废电解液除杂制取硫酸铜和粗镍

介绍了废电解液除杂制取硫酸铜和粗镍的主要工艺条件及试验结果。在废电解液中加入CH80调节pH值到一定范围后,再加入CH64将电解液中Fe2+等杂质除去,铁的去除率可达到94%～98%。然后向滤液中加入CH80调节pH值沉淀铜。过滤后的滤饼用H2SO4溶解后再结晶,可得到CuSO4·5H2O晶体。滤液中加入Na2CO3沉淀镍,过滤后的滤饼即为粗镍(NiCO3)。铜和镍的回收率分别达96%和90%。该流程简单,投资少,效益高,环境保护好,在工业上有较广的应用前景。     

On the permeation rate of copper extraction through liquid membranes

The understanding of the permeation rate of metal ions through liquid membranes is important for the design of such systems. In this paper, the permeation rates of copper ions through liquid surfactant membranes, including interfacial reaction rates and the diffusion rate of the copper ion, were analyzed using a model based on a mobilized hollow spherical globule configuration. The analysis shows that the extracting reaction is dominant at the external interface of the membrane and the stripping reaction is dominant at the internal interface; this means the reactions at both interfaces are not in equilibrium during the course of extraction. It also shows that the extraction rate, the diffusion rate and the stripping rate are not of equal value, especially at the early stage of the run.     

Growth and characterization of barium copper oxalate single crystals in gels

Barium copper oxalate was grown in silica hydrogel at ambient temperature. The effect of various parameters like gel pH, gel density, gel aging and concentrations of reactants on the growth of these crystals was studied. The crystals grown were characterized by chemical analysis, X-ray powder diffractometry, infrared spectroscopy, thermogravimetric and differential thermal analysis. The results of these observations are described and discussed.     

进一步降低钼精矿中铜、铅含量的生产实践

分析了钼精矿Cu、Pb含量高的主要原因 ,通过实施一系列措施 ,达到了降低钼精矿中Cu、Pb含量的目的     

江西铜工业存在的问题及对策探讨

简要介绍了我国铜工业概况，重点分析了江西铜工业存在的问题，并提出发展对策，如优化铜产品结构、利用国内外两种资源和大力发展湿法炼铜等。江西要发挥潜在优势，建立我国铜加工材生产基地，利用外力，提高铜加工材的竞争力，由进口替代逐步走向增加出口。     

Fire performance of wood (Pinus radiata) treated with fire retardants and a wood preservative

In this work, we co‐formulated an oil‐borne copper naphthenate/permethrin wood preservative system with synthetic polymer‐based fire‐retardant additives prior to the impregnation of Pinus radiata sapwood. We evaluated what effect, if any, the preservative had upon the fire performance properties of the fire retardants and whether the fire retardants impacted on the fungicidal and termiticidal efficacy of the preservative. The fire retardants included halogenated and phosphorus‐based systems. A mass loss calorimeter, in conjunction with a thermopile, was used to measure the time to ignition and the peak heat release rate (PHRR) from which the fire performance index (FPI) was determined. The preservative properties were evaluated using termite and soil‐block decay bioassays. In summary, we found that the rate of fire growth was reduced when the fire retardants were used in combination with the wood preservative. We also found that the PHRR was a better determinant of fire performance than the FPI. The performance of the wood preservative was enhanced against fungal decay and termite attack when used in combination with the fire retardants. The fire retardants also demonstrated some wood preservative properties of their own. Copyright © 2008 John Wiley & Sons, Ltd.     

3t电渣钢9Cr2Mo工艺实践

为进一步提高冷轧辊电渣锭的内(外)质量、降低生产成本的要求,贵阳特钢采用400mm×300mm矩形连铸坯取代(φ)330mm铸锭做为电渣母材,在计算机全过程自动控制下,实现1支自耗电极重熔1支3吨电渣锭9Cr2Mo.电渣冶炼的填充比由初期的0.347提高到0.487,电渣锭成锭率由91.17%提高到96.87%,电渣重熔电耗由1762kWh/t下将到1477 kWh/t.     

铜冶炼系统节能降耗与余热利用前景分析

大规模铜冶炼系统的技术改造,可在短期内改变铜厂的面貌,快速提升产品产量,大幅降低铜冶炼的能耗,如何能更深层次地利用好余热资源,是我们研究和发展的方向。     

涟钢连铸优质钢的实践分析

本文介绍涟钢第一炼钢厂１号小方坯连铸机浇铸优质钢的生产实践，并探索连铸优质钢的途径。指出为保证质量，必须严格保证钢水质量，控制合适的浇铸温度，拉坯速度和冷却强度；钢水必须吹氩；采用大容量中间包和伸入式水口保护渣浇涛，确保连铸机的状况良好。     

高铅硫化铜精矿的二段焙烧

高铅硫化铜精矿进行湿法铜铅分离时，焙烧过程因有低熔点组份产生，使培砂中铜浸出率仅为73％～82％，达不到工艺要求。经二段焙烧后消除了上述影响，铜浸出率达到97．4％，实现了铜铅分离。