Synergistic Influence of Poly(4-Vinylpyridine) and Potassium Iodide on Inhibition of Corrosion of Mild Steel in 1M HCl

The corrosion and inhibition behavior of mild steel in 1 M HCl in the presence of poly(4-vinylpyridine)(P4VP) and potassium iodide (KI) was investigated using weight loss measurements, potentiodynamic polarization studies and impedance measurements. The inhibition efficiency increased with increasing P4VP concentration. The inhibiting action of P4VP is considerably enhanced by the addition of potassium iodide. The adsorption of this compound either alone or in combination with iodide ions on the metal surface is found to obey Lamgmir's adsorption isotherm. The experimental results suggest that the presence of iodide ions in the solution increases the surface coverage and, therefore, indicate the joint adsorption of P4VP and iodide ions. On the other hand, it was found that the inhibiting effect of P4VP and (P4VP + KI) increased with increasing temperature of the corrosion medium. The presence of these species in the solution decreases the double layer capacitance and increases the charge transfer resistance, both derived from Nyquist plots obtained from a.c. impedance studies. The variation of charge transfer resistance with time suggests that the inhibitive action of (P4VP + KI) depends mainly on the protective inhibitor film formed on the steel surface.     

汽车工业生产用热熔胶膜的研制

介绍了汽车工业生产内装饰复合材料用热熔胶膜的性能及其研制状况。这种热熔胶膜具有使用便捷,高效,生产、使用过程中没有污染的具有热熔胶膜的特长。     

不锈钢转化器在中小型硫酸装置上的应用前景

分析了传统碳钢转化器存在的缺点。相对于碳钢转化器，不锈钢转化器具有结构简单、安装方便、耐高温、不易漏气、维护工作量小等优点。通过碳钢转化器和不锈钢转化器结构和造价的比较，表明不锈钢转化器在中小型硫酸装置中也有良好的应用前景。     

Polyaniline for corrosion prevention of mild steel coupled with copper

Polyaniline emeraldine base/epoxy resin (EB/ER) coating was investigated for corrosion protection of mild steel coupled with copper in 3.5% NaCl solution. EB/ER coating with 5-10 wt% EB had long-term corrosion resistance on both uncoupled steel and copper due to the passivation effect of EB on the metal surfaces. During the 150 immersion days, the impedance at 0.1 Hz for the coating increased in the first 1-40 days and subsequently remained constant above 10⁹ Ω cm², whereas that for pure ER coating fell below 10⁶ Ω cm² after only 30 or 40 days. Immersion tests on coated steel-copper galvanic couple showed that EB/ER coating offered 100 times more protection than ER coating against steel dissolution and coating delamination on copper, which was mainly attributed to the passive metal oxide films formed by EB blocking both the anodic and cathodic reactions. Salt spray tests showed that 100 μm EB/ER coating protected steel-copper couple for at least 2000 h.     

Bulk and Interphase Effects in Aged Structural Joints

Although structural adhesives are becoming widespread in numerous applications, one important limitation at present is the long term behaviour of bonded assemblies under conditions of high humidity, especially at elevated temperatures. This study presents a comparison between bulk properties of a structural epoxy resin and its behaviour in a torsional joint consisting of a hollowed-out cylinder bonded to a plate—both substrates being in stainless steel. Exposure to ca. 100% relative humidity at 70°C leads to modification of the bulk properties of the polymer, notably reduction of its elastic modulus. Although this may explain some differences in behaviour of the torsional joint, premature failure is attributed to weaknesses in the interphase zone.

Auger Electron Spectroscopy (AES) has been employed to investigate both unbonded steel surfaces and fracture zones. Although prolonged exposure to water leads to a more extensive degree of (apparently) adhesive failure at the interface polymer/metal, AES has shown the presence of non-negligible quantities of carbon, attributed to residual polymer. Failure would seem to occur, at least partly, in a weak interphase of the polymer, near, but not at, the interface.

Various possible causes are evoked. For dry failure, residual polymer may be due to the topography of the metal surface and/or local modification of the adhesive during cure. In the case of aged joints, in addition there are potential effects due to swelling and differential stresses, secondary bond failure and molecular chain scission within the polymer, all provoked by the presence of water.     

Effect of fretting amplitudes on fretting wear behavior of steel wires in coal mines

Given that fretting wear causes failure in steel wires, we carried out tangential fretting wear tests of steel wires on a self-made fretting wear test rig under contact loads of 9 and 29 N and fretting amplitudes ranging from 5 to 180 μm. We observed morphologies of fretted steel wire surfaces on an S-3000N scanning electron microscope in order to analyze fretting wear mecha-nisms. The results show that the fretting regime of steel wires transforms from partial slip regime into mixed fretting regime and gross slip regime with an increase in fretting amplitudes under a given contact load. In partial slip regime, the friction coefficient has a relatively low value. Four stages can be defined in mixed fretting and gross slip regimes. The fretting wear of steel wires in-creases obviously with increases in fretting amplitudes. Fretting scars present a typical morphology of annularity, showing slight damage in partial slip regime. However, wear clearly increases in mixed fretting regime where wear mechanism is a combination of plastic deformation, abrasive wear and oxidative wear. In gross slip regime, more severe degradation is present than in the other regimes. The main fretting wear mechanisms of steel wires are abrasive wear, surface fatigue and friction oxidation.     

GCr15轴承钢连铸过程中热物性参数的研究

借鉴前人实验数据,采用一定的数学方法,对轴承钢的热物性参数进行了研究.结果表明：GCr15轴承钢的液相线温度为1 465.7℃,固相线温度为1 328.4℃,零强度温度为1 380℃左右,零塑性温度为1 330℃左右;在固相区、液固两相区、液相区分别采用不同的公式进行处理,可使结果更加准确,还避免了奇异性.研究结果可为轴承钢连铸工艺有限元模拟提供基础.     

混炼硅橡胶的配合技术(八)

介绍了2种汽车部件（密封图、汽车挡风玻璃刮片）装配用混炼硅橡胶的配制，以及硫化过程中能与接触基材粘接的混炼硅橡胶（通过添加各种增粘剂如含乙烯烃碳酸酯基或巯基乙酸酯基化合物、烷氧基硅烷、含乙烯基硅官能基过氧化物为硫化剂）的配制。     

Intergranular oxidation of silicon in 20Cr-25Ni niobium-stabilized stainless steel at 1140–1230 K

The kinetics of intergranular oxidation of silicon in a 20Cr-25Ni Nb-stabilized stainless steel are reported, at temperatures in the range 1140–1230 K, in CO₂ at 40 bar pressure. The depth of attack increased parabolically with respect to time, with an activation energy of 335±30 kJ/mol. The mechanism of growth is discussed in terms of classical internal-oxidation theories, and an alternative explanation based on an available-space theory is developed. The internal oxidation rates in a number of different alloys are compared with diffusivities of metals in the base alloy. It is proposed that intergranular oxidation in the 20–25 Nb steel is controlled by the rate of outward diffusion of iron or chromium in the alloy.     

Effects of laser heat treatment on the fracture morphologies of X80 pipeline steel welded joints by stress corrosion

The surfaces of X80 pipeline steel welded joints were processed with a CO2 laser, and the effects of laser heat treatment （LHT） on H2S stress corrosion in the National Association of Corrosion Engineers （NACE） solution were analyzed by a slow strain rate test. The fracture morphologies and chemical components of corrosive products before and after LHT were analyzed by scanning electron microscopy and energy-dispersive spectroscopy, respectively, and the mechanism of LHT on stress corrosion cracking was discussed. Results showed that the fracture for welded joints was brittle in its original state, while it was transformed to a ductile fracture after LHT. The tendencies of hydrogen-induced corrosion were reduced, and the stress corrosion sensitivity index decreased from 35.2% to 25.3%, indicating that the stress corrosion resistance of X80 pipeline steel welded joints has been improved by LHT.