石墨电极炼钢时受力状态的有限元研究

采用有限元法对比研究了φ５００ｍｍ的日本电极和国产电极炼钢时电极－接头连接区的热应力分布，对结果进行了分析和讨论，并提出了相应的结论和建议。     

油田采出水的精细过滤技术

低渗透油层渗透率〈0．1μm^2，孔喉半径小，容易被堵塞，对注入水质要求高，目前缺乏对含有原油、化学添加剂、粉质颗粒和无机盐的油田采出水适应性强的精细过滤设备。本文介绍了油田采出水回注精细过滤材料试验和采用旋流配水、脉冲水流反洗技术的改性聚四氟乙烯滤芯过滤装置的小试和中试研究情况，研究开发的改性聚四氟乙烯精细过滤装置，当进水含油量〈20mg／L、悬浮物含量〈20mg／L时，出水达到了（《碎屑岩油藏注水水质推荐指标》（SY5329-94）规定的A1级注水水质标准。     

加快创新开发,开拓聚氯乙烯压力管道系统的新局面

近年来聚氯乙烯管道取得了重大进步。PVC-M管材(改性聚氯乙烯管材)、PVC-O管材(取向聚氯乙烯管材)兼有非凡的强度和韧度,和传统的硬聚氯乙烯管材比可以采用较高的设计应力,显著地节约材料。     

超磁致伸缩作动器的率相关Hammerstein模型与H∞鲁棒跟踪控制

利用Hammerstein模型对超磁致伸缩作动器（Giant magnetostrictive actuators,GMA）的率相关迟滞非线性进行建模,分别以改进的 Prandtl-Ishlinskii（Modified Prandtl-Ishlinskii）模型和外因输入自回归模型（Autoregressive model with exogenous input,ARX）代表Hammerstein模型中的静态非线性部分和线性动态部分,并给出了模型的辨识方法. 此模型能在1～100Hz频率范围内较好地描述GMA的率相关迟滞非线性. 提出了带有逆补偿器和H∞鲁棒控制器的二自由度跟踪控制策略,实时跟踪控制实验结果证明了所提策略的有效性.     

Electrochemical study of the chromium electrode behaviour in borate buffer solution

The electrochemical behaviour of the chromium electrode in borate buffer solution (pH 9.3) was studied by cyclic voltammetry and electrochemical impedance spectroscopy. Chromium passivity was observed over a broad potential region, from –1.0 to 0.5 V vs SCE. The passivation process took place in two steps: formation of a chromium oxide monolayer and transition of chromium to a higher valence state. The anodic film exhibited the properties of a p-type semiconductor. Transpassive dissolution of chromium occurred at 0.5 V vs SCE, with two reaction intermediates present, Cr_Cr ^III and Cr_ad ⁴⁺.     

高性能自干型汽车用面漆的研制

用酯化法制得高性能丙烯酸改性醇酸树脂,并用该树脂配制成施工方便,干燥迅速,抗回黏性、耐沾污性、耐候性及耐油性好的单组分汽车涂料。介绍了该树脂及涂料的配方设计、生产工艺和产品性能。     

Modelling of copper etching in aerated chloride solutions

The effect of dissolved oxygen on the rate of chemical etching of copper by acidic cuprous chloride solution was investigated numerically for the case of a rotating disc electrode (RDE). Copper dissolution in aerated acidic cupric chloride solutions of composition 3.5M CuCl2 + 0.5M HCl + 0.5M KCl and 3.5M CuCl2+0.5M HCl was investigated with consideration of the instantaneous homogeneous reaction 4CuCl32-+4H++O2rlhar4CuCl 3-+2H2O which takes place within the mass transport boundary layer. It was assumed that CuCl32- and O2 react instantaneously, resulting in the formation of a reaction plane which separated the mass transport boundary layer into two regions: a region adjacent to the electrode where oxygen was depleted, and a region adjacent to the bulk where CuCl32- was absent. A one-dimensional mathematical model was developed to predict the position of the reaction plane. The model accounted for diffusion, migration and fluid flow generated by an RDE and included nine species and five heterogeneous electrochemical reactions. The homogeneous redox reaction served to regenerate the chemical etchant solution and thus enhance the etch rate. With increasing oxygen concentration and rotation rate the reaction plane was found to move closer toward the electrode and thus the etch rate of copper increased. Addition of KCl increased the Cl- content in solution so as to shift the reaction plane toward the bulk.     

苯酚改性脲醛树脂合成工艺及性能的研究

用苯酚作为改性剂,采用高温(90℃)缩聚反应合成改性脲醛树脂胶粘剂,改进了合成工艺,缩短了反应时间。通过引入苯环改善了耐水、耐老化性能。分析了各因素对改性脲醛树脂的影响,得到甲醛、尿素、苯酚摩尔比为10:8:1时树脂性能最佳,胶合强度和木破率均达到GB／T 17656-1999标准规定值。     

无烟超薄型钢结构防火涂料的研制

介绍了无烟超薄型钢结构防火涂料的研制方法,将纳米有机-无机硅系阻燃剂应用到超薄型钢结构防火涂料中,改善了以往防火涂料单一使用APP阻燃剂而大量产生浓烟及有毒气体的缺陷。该防火涂料具有较好的耐火性能和装饰性能。     

变性淀粉取代聚乙烯醇生产Al2O3刚玉陶瓷的胶粘剂研究

论述了变性淀粉取代聚乙烯醇(PVA)生产Al2O3刚玉陶瓷的意义及聚乙烯醇结构与吸附性能的关系，并且根据胶粘机理，通过分析Al203胶粒的表面特性和变性淀粉的结构，说明了变性淀粉可以取代聚乙烯醇。