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排序方式: 共有10000条查询结果,搜索用时 15 毫秒
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《International Journal of Hydrogen Energy》2020,45(8):5367-5374
High-entropy alloys (HEAs), as a new class of metallic materials, have received more and more attention due to its excellent mechanical properties. In this study, the hydrogen absorption properties, such as hydrogen absorption capacity, thermodynamics, kinetics and cyclic properties, as well as the hydride structure of a newly designed TiZrNbTa HEA were investigated. The results showed that multiple hydrides including ε-ZrH2, ε-TiH2 and β-(Nb,Ta)H were found in the TiZrNbTa HEA after hydrogenation. With the increase of temperature from 293 K to 493 K, the maximum hydrogen absorption capacity decreased from 1.67 wt% to 1.25 wt% and the plateau pressure related with β-(Nb,Ta)H hydrides increased from 1.6 kPa to 14.8 kPa. The formation enthalpy of β-(Nb,Ta)H hydride was determined to be −6.4 kJ/mol, which was less stable than that of NbH and TaH hydrides. The results also showed that the TiZrNbTa HEA exhibited a rapid hydrogen absorption kinetic even at the room temperature with a short incubation time, and the hydrogen absorption mechanism was determined to be the nucleation and growth mechanism. Moreover, the hydrogen absorption capacity at 293 K decreased slowly with the cycle numbers, and remained 86% capacity after 10 cycles. Cracking occurred after hydrogen absorption and became worse with cycles. 相似文献
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15.
Preparation and properties of nano-sized SnO2 powder 总被引:2,自引:0,他引:2
1 INTRODUCTIONSnO2isoneofthemainmaterialsusedingassensor.Becauseofthehumidityandgassensingfunction,itattractsmoreandmoreattentions.Butthepresentproblemishowtoimprovethestabilityandsensibilityofgassensor.Researchershavetakenmanymeasurestoresolvethisproble… 相似文献
16.
S V Bhat 《Bulletin of Materials Science》1994,17(7):1271-1285
When examined using continuous wave electron paramagnetic resonance and nuclear magnetic resonance spectrometers, the highT
c superconductors give rise to intense, low field, ‘non-resonant’ absorption signals in the superconducting state. This phenomenon
can be used as a highly sensitive, contactless technique for the detection and characterization of superconductivity even
in samples containing only minute amounts of the superconducting phase. Further, it can also be applied to the determination
of material parameters of interest such asJ
c andH
c2 in addition to being a powerful way of distinguishing between weak-link superconductivity and bulk superconductivity. The
details of these aspects are discussed. 相似文献
17.
V S R Murthy 《Bulletin of Materials Science》1993,16(2):87-108
Research and development efforts on high-temperature, oxidation-resistant fibres have increased over the past decade due to
the demand for light-weight, stiff and strong composite materials in aerospace applications. Varieties of ‘high-performance’,
continuous, non-oxide fibres with low-density, high tensile strength and tensile modulus have been developed either from organic
precursors or via chemical vapour deposition for fabrication of ceramic matrix composites. Fibres derived from polymer precursors
(e.g. Nicalon, Tyranno, HPZ) are small in diameter (compared to CVD monofilaments) and are ideally suited for ceramic composites.
Processing, microstructural stability and mechanical properties of these newly developed SiC and Si3N4 base fibres are briefly reviewed in this paper. 相似文献
18.
超细Fe3O4粒子表面包覆酞菁钴性质研究 总被引:3,自引:1,他引:2
本文研究了合成载氧体的金属有机化学液相淀积法制造工艺,所得产物经TEM、XPS、Moss-bauer谱和B-H仪等手段,研究了它的结构和磁性能。实验表明,酞青钴以薄层形式包覆在Fe_3O_4的表面,封闭了Fe_3O_4的表面孔洞,稳定了Fe_3O_4的物相,增强了磁性能。 相似文献
19.
油田污水中咪唑啉缓蚀剂浓度检测技术研究 总被引:5,自引:0,他引:5
研究评价了油田污水中咪唑啉缓蚀剂浓度检测的七种方法 ,其中紫外光分析法和显色反应法适合于低浓度咪唑啉缓蚀剂检测 ,且方法简便、速度快、成本低 ,检测浓度范围 2~ 5 0mg/L。 相似文献
20.