Low temperature synthesis of aluminium titanate by an aqueous sol-gel route

Formation of aluminium titanate (AT) has been achieved at low temperature through sol-gel process using boehmite and titanium hydroxide as precursors by controlling the particle size at nanoscale followed by in-situ peptisation. The formations of AT phase, particle size distributions, sintering and thermal expansion characteristics, and microstructural features have been reported. DTA and XRD analysis have been performed to confirm the formation of AT. A 94% relative density was obtained for aluminium titanate sintered at 1550 °C with controlled grain size in the range of 2-3 μm.     

The Effect of Structural Defects on the Thermal Conductivity of ZnS, ZnSe, and CdTe Polycrystals

ZnS, ZnSe, and CdTe polycrystals are experimentally investigated. Mechanisms are treated which restrict the thermal conductivity in samples prepared by recrystallization pressing and by deposition from the vapor phase and subjected to additional strain. Anomalies are observed on the temperature dependences of the thermal resistance of investigated samples, which are due to the special features of their phonon spectra and to the variation of the contribution made by longitudinal and transverse phonon branches to the heat transfer in the Debye temperature region and higher.     

Wettability of Lithium by Liquid Sodium, Potassium and Rubidium

The wettability of the lithium surface by liquid alkali metals Na, K and Rb is investigated for the first time by the sessile drop method in an all-soldered instrument under conditions of a high vacuum. The presence of the temperature threshold of wetting is found in Li–Na and Li–K systems at temperatures of 325°C and 160°C, respectively. A conclusion is drawn that an abrupt decrease in wetting angles in the investigated systems is associated with a marked decrease in the interfacial tension at lithium-lithium, lithium-potassium, and lithium--rubidium interfaces owing to the beginning of a noticeable mutual solubility of the components at relatively high temperatures.     

A three‐dimensional model describing stress‐temperature induced solid phase transformations: solution algorithm and boundary value problems

An always increasing knowledge on material properties as well as a progressively more sophisticated production technology make shape memory alloys (SMA) extremely interesting for the industrial world. At the same time, SMA devices are typically characterized by complex multi‐axial stress states as well as non‐homogeneous and non‐isothermal conditions both in space and time. This aspect suggests the finite element method as a useful tool to help and improve application design and realization. With this aim, we focus on a three‐dimensional macroscopic thermo‐mechanical model able to reproduce the most significant SMA features (Int. J. Numer. Methods Eng. 2002; 55 : 1255–1264), proposing a simple modification of such a model. However, the suggested modification allows the development of a time‐discrete solution algorithm, which is more effective and robust than the one previously discussed in the literature. We verify the computational tool ability to simulate realistic mechanical boundary value problems with prescribed temperature dependence, studying three SMA applications: a spring actuator, a self‐expanding stent, a coupling device for vacuum tightness. The effectiveness of the model to solve thermo‐mechanical coupled problems will be discussed in a forthcoming work. Copyright © 2004 John Wiley & Sons, Ltd.     

Simulating Experiment for Temperature Field of Frozen Subgrade Using Regulation Tubes

The main factors that influence the temperature field of frozen subgrade were analyzed.The experimental equipment for simulating frozen subgrade was built up,and the declining regulating tubes were placed at the foot of the embankment. By means of this equipment two simulating experiments of controlling temperature filed of frozen subgrade were carried out in the laboratory. One method is to collect natural cold energy, and the other one is to collect natural cold energy ccompanied by artificial refrigeration simultaneously. The result indicates that the latter is an effective method for maintaining the stability of the frozen subgrade.     

八种新功能晶体的比热及其与相变掺杂物关系的实验研究

本文对八种新型功能晶体Ｌｉ２Ｂ４Ｏ７、Ｂｉ１２ＴｉＯ２０、Ｂｉ１２ＧｅＯ２０、Ｂｉ１２ＧｅＯ２０、Ｂｉ４Ｇｅ３Ｏ１２、Ｓｒ１－ｘＢａｘＮｂ２Ｏ６（ｘ＝０．３３，０．４８）、ＬｉＴａＯ３等在１３０～９７３Ｋ范围内的比热行为及其与相变、组分之间的关系进行了实验研究，给出了比热的多项式拟合方程，并与用纽曼－卡普定律及用Ｗｉｋｅｌｍａｎｎ经验方程的比热计算值作了对比，为晶体比热的估算提供了依据和方法。     

Mapping Turbidity, Surface Temperature and Water Circulation Patterns with the Aid of Satellite Imagery

Water turbidity, surface temperature and circulation of Barton and Wroxham Broads, two of the Norfolk Broads, were studied using one reflective (TM1) and the thermal (TM6) TM band. The results indicated that the through-flowing path of the River Ant in Barton Broad is the major influence on the distribution of these parameters. In Wroxham Broad, both turbidity and surface temperature displayed a uniform distribution. This could be explained by the absence of a predominant direction of flow.     

AHMED experiments on hygroscopic and inert aerosol behaviour in LWR containment conditions: experimental results

Hygroscopic NaOH, CsI, CsOH and inert Ag aerosol behaviour at different temperatures and relative humidities (RH) has been studied in a well instrumented and controlled vessel of 1.81 m³ total free volume. Homogeneous thermal-hydraulic conditions for aerosol measurement in the vessel were achieved. The aerosol number and mass concentration were measured continuously during the experiments using a Condensation Nucleus Counter and a Tapered Element Oscillating Microbalance. The particle size distribution and chemical composition in the test conditions were measured by Berner low pressure impactors. In the case of NaOH the half life of the aerosol mass concentration was more than four times longer at low RH (22%) as compared to high RH (96%). The half lives of the CsOH and CsI aerosols were only twice as long at low RH as compared to high RH. Thus at high RH (96–97%) the half lives of CsOH and CsI were twice as long as the half life for the NaOH aerosol. The faster decay of the NaOH aerosol is due to the smaller density decrease of NaOH during water condensation. CsOH particles grew rapidly to their equilibrium size at all humidities. The measured equilibrium size for CsOH aerosol agree well with the calculated particle size at different RHs. Experimental results were also compared with calculations obtained by severe accident computer codes. These calculated results will be presented in a later paper.     

蒸汽压法测定导热油热分解温度的研究

根据克拉贝龙—克劳修斯方程，建立了国内外文献未见报道的测定导热油热分解温度的试验装置和试验方法，测定了大量国内外导热油的热分解温度，数据表明该法具有准确、简单、实用、省时、省力等优点     

Nb,Ti微合金钢热变形的动态模拟变形抗力模型

本文报道 Nb,Ti 微合金钢的热变形动态模拟变形抗力模型。在试验中用热加工模拟试验机进行高温压缩试验,其变形温度为1123—1423K,变形速率为0.1—60s~(-1)。结果表明,在峰值以前该钢种的流变应力数学模型为:σ=5.99.ε~(0.167)·(?)~(6.47×10~(-5)·T)·exp(4064/T)。形变激活能(Q)为444 kJ/mol,β系数为0.080。峰值应力(σ_p),临界应变(ε_c)和温度补偿应变速率参数(Z)之间的关系分别为:σ_p=12.56·lnZ-391.8;lnε_c=0.157·lnZ-7.39。