重油催化裂化装置再生器的改造

上海石化股份公司重油催化裂化装置为反应沉降器与再生器并列布置 ,两个再生器同轴布置。通过处理能力由 0 .8Mt/a提高至 1.0Mt/a的局部改造后 ,该装置产生了外取热器无法正常投用 ,两个再生器烧焦比例不易合理分配、第一再生器 (一再 )烧焦强度较低、剂油比偏低及催化剂单耗偏高等问题。因此 ,又对再生器进行了改造 :将一再船形待生催化剂分布器改为Y形分布器、在一再密相床上部增设格栅、外取热器催化剂返回分布器增设软密封、待生催化剂输送线路由斜管 立管 斜管的形式改为斜管形式等 ,改造效果好。     

催化裂化装置反应再生系统优化改造

重点介绍了呼和浩特石油化工公司重油催化裂化装置反应再生系统优化改造的目的、内容及运用的新技术;着重从物料平衡、原料及产品性质、催化剂性质、装置能耗、操作参数等方面与改造前进行了对比。装置改造后,在原料明显变重,催化剂单耗明显降低的情况下,生焦率下降了0.13个百分点,轻质油收率提高了3.54个百分点;汽油诱导期较改造前延长了140min,烯烃体积分数降低了1.9个百分点;柴油十六烷值比改造前提高了4个单位;装置能耗较改造前下降了906MJ/t,年创经济效益1030.9×10~4RMB￥。     

常减压蒸饱装置几起典型硫腐蚀事例分析

随着高（含）硫原油加工量的增加,硫腐蚀事故也时有发生。通过对常减压装置硫腐蚀事例进行分析,指出合理的混炼比,加强“一脱三注”管理,材料升级和实施腐蚀监测是防止腐蚀事故发生的有效措施。     

弱激发氩离子激光的振荡频率特性

通过改变激光器的相对激发,观察到了氩离子激光器振荡频率的演变特性。用模竞争效应对实验现象进行了理论解释。     

叶绿素衍生物─CPD_4在人血清中的激发和发射荧光谱

叶绿素衍生物４号（ＣＰＤ４）是一种新型中药光敏剂，本文研究了不同浓度的ＣＰＤ４分别在含１０％不同血型人血清的生理盐水中以及纯生理盐水中的激发和发射荧光光谱，并对结果进行了分析，结论对ＣＰＤ４在光动力诊断恶性肿瘤的临床应用具有一定的指导意义．     

小型全内腔脉冲Ar~＋激光管的研制

介绍一种小型全内腔脉冲Ａｒ＋激光管的设计和结构。并对不同阴极，放电管直径，激励电压及Ａｒ气压等对输出功率及激光管寿命的影响作了一系列的实验，试制出结构简单，使用方便，价格便宜的有一定实用价值的小型全内脏脉冲Ａｒ＋激光管。     

Rapid determination of chlorophylls in vegetable oils by laser-based fluorometry

The presence of chlorophylls in vegetable oils is considered undesirable due to their adverse effects on oxidative deterioration, bleachability and hydrogenation. The usual methods for determination of chlorophylls in vegetable oils are absorption spectrophotometry, fluorometry and liquid chromatography using fluorescence detectors. This paper outlines a fluorometric method using a laser as the excitation source. The chlorophylls in crude palm oil, rapeseed oil, soya bean oil and olive oil were determined directly by laser-based fluorometry using (a) a helium-neon laser (632-8 nm, 5 mW) as the excitation source and an optical-multichannel analyser (OMA) with an intensified diode array as the detector, and (b) a helium-neon laser and a photomultiplier tube as the detector. The method is especially suitable for the detection of chlorophylls in crude palm oil since no pre-extraction step is required. The levels of chlorophylls measured in vegetable oils using the laser technique was also compared against values obtained by conventional spectrophotometric methods. The simplicity and rapid quantification of laser based fluorometry suggest that this technique can be readily applied to the detection or a wide variety of fluorescing species in vegetable oils.     

催化裂化再生系统设备应力腐蚀开裂成因分析及解决对策

通过对催化裂化装置再生系统设备裂纹断口分析 ,以及对再生烟气的组分、冷凝水酸度及露点等的分析及对设备焊接残余应力测试 ,阐明了设备应力腐蚀开裂发生的原因 ,指出了富氧操作、高露点温度和高应力水平对再生系统设备应力腐蚀的影响作用 ,并重点提出了解决和防止应力腐蚀开裂的一系列有效措施和部分应用情况     

数字视频混合系统的设计

介绍了利用Philips的一款视频芯片SAA71 99B实现的数字视频混合系统.该系统可以将一路PAL制彩色复合视频信号编码进入另一路PAL制彩色复合视频信号中,以取代第二路视频中用户指定的颜色,从而实现了两路视频的混合.另外还介绍了如何利用单片机的I/O口模拟I 2C总线以及如何利用单片机进行彩色空间变换的算法.     

Electron-Impact Cross Sections for Dipole- and Spin-Allowed Excitations of Hydrogen,Helium, and Lithium

Electron-impact excitation cross sections are presented for the dipole- and spin allowed transitions from the ground states to the np ²P states for hydrogen and lithium, and to the 1snp ¹P states for helium, n = 2 through 10. Two scaling formulas developed earlier by Kim [Phys. Rev. A 64, 032713 (2001)] for plane-wave Born cross sections are used. The scaled Born cross sections are in excellent agreement with available theoretical and experimental data.