Leaching of complex sulphide concentrate in acidic cupric chloride solutions

The chemical analysis of a complex sulphide concentrate by emission spectrometry and X-ray diffraction shows that it contains essentially copper, lead, zinc and iron in the form of chalcopyrite, sphalerite and galena. A small amount of pyrite is also present in the ore but does not be detected with X-ray diffraction. The cupric chloride leaching of the sulphide concentrate at various durations and solid/liquid ratios at 100 ℃ shows that the rate of dissolution of the ore is the fastest in the first several hours, and after 12 h it does not evolve significantly. If oxygen is excluded from the aqueous cupric chloride solution during the leaching experiment at 100 ℃, the pyrite in the ore will not be leached. The determination of principal dissolved metals in the leaching liquor by flame atomic absorption spectrometry, and the chemical analysis of solid residues by emission spectrometry and X-ray diffraction allow to conclude that the rate of dissolution of the minerals contained in the complex sulphide concentrate are in the order of galena 〉 sphalerite 〉 chalcopyrite.     

Reaction process of monazite and bastnaesite mixed rare earth minerals calcined by CaO-NaCl-CaCl2

The decomposition reactions of monazite and bastnaesite mixed rare earth minerals calcined by CaO-NaCl-CaCl2 were studied by means of TG-DTA and XRD. The results show that the process of the minerals decomposed by CaO involves two steps. The first step occurs in the temperature range of 425-540 ℃, and the main reactions are bastnaesite decomposition, i.e. REOF reacts with CaO to produce RE2O3 and CaF2, and Ce2O3 is oxidized to CeO2. During this step, CaCO3 is formed at about 500 ℃. The second step takes place in the temperature range of 610-700 ℃, and the reactions are monazite decomposition into RE2O3, Ca5F（PO4）3 and Ca3（PO4）2 by CaO and CaF2. In this process, the decomposition ability is improved because CaO from CaCO3 decomposing has high chemical activity. In calcining process, the new formed Ca5F（PO4）3 restrains fluorine that can escape in form of gaseous compound. The decomposition ratio of the mixed rare earth minerals reaches 90.8% at 700 ℃.     

含锑金精矿碱性硫化钠浸出锑研究与工业实践

为了回收含锑金精矿中的锑，减少锑对两段焙烧过程的影响，对浮选富集得到的含锑金精矿进行硫化钠碱性浸出锑研究。优化实验表明，在液固比1.5:1 (mL/g)，氢氧化钠用量20 g/L，硫化钠用量40 g/L，反应温度80℃，浸出30 min，锑浸出率可达98%以上。在此基础上，采用焙烧炉余热将电解贫液加温至80℃，对液固分离方式、锑电积阴阳极板和冷冻结晶装置进行工艺改造，使锑的浸出率>98%、阴极锑纯度>95%，日产锑量增加17.35%。     

20％磷威乳油（沅化938）的配制

２０％磷威乳油（沅化９３８）是一种以有机磷、氨基甲酸酯类农药为有效成分的新的混配制剂，在防治棉蚜、棉铃虫、棉叶螨等方面的增效作用十分显著。它有击倒快、触杀作用强、广谱等特点。该乳油配方先进，独特，系国内首创。生产工艺简单，易于操作，产品性能稳定。     

固氟氯化铵焙烧法从包头稀土矿中回收稀土的动力学

研究了固氟氯化铵焙烧法分解包头混合型稀土精矿回收稀土的动力学.结果表明:固氟焙砂的氯化反应过程符合Bagdasarym提出的区域反应速率模型,氯化反应过程经过了两个串联反应步骤,且反应生成物的核按一个方向长大;反应速率方程遵从Erofeev方程的串联反应步骤模型,反应表观活化能Ea为36.831 KJ·mol-1,过程控制步骤是内扩散控制.     

厦门城市污泥深度脱水处理及资源化利用研究

结合厦门污水处理厂污泥深度脱水工艺的应用情况,考察了预浓缩—FeC l3和CaO调质—高压隔膜厢式压滤机对污泥的深度脱水效果,并研究了泥饼的处理、处置和资源化利用情况。结果表明,污泥经深度脱水后,泥饼含水率60%,自然放置7 d后,含水率可进一步降至45%左右,满足填埋的要求,另外还可用于制砖和作园林绿化的土壤基质,也可作焚烧处置。污泥深度脱水过程中产生的滤液可循环利用,回流至进水处时,对出水水质影响很小,且可为脱氮过程提供碳源和碱度;回流至重力浓缩池时,可改善污泥沉降性能,提高脱水效率。与传统污泥脱水工艺相比,该工艺具有经济优势。     

水泥搅拌桩帷幕结构在基坑开挖中的应用

以太中银铁路红柳河特大桥为例,对10号承台基坑开挖、支护及降水方案进行了研究,提出了采用水泥搅拌桩止水帷幕结构,并指出该结构在基坑开挖、支护及降水方面的运用。     

谈深基坑内降水井钢制水鼓留置与封堵措施

结合工程实例,提出了在深基坑坑内降水井设置方法及封堵技术措施,并对隔水帷幕止水、基坑内管井降水相结合的技术进行了论述,通过工程案例的应用,证明该方法经济、实用、简单易行,适用于在基础筏板上留置降水井的工程。     

管井降水施工要点分析

结合泰州市中医院工程实例,对管井降水施工中测量放线、泥浆池开挖、吊放井管、潜水泵安装等技术措施进行了研究,并论述了管井降水安全、环保措施,可为类似管井降水施工提供科学可靠的施工方案和依据。     

设备基础开挖及降水施工技术

以具体工程为例,对设备基础坐落的位置和周边环境进行了分析,并对施工方案选择及施工部署进行了阐述,指出采用轻型井点降水的方式进行基坑开挖,解决了工程施工的困难,对周边的环境及地基未造成影响。