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71.
72.
In this paper, two brittle fracture problems are numerically simulated: the failure of a ceramic ring under centrifugal loading and crack branching in a PMMA strip. A three‐dimensional finite element package in which cohesive elements are dynamically inserted has been developed. The cohesive elements' strength is chosen to follow a modified weakest link Weibull distribution. The probability of introducing a weak cohesive element is set to increase with the cohesive element size. This reflects the physically based effect according to which larger elements are more likely to contain defects. The calculations illustrate how the area dependence of the Weibull model can be used to effectively address mesh dependency. On the other hand, regular Weibull distributions have failed to reduce mesh dependency for the examples shown in this paper. The ceramic ring calculations revealed that two distinct phenomena appear depending on the magnitude of the Weibull modulus. For low Weibull modulus, the fragmentation of the ring is dominated by heterogeneities. Whereas many cracks were generated, few of them could propagate to the outer surface. Monte Carlo simulations revealed that for highly heterogeneous rings, the number of small fragments was large and that few large fragments were generated. For high Weibull modulus, signifying that the ring is close to being homogeneous, the fragmentation process was very different. Monte Carlo simulations highlighted that a larger number of large fragments are generated due to crack branching. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
73.
Specific interactions in blends containing Chitosan and functionalized polymers. Molecular dynamics simulations 总被引:2,自引:0,他引:2
Chitosan (CS)/poly(vinyl alcohol) (PVA) and Chitosan/poly(2-hydroxyethyl methacrylate) (P2HEM) blends have been studied through molecular dynamic simulations. In a previous work it was found miscibility between these polymers and it was attributed to hydrogen bonding formation. However, the experimental information obtained was not enough to know which of the interacting groups of Chitosan, i.e. -CH2OH or -NH2, are responsible of the interaction. Therefore, we have performed molecular dynamics simulation runs of 1 ns in order to calculate radial distribution functions (RDF) for the groups tentatively involved in the interaction. The results are correlated with our previous experimental data. This way, we have obtained a more precise conclusive information about the interactions involved as function of the blends composition. For low compositions of PVA and P2HEM the interaction is predominantly with the hydroxymethyl groups of CS while as the composition of PVA and P2HEM increases, the interaction with the amine groups increases. 相似文献
74.
本文主要介绍了在动态汽车衡的试验过程中不确定度来源,并以动态试验为例重点介绍了计算各分量的标准不确定度、合成标准不确定度以及扩展不确定度的方法. 相似文献
75.
N. A. Kochetov B. S. Seplyarskii S. G. Vadchenko 《International Journal of Self-Propagating High-Temperature Synthesis》2008,17(3):206-209
Combustion of bulk density Ti powder (containing 20 wt % TiN as a diluent) in a coflow of N2-Ar mixture was investigated upon variation in the nitrogen content of the gaseous mixture. The obtained data are believed
to open up new horizons for fabrication of layered and composite ceramics by infiltration-mediated combustion.
相似文献
76.
系统阐述了全集成自动化理念的内涵,指出其特点在于统一的数据管理、统一的编程组态、统一的通讯以及无与伦比的开放性,其中采用WINCC与STEP7两个软件进行了说明,井提出全集成自动化应用将是今后自动化技术发展应用的方向。 相似文献
77.
Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)3) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)3 exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 104 g mol?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)3 has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)3 is 69.6 kJ mol?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry 相似文献
78.
An experimental investigation was carried out to examine the tribological behavior of NAO (non-asbestos organic) type brake linings containing different volume ratios of graphite and antimony trisulfide (Sb2S3). A scale dynamometer was used for friction tests and particular emphases were given to the effect of applied pressure, sliding speed, and temperature on the coefficient of friction according to the relative amounts of the two solid lubricants. Results showed that the brake linings with both solid lubricants exhibited better friction stability and less speed sensitivity than the friction materials containing a single solid lubricant. In particular, the brake lining containing higher concentrations of graphite showed better fade resistance than others during high-temperature friction test. 相似文献
79.
Organic photovoltaic solar cells bear an important potential of development in the search for low-cost modules for the production of domestic electricity. One of the main differences between inorganic and organic solar cells is that photo-excitation in these materials does not automatically lead to the generation of free charge carriers, but to bind electron–hole pairs (exciton) with a binding energy of about 0.4 eV. Till now various numerical methods using approximations have been reported to study different aspects of organic solar cells. For the first time an accurate method using Lambert W-function is presented to study different parameters of organic solar cells. 相似文献
80.
This article introduces the basic structure of a symmetric self-electrooptic effect device (S-SEED), and applies the Kirchoff' s current law and a purely equivalent capacitive model, to analyze S-SEED's switch characteristics. Linear approximation and N-segment approximation are utilized to obtain S-SEED's voltage-time (V-T) and characteristics. Theoretical analysis is verified by simulations, and the results demonstrate that the precision of S-SEED's switch time can satisfy the requirement in applications with linear approximation. Moreover, the simulations compare S-SEED's switch characteristics with different input powers and input contrast ratios, which reveal that increasing input contrast ratio is an effective way to improve S-SEED's switch characteristics. 相似文献