铝合金熔剂的研究

本文介绍了熔剂在铝合金熔炼过程中的作用,熔剂的分类和要求,常用熔剂的组成,适用范围及使用方法等。     

氮化铝一维纳米结构制备方法和物性研究的最新进展

全面总结了近年来氮化铝一维纳米结构的各种制备方法及物理性能等研究的最新进展,并提出了有待进一步深入研究的一些发展方向。     

铝合金表面搅拌摩擦加工技术的研究进展(Ⅰ)

以搅拌摩擦加工原理为基础,概述了近年来铝合金表面搅拌摩擦加工处理中的细化晶粒与消除铸件内部缺陷的应用,分析了该技术用于铝合金性能(如表面硬度、强度、耐磨性能和超塑性等)改善的机理,展望了搅拌摩擦加工技术在铝合金表面处理中的应用前景。     

SWD型溶液水分测定仪在工作电解液水分测定中的应用

叙述了ＳＷＤ型溶液水分测定仪的设计思想、工作原理等，该仪器可在各种溶液中直接测定含水量，通过实例说明该仪器也可广泛用于电解电容器厂家生产工作电解液中的水分测定；又采用特殊结构和温度补偿器可获得过去没有的性能优良、价格低廉的水分测定仪，可望扩大其用途。     

铝型材隔热断桥工艺的应用

对铝型材隔热断桥生产过程中所涉及的一些因素及加工方式进行探讨,寻找提高加工工艺水平的方法,同时使这种工艺中的某些方式、方法得到广泛的认同与理解。     

A Composite Formation Route to Well‐Crystalline Manganese Oxide Nanocrystals: High Catalytic Activity of Manganate–Alumina Nanocomposites

Manganese oxide nanocrystals are combined with aluminum oxide nanocrystals to improve their crystallinity via calcination without a significant increase of crystal size. A nanocomposite, consisting of two metal oxides, can be synthesized by the reaction between permanganate anions and aluminum oxyhydroxide keggin cations. The as‐prepared manganese oxide–aluminum oxide nanocomposite is X‐ray amorphous whereas heat‐treatment gives rise to the crystallization of an α‐MnO₂ phase at 600 °C and Mn₃O₄/Mn₂O₃ and γ‐Al₂O₃ phases at 800 °C. Electron microscopy and N₂ adsorption‐desorption‐isotherm analysis clearly demonstrate that the as‐prepared nanocomposite is composed of a porous assembly of monodisperse primary particles with a size of ～20 nm and a surface area of >410 m² g^?1. Of particular interest is that the small particle size of the as‐prepared nanocomposite is well‐maintained up to 600 °C, a result of the prevention of the growth of manganate grains through nanoscale mixing with alumina grains. The calcined nanocomposite shows very‐high catalytic activity for the oxidation of cyclohexene with an extremely high conversion efficiency of >95% within 15 min. The present results show that the improvement of the crystallinity without significant crystal growth is very crucial for optimizing the catalytic activity of manganese oxide nanocrystals.     

以蔗糖为模板剂合成介孔氧化铝

以蔗糖为模板剂,异丙醇铝为铝源,水相体系下,考察了体系pH和模板剂用量对介孔氧化铝合成的影响。并采用X射线衍射、透射电镜(TEM)、氮吸脱附以及固体核磁等手段对合成样品进行表征。结果表明,合成的介孔氧化铝为γ-Al2O3,具有较高的比表面积以及较集中的孔径分布。体系的pH和模板剂用量对介孔氧化铝产物的性能有一定影响,并对蔗糖的模板作用机理进行了讨论。     

液相法合成氢化铝钠的研究

以NaH和AlCl3为主要原料,通过改变实验条件,探索研究液相法合成NaAlH4的合成条件。实验表明,在不加入任何催化剂的情况下无法实现NaAlH4的合成,在以NaAlH4、三乙基铝等物质为催化剂的条件下,虽有少量的产物生成,但是反应不明显,且产物中存在大量的非晶态物质。即便在高温高压下反应亦难以进行,大量的化合物均以非晶态形式存在。     

3-丙酰氨基-N,N-二丙酸甲酯基苯胺的合成研究

用无水三氯化铝作催化剂在较低温度下将3-氨基丙酰苯胺和丙烯酸甲酯转化为3-丙酰氨基-N,N-二丙酸甲酯基苯胺,其产品收率达到89%,纯度高于92%。     

New DC Hybrid Filter for Attenuating Low-Frequency Ripple of AC-DC Power Converter

In this article, a new DC hybrid power filter is proposed to attenuate the low–frequency ripple of AC-DC power converter. The proposed DC hybrid power filter is connected between the DC bus of AC-DC power converter and the load, and it composes of a passive power filter and a single-arm power converter. The passive power filter can reduce the voltage rating of single-arm power converter, and the operation of single-arm power converter generates a virtual harmonic resistor connected to the load in series. The DC hybrid power filter can suppress the twice-utility-frequency ripple for eliminating the use of electrolytic capacitor. The salient feature is that the control circuit of the proposed DC hybrid power filter is simplified because only a feedforward control is used. A hardware prototype is developed to validate the performance of the proposed DC hybrid power filter. The experimental results are as expected.