Effect of organoclay structure on nylon 6 nanocomposite morphology and properties

A carefully selected series of organic amine salts were ion exchanged with sodium montmorillonite to form organoclays varying in amine structure or exchange level relative to the clay. Each organoclay was melt-mixed with a high molecular grade of nylon 6 (HMW) using a twin screw extruder; some organoclays were also mixed with a low molecular grade of nylon 6 (LMW). Wide angle X-ray scattering, transmission electron microscopy, and stress-strain behavior were used to evaluate the effect of amine structure on nanocomposite morphology and physical properties. Three surfactant structural issues were found to significantly affect nanocomposite morphology and properties in the case of the HMW nylon 6: decreasing the number of long alkyl tails from two to one tallows, use of methyl rather than hydroxy-ethyl groups, and use of an equivalent amount of surfactant with the montmorillonite, as opposed to adding excess, lead to greater extents of silicate platelet exfoliation, increased moduli, higher yield strengths, and lower elongation at break. LMW nanocomposites exhibited similar surfactant structure-nanocomposite behavior. Overall, nanocomposites based on HMW nylon 6 exhibited higher extents of platelet exfoliation and better mechanical properties than nanocomposites formed from the LMW polyamide, regardless of the organoclay used. This trend is attributed to the higher melt viscosity and consequently the higher shear stresses generated during melt processing.     

基于任务驱动的外训图像处理课程教学实践

从军校外训教学特点出发,结合课程设计,介绍了任务驱动教学法在外训Photoshop课程中的具体运用。在任务驱动教学法的理论依据、案例的设计、案例教学的实施等方面作了研究,在如何将理论与实践相结合进行设计上,进行了尝试并取得较好效果。     

费托合成熔铁催化剂对液体产物的影响

实验考察了温度、压力、H2/CO和空速等不同操作条件对固定床熔铁催化剂费托合成液态产物的影响,得出了液态产物在不同操作条件下的时空产率、烃类产率、含碳量(C5～C13)、烯烷比及正构烷烃与支链烷烃(正支比)的一些变化规律。     

铸铝合金在有机羧酸体系中电化学陶瓷成膜

利用电化学沉积陶瓷膜（EDCF）技术将铸铝ZL108合金置于有机羧酸复合体系，制得了具有较高硬度和良好外观的灰色类陶瓷膜。详细研究了各工艺参数对膜层性能的影响，结果表明，有机羧酸是主要成膜物质；金属硫酸盐是阳极反应的活化剂，但浓度过高会加快膜层溶解；方波脉冲电源有利于生成厚膜；峰值电流密度越大，成膜时间越短，但过大会使膜层减薄；溶液pH值、搅拌等对成膜过程有一定影响。     

异向旋转双螺杆挤出机的发展前景

本文通过分析螺杆在不同区段的几何特征及其对相应加工阶段的影响对平行和锥形双螺杆挤出机进行了全面的比较。     

Pressureless low temperature sintering of nanocrystalline zirconia ceramics via dry powder processing

Pressureless sintering approaches provide a simple avenue to manufacture dense ceramic parts with minimal processing equipment, but current pressureless sintering techniques have yet to demonstrate capabilities of producing dense ceramics while maintaining sub-50 nm grain sizes. Nanocrystalline yttria stablized zirconia ceramics were process from 4 mol% yttria stablized zirconia (4YSZ) nanopowders with a crystallite size of 7.5 nm using dry cold isostatic pressing (CIP) where powders are dried immediately prior to green compact formation and CIP vacuum bagging. It is shown that CIP pressures >75 000 psi (517 MPa) effectively remove pores larger than 100 nm and that pressureless sintering occurs at reduced temperatures for green densities ≥50%. Though the sintering kinetics are shown to be similar to other zirconia nanopowder sintering studies, the small initial crystallize size and reduced sintering temperature allowed densities as high as 97.2%, while retaining a ceramic grain size at or below 40 nm. Produced nanocrystalline 4YSZ ceramics with a grain size of 30.3 nm and a density of 96.3% had Vicker's hardnesses as high as 14.2 GPa and Vicker's indentation fracture resistance of 3.43 MPa·, demonstrating that simple processing approaches can be refined to fabricate nanocrystalline ceramics while maintaining high hardness and indentation fracture resistance.     

采用支持向量回归抑制噪声的经验模态分解方法

在实际信号分解中,经验模态分解（ EMD）是对噪声敏感的,往往会分离出一些虚假的本征模函数,对信号的分析产生一定影响。为了提高EMD分解的正确率,减少其出现虚假本征模函数的情况,文中提出了一种基于支持向量回归（ SVR）的去噪方法。先对一次EMD分解结果进行SVR逐层滤波并且对信号进行重组,然后利用EMD方法对重组信号进行二次分解。实验表明,二次分解结果已经非常接近于理想的分解结果,不会出现虚假IMF。这种分解方法对噪声不敏感,能有效提高EMD方法对噪声的容忍度。     

A social interaction system based on cloud computing for mobile video telephony

As the use of smartphones become popular,people heavily depend on smartphone applications to deal with their social activities.For this reason,traditional message texting between mobile applications does not fulfill the versatile requirements of social networking.Many mobile applications use multimodality to deliver multimedia messages including sticker,voice and photo message,video call,and snap movie to enhance the communicative capability.However,without face-to-face interaction,people may fail to detect the other side’s non-verbal social behavior such as fine-grain facial expressions,body movements,or hand gesture.During social interaction,non-verbal behavior conveys information about the involved individuals and help the speakers express their social emotion in an implicit way.It is so important for real-world face-to-face interaction but is often blocked on the mobile telephony.To cope with this problem,we propose an afective computing model to assist the representation of social emotion and then help the progress of social interaction on the mobile telephony.In this model,for the purpose of real-time afective analysis,we delegate the computing loading to the cloud side service and enhance the system’s scalability and availability.The result of this experiment approves the feasibility of our system design for the applications of social intelligent.Also,the system provides a research framework of the social intelligent system on the mobile telephony.     

Low-complexity optimal spatial channel pairing for AF-based multi-pair two-way relay networks

This paper considers a multi-pair two-way relay system with multi-antenna users and proposes a low-complexity optimal spatial channel pairing （SCP） strategy at the relay station （RS） for such a system. The proposed SCP scheme, following the BD-like beamformer at RS, pairs the uplink spatial subchannels of each user pair with the corresponding downlink spatial subchannels by maximizing sum-rate （Max-SR）. Furthermore, a new mathematical inequality （arrangement inequalities of a product） is developed and applied to obtain sufficient and necessary conditions for achieving Max-SR-SCP. This also yields a simple low-complexity implementation of the proposed SCP in contrast to the NP-hard complexity of the original Max-SR-SCP problem. Simulation results illustrate that the proposed Max-SR-SCP achieves substantial sum-rate gains over other pairing schemes.     

电解铝厂整流变电所直流大母线施工技术

介绍电解铝工艺设备中直流汇流母线的加工和安装施工技术.