢电流化性能进行了研究.试验测出的电化学参数表明,在NaOH溶液中电解制氢时,枪黑色Sn-Ni合金的析氢电催化性能比45钢和高硫镍的强很多,而且具有很高的电化学稳定性.用它取代目前工业上使用的45钢和高硫镍作为电解制氢的阴极,可显著降低制氢的生产成本.     

两种不同焊丝对7A05铝合金焊接性的影响

选择两种焊丝,对Al Zn Mg系合金7A05 T6进行焊接性研究。焊接裂纹试验结果表明,采用两种焊丝焊接7A05合金时,接头均具有较好的抗热裂纹敏感性。两种焊丝焊接接头的拉伸强度均为母材强度的75%以上,经过时效处理的焊接接头力学性能有了明显的提高。分析认为微观组织中沉淀物质点越小,均匀分散到晶界上越多,接头的拉伸强度越高。     

Annealing process of fine grained co-stabilised (Y,Mg)-PSZ/MgAl2O4 ceramics

Abstract

Co-stabilised (Y,Mg) partially stabilised zirconia (PSZ) ceramics with MgAl₂O₄ spinel additions were produced, with industrial zirconia as the main starting material. Powders were prepared using a mechanical milling–mixing process. The effect of the annealing process on the mechanical properties, phase compositions, and microstructure of fine grained PSZ ceramics was investigated.     

ZnCl2-assisted Synthesis of ZnSe Polycrystal

A chemical-assisted element direct-reaction method is developed to synthesize ZnSe compound semiconductor material at a relatively low temperature (～1000 C). ZnSe polycrystal was obtained in the closed-tube systems with Zn-Se, Zn-Se-Zn(NH3)2Cl2, Zn-Se-NH4Cl and Zn-Se-ZnCl2. The as-synthesized samples were tested by X-ray diffraction (XRD), thermogravimetric analysis (TGA) and analyzed by thermodynamic numerical method. The results demonstrate that the synthesis efficiency is higher than 99.96% for Zn-Se-ZnCl2 system at around 1000 C for 3 weeks. It also exhibits that not only temperature, but also low apparent ratio of volume and surface area of the source materials and higher ZnCl2 content are required to achieve high synthesis efficiency. A SeCl transporting reaction synthesis process is proposed based on the thermodynamic analysis.     

铝合金熔剂的研究

本文介绍了熔剂在铝合金熔炼过程中的作用,熔剂的分类和要求,常用熔剂的组成,适用范围及使用方法等。     

Mg-Ca-Mn、Mg-Ca-Sr三元生物镁合金制备与研究

为了改善Mg-Ca二元生物镁合金的力学性能和体外降解性能,分别制备了Mg-Ca-Mn和Mg-Ca-Sr三元合金,比较了3种合金的显微组织、力学性能及在Hanks溶液中的降解性能.实验结果表明,Mg-Ca-Sr合金的力学性能和体外降解性能较好,抗拉强度为230MPa,析氢腐蚀速率为0.042 mL/(d·cm2).     

铝合金表面搅拌摩擦加工技术的研究进展(Ⅰ)

以搅拌摩擦加工原理为基础,概述了近年来铝合金表面搅拌摩擦加工处理中的细化晶粒与消除铸件内部缺陷的应用,分析了该技术用于铝合金性能(如表面硬度、强度、耐磨性能和超塑性等)改善的机理,展望了搅拌摩擦加工技术在铝合金表面处理中的应用前景。     

55t均火炉的温度检测及铸锭均火工艺参数确定

介绍新建的均匀化退火炉的空炉温度和带料温度测试,以及铸锭均火工艺参数的制定方法,并指出确定铸锭均火工艺参数的原则。     

Zn对AB5型贮氢合金的影响

研究了Zn替代Co对AB5型MlNi3.6Mn0.4Al0.3Co0.7贮氢合金相结构和电化学性能的影响。Zn替代Co使合金的晶胞参数和体积增大,导致贮氢合金最大放电容量增加,循环稳定性有所下降;随着Zn含量由0增加到0.5,氢的扩散系数由0.31×10-7m2/s增加到3.72×10-7m2/s,交换电流密度由157 mA/g增加到191 mA/g,合金极化电阻由1.23Ω减少到1.01Ω,合金表面电催化活性和高倍率性能得到了改善。