弱凝胶调驱降维数值模拟方法研究

目前用于弱凝胶调驱的化学驱软件大多存在计算速度慢、数值弥散现象严重的问题,为了提高弱凝胶调驱数值模拟的速度和精度,提出了降低维数的模拟方法。利用追踪流线的方法,将弱凝胶调驱的三维渗流问题,转化为沿流线计算饱和度的一维问题,大大降低了求解饱和度方程组中方程的数目,从而提高了计算速度。利用该方法,模拟了玉门老君庙油田一个试验井区的水驱开发历史,优化了弱凝胶调驱的注入浓度、注入速度及注入体积等参数,并预测了弱凝胶调驱的动态,预测该方案可提高采收率7.6%。     

An integrated system of biological and catalytic oxidation for the removal of o-xylene from exhaust

Biofiltration is an efficient technology for treatment of gaseous waste. Its disadvantages, however, include large volume of bioreactor and slow adaptation to fluctuating concentrations in waste gas. Catalytic oxidation offers a high destructive efficiency at relatively low operating temperature and small unit. A bench scale system integrated with a biofilter and a catalytic oxidation unit for the treatment of gases containing o-xylene was investigated in this study. The catalytic oxidation unit was packed with Cu/Al₂O₃ catalyst. The results showed that 90% of o-xylene could be removed in the biofilter at the load below 38.2 g m⁻³ h⁻¹. High o-xylene concentration in inlet gas resulted in an overload of the biofilter. Using the Cu/Al₂O₃ catalytic oxidation unit, the concentration of o-xylene could be reduced evidently. The combination of the chemical and microbial processes not only led to a high and stable efficiency of o-xylene conversion, but also improved capacity resisting the shock loads. The Cu/Al₂O₃ was studied for o-xylene oxidation in temperature range of 90–320 °C. The o-xylene conversion was improved correspondingly with the increasing of oxidation temperature. The reaction mechanism of o-xylene oxidation on Cu/Al₂O₃ was also investigated using diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS).     

40Cr钢复合热处理强韧化

用光学及电子显微镜(SEM.TEM)观察不同热处理的40Cr 钢的冲击及断裂韧性断口、及金相组织,阐明其间相互关系;断口结构可反映断裂特征,组织情况;细化晶粒提高强度、塑性和冲击韧性,但却减少脆断的特性距离 l 因而降低 K_(1c)模;减少碳(杂质)偏聚而使其呈较均匀地分布,从而减少可诱发塑坑的较粗大的碳(杂质)化合物的析出,即增加塑坑的间距 di 以及增加塑断组成物。从而都可增加断裂临界应变 ef,都可以提高 K_(1c)40Cr 复合热处理既靠先超高温淬、回火以减少碳(杂质)偏聚,改善其分布,以反增加位错马氏体从而提高 K_(1c),也靠后淬、回火细化晶粒而提高强度、塑性和冲击韧性,各自发挥长处达到强韧化。     

Synthesis and activation of Pt nanoparticles with controlled size for fuel cell electrocatalysts

Well-dispersed Pt nanoparticles with controlled size and narrow size distribution were prepared by polyalcohol reduction of platinum acetylacetonate, using oleylamine as a capping agent. The particle size was varied from 3.5 nm to 11.5 nm by decreasing the amount of oleylamine added in the synthesis. Size selection of the as-prepared particles by solvent fractionation yielded nearly monodispersed Pt particles. The as-prepared particles were loaded on a carbon support by physical deposition, but showed no electrocatalytic activity due to the oleylamine bound to the particle surface. The particles were activated for electrocatalysis after heating the particles in air at 185 °C for 5 h, conditions that gave no particle-sintering and no oxidation. Cyclic voltammetry showed that the particles after the heat treatment in air were electrocatalytically active for methanol oxidation. The smaller 3.5 nm and 4.0 nm Pt particles had a higher intrinsic activity for methanol oxidation, but a lower tolerance to CO poisoning, compared with 6.0 nm, 9.5 nm and 11.5 nm particles. CO-stripping results suggest that CO is more easily oxidized on larger Pt particles.     

酶法提取树莓汁的研究

本试验以澳洲红、早红、美国22三个品种树莓为原料，通过不同的酶处理方法来制原果汁，优选适于制汁的品种和酶处理方法。     

超高相对分子质量聚乙烯纤维研究进展

介绍了超高分子质量聚乙烯纤维的制备、表面改性及应用的研究进展 ,指出了今后超高分子质量聚乙烯纤维的研究及应用的发展方向     

Electrical and optical studies of ZnO:Ga thin films fabricated via the sol–gel technique

The effects of dopant (Ga) concentration, post-heat treatment temperatures, and different heat treatment environments on the morphology, electrical and optical properties of ZnO films were studied. ZnO films doped with Ga are derived from non-alkoxide zinc acetate via the alcoholic route by a sol–gel dip-coating technique. Introduction of Ga, as a dopant, can reduce crystallite size, which is attributed to the increased number of nucleation centers. Grain growth was also observed at high post-heat treatment temperature. It was discovered that different post-heat treatment environments (air or reduced atmosphere) did not change the structure orientation, microstructure shapes and size. It was found that the sheet resistance, R_s could be reduced by an order of magnitude, using post-heat treatment in reduced atmosphere (4%H₂–96%N₂).     

胍基聚合物的合成及抗菌性能

采用熔融缩聚的方法合成了聚亚己基胍盐酸盐（PHGC）及聚亚己基双胍盐酸盐（PHBG）。应用气相渗透压法（VPO）及粘度法测定了其分子质量，应用元素分析，FT－IR，XPS分析了聚合物的化学组成，抗菌活性的研究结果表明所合成的胍基聚合物具有较强的而且广谱的抗菌性能。     

超细氧化锌粉体的制备及尺寸控制

根据气相化学反应法 (CAD)制备超细粉的原理 ,从低品位氧化锌矿中采用火法冶金方法直接制备超细氧化锌粉 ,对所得氧化锌的粒度尺寸、微观结构和粒度分布进行测试 ;考察了冷却强度以及收集装置对超细氧化锌粒度及粒度分布的影响 ;讨论了氧化锌粉体团聚的原因及对策、试验条件对氧化锌尺寸的控制等     

注硼中子寿命测井注硼工艺优化设计

注硼中子寿命测井是一项水淹层测井新技术 ,对老油田的产层分析评价、剩余油含量估算等方面发挥了重要的作用。但测井施工时 ,往往由于注硼工艺不当导致硼酸的渗吸量难以准确反映地层可动水的含量 ,从而产生解释上的困难和误区。在渗流与扩散理论相结合的基础上 ,结合华北油田的施工实践 ,介绍了确定注硼管柱、硼酸用量、注硼压力以及硼酸扩散时间的基本原则和实际经验 ,为工艺的优化设计提供了一些方法与思路