Phase behavior in liquid crystallization for diblock copolymers consisting of rubbery amorphous and side-chain liquid crystalline components

Phase behavior in liquid crystallization was studied for a series of liquid crystalline (LC) diblock copolymers consisting of rubbery amorphous and side-chain liquid crystalline components, poly(n-butyl acrylate) (PBA) and poly[11-(4′-cyanophenyl-4″-phenoxy)undecyl acrylate] (PLC), respectively, using a time-resolved small-angle X-ray scattering (SAXS) techniques, DSC and polarized optical microscopy (POM). The block copolymers used had three kinds of copolymer compositions, 44, 20 and 15 wt% of PLC compositions (BLC44, BLC20 and BLC15, respectively). BLC44 showed a smectic liquid crystalline structure. In the process of liquid crystallization for BLC44, the SAXS peak due to the microphase separation structure existing before liquid crystallization was changed continuously to be at a smaller angular side, and at almost the same time, a new peak appeared at a further smaller angular side and developed. The former peak disappeared with the development of liquid crystallization. The behavior of these SAXS peaks suggests that the microphase separation structure was changed discretely at the transition from isotropic to smectic and that two phases coexist in the early stage of the liquid crystallization. The coexistence of two peaks in the early stage of the liquid crystallization corresponded to the POM observation. In the isotropization process, coexistence of two phases was not observed. For BLC20 exhibiting a cylindrical structure in both isotropic and liquid crystalline states, the liquid crystalline structure was not smectic but probably nematic, and the spacing was changed continuously in liquid crystallization. No liquid crystallization was observed in SAXS, POM and DSC for BLC15. The orientation of smectic layers within lamellar domains was investigated using 2D-SAXS images. The smectic layer was aligned perpendicularly to the lamellar interface.     

矩形垂直筛板的流体力学性能研究

在600mm的有机玻璃冷模塔中,用水-空气体系测定矩形垂直筛板的塔板压降、漏液和雾沫夹带等流体力学性能,确定了合理的塔板结构,使其具有较高的气液通量和较宽的操作范围,空塔动能因子最大可达3.0kg1/2(m1/2.s)-1,液流强度可达21.6m3/(m.h)。并对不同气液流量下塔板的流体力学实验数据进行关联和分析,得出了矩形垂直筛板的干板压降计算关联式以及漏液率随液流强度和空塔动能因子的变化关系,为矩形垂直筛板的设计提供了依据。与新垂直筛板相比,矩形垂直筛板具有更低的塔板压降。     

18臂机械井径与磁法井径组合测井仪原理及应用

文章主要介绍了18臂机械井径与磁法井径组合测井仪的仪器结构、主要技术特性、测量原理及测井资料在油田中的应用。通过对测井资料的分析，阐述了该仪器在套损检测、补贴效果检查、射孔工程作业效果评价等方面的应用，为油田套管分析提供了可靠的保证。     

Solving the trade-off between fairness and throughput: Token bucket and leaky bucket-based weighted fair queueing schedulers

In this article, we present two efficient weighted fair queueing (WFQ) scheduling algorithms leaned on the well-known token bucket and leaky bucket shaping/policing algorithms. The performance of the presented algorithms is compared to those of the state-of-the-art WFQ approximations such as weighted round robin (WRR) and the recently proposed bin sort fair queueing (BSFQ). Our simulation results show that the proposed algorithms provide a better fairness at a lower implementation complexity while simultaneously achieving a comparable network utilization.     

催化裂化沉降器多臂式旋流快分系统封闭罩内的流场

用智能型五孔探针对催化裂化沉降器内多臂式旋流分离系统封闭罩内的气体流场进行了测试。测试结果表明，罩内流场为轴对称的三维湍流场，在旋流头喷出口处径向速度较大，呈短路流现象。根据流场测试结果，建立了三维气流速度分布的无因次计算式，可供工程设计参考。     

锚索锚杆联合支护在破碎顶板中的应用

结合工程工作面概况，就锚索和锚杆补强加固支护参数的选择进行了介绍，并指出锚索、锚杆的联合支护，保证了顶板的完整性，有效地控制了巷道的变形。     

氧气合理利用决策支持系统和空分装置操作仿真系统

分析了钢铁企业空分系统能源管理的特点 ,并开发出降低空分能耗的应用软件 :氧气合理利用决策支持系统和空分装置操作仿真系统。前者可为决策者提供全面的辅助决策信息和决策支持以降低氧气放散 ,实现氧气的合理利用 ;后者既可实现空分装置运行操作的仿真 ,也可实现空分装置的仿真实验和仿真操作 ,为实施空分装置的节能优化运行提供技术支持     

金的分离富集

综述了金的分离和富集方法，主要包括各种吸附和萃取方法。采用活性炭和泡沫塑料(简称泡塑)吸附分离金是传统的分离富集法，有负载活性炭和有负载泡塑可以提高富集金的能力。近些年，离子交换树脂和离子交换纤维素在分离富集金的应用中，占有相当大的比例。萃取法除了使用传统的MIBK作为萃取剂，又见报道硫醚、亚砜、醇类等作为萃取剂的各种萃取体系。中引用参考献107篇。     

阳平关砂金矿精选厂尾矿综合回收的研究

本文详细的介绍了陕西省阳平关砂金矿精选厂尾矿金和其他可利用的矿物综合回收方法和最佳分选流程。     

注聚采出水分离用动态水力旋流器特性研究

原有的地面工艺和设备已不能满足聚合物驱采出水分离的要求。采用自行研制的动态水力旋流器，在增压与不增压两种工艺流程下，分别进行了流量和转数对分离效率的影响、转数与压力降的关系，以及入口压力与处理量的关系等项试验研究。试验结果表明，与静态水力旋流器相比，动态水力旋流器的分离效率明显提高，一般可提高10％左右；压力损失显著降低，约可减少0．1MPa，足见可在低压下工作，易于实现无泵运行；无泵运行明显比有泵增压运行的分离效率高，但处理量会有所降低。将动态水力旋流器应用于聚合物驱产出水的油－水分离处理是完全可行的。