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91.
92.
Melanie H. Bowler Aditya Mishra Austen C. Adams Corinne L.‐D. Blangy Jason D. Slinker 《Advanced functional materials》2020,30(33)
Light‐emitting electrochemical cells (LECs) are devices that utilize efficient ion redistribution to produce high‐efficiency electroluminescence in a simple device architecture. Prototypical polymer LECs utilize three components in the active layer: a luminescent conducting polymer, a salt, and an electrolyte. Similarly, many small‐molecule LECs also utilize an electrolyte to disperse salts. In these systems, the electrolyte is incorporated to efficiently conduct ions and to maintain phase compatibility between all components. However, certain LEC approaches and materials systems enable device operation without a dedicated electrolyte. This review describes the general methods and materials used to circumvent the use of a dedicated electrolyte in LECs. The techniques of synthetically coupling electrolytes, incorporating ionic liquids, and introducing inorganic salts are presented in view of research efforts to date. The use of these techniques in emerging classes of light‐emitting electrochemical cells is also discussed. These approaches have yielded some of the most efficient, long‐lasting, and commercially applicable LECs to date. 相似文献
93.
Yang Cao Qing Zhang Yaqing Wei Yanpeng Guo Zewen Zhang William Huang Kaiwei Yang Weihua Chen Tianyou Zhai Huiqiao Li Yi Cui 《Advanced functional materials》2020,30(7)
Layered transition metal (TM) oxides of the stoichiometry NaxMO2 (M = TM) have shown great promise in sodium‐ion batteries (SIBs); however, they are extremely sensitive to moisture. To date, most reported titanium‐based layered anodes exhibit a P2‐type structure. In contrast, O3‐type compounds are rarely investigated and their synthesis is challenging due to their higher percentage of unstable Ti3+ than the P2 type. Here, a pure phase and highly crystalline O3‐type Na0.73Li0.36Ti0.73O2 with high performance is successfully proposed in SIBs. This material delivers a reversible capacity of 108 mAh g?1 with a stable and safe potential of 0.75 V versus Na/Na+. In situ X‐ray diffraction reveals that this material does not undergo any phase transitions and exhibits a near‐zero volume change upon Na+ insertion/de‐insertion, which ensures exceptional long cycle life over 6000 cycles. Importantly, it is found that this O3‐Na0.73Li0.36Ti0.73O2 shows superior moisture stability, even when immersed into water, which are both elusive for conventional layered TM oxides in SIBs. It is believed that the small interlayer distance and high occupation of interlayer vacancy promise such unprecedented water stability. 相似文献
94.
紫外光电离源是离子迁移谱中最重要的电离源之一,常被用来电离有机物,产生正离子。利用紫外光照射金属表面产生电子作为离子源,建立了一套光电子源离子迁移谱仪,由于卤化物具有较强的吸附电子能力,该装置可以应用于卤化物的检测。使用CCl4样品,得到了该装置的离子峰强度、半峰宽、分辨率随迁移管电场、离子门脉宽、离子门电压的变化关系,并进行了简单的理论分析。兼顾离子峰强度与分辨率,得到了优化的实验参数,在该参数下测量了CCl4的检测限达到4 ppb,线性范围跨越2个数量级。 相似文献
95.
为了实现仪器的实时在线监测,利用能量为10.6 eV的紫外光灯取代传统础Ni放射性电离源,自主研发出便携、快速、高灵敏的光电离/离子迁移谱仪.紫外光灯为直流供电,避免了放射性物质严格的操作规程,并且实现了易制毒化学品有机物分子的软电离.最近的实验结果表明,在列出的23种违禁物品中,13种以上可以得到快速有效的鉴别,检测时间在几秒以内,检测下限可以达到PPb量级,其中挥发性成分的检测结果尤为显著. 相似文献
96.
97.
B.A. Park C.A. Musca J. Antoszewski J.M. Dell L. Faraone 《Journal of Electronic Materials》2007,36(8):913-918
Exposure of p-type HgCdTe material to Ar/H2-based plasma is known to result in p-to-n conductivity-type conversion. While this phenomenon is generally undesirable when aiming to perform physical etching for
device delineation and electrical isolation, it can be used in a novel process for formation of n-on-p junctions. The properties of this n-type converted material are dependent on the condition of the plasma to which it is exposed. This paper investigates the
effect of varying the plasma process parameters in an inductively coupled plasma reactive ion etching (ICPRIE) tool on the
carrier transport properties of the p-to-n type converted material. Quantitative mobility spectrum analysis of variable-field Hall and resistivity data has been used
to extract the carrier transport properties. In the parameter space investigated, the n-type converted layer carrier transport properties and depth have been found to be most sensitive to the plasma process pressure
and temperature. The levels of both RIE and ICP power have also been found to have a significant influence. 相似文献
98.
静态电流(IDDQ)测试是一种很灵敏且具有成本效益的集成电路测试技术,针对0.13μm某种DSP芯片在量产初期所遇到的IDDQ测试失效情况,利用激光束诱导电阻值变化(OBIRCH)、电压对比(VC)、扫描电镜(SEM)和聚焦离子束(FIB)等电学与物理失效分析方法,确定由离子注入偏差所引起的MOS器件物理缺陷是造成IDDQ失效的原因,据此进行了离子注入光阻的工艺改进,最终实现了成品率的提升. 相似文献
99.
100.
A device able to electrokinetically concentrate cationic samples has many potential medical and industrial applications, but until now has remained undeveloped due to the lack of a commercial anion-permselective material leading to a prohibitively complex fabrication procedure. Herein, a novel multiscale-porous anion exchange membrane (MP-AEM) that enables the convenient and scalable electrokinetic concentration of cationic species is proposed. A mechanically enhanced multiscale-porous structure with a solid framework is realized by adopting polyester resin as an additive to overcome the intrinsic limitations of the AEM material. The scalable MP-AEM-embedded electrokinetic concentrator is devised based on the peculiar properties of the MP-AEM that for allow both ion and fluid transport. With the MP-AEM, the concentrator is fabricated in a highly streamlined manner consisting only of a simple insertion and assembly. The concentration performance of the MP-AEM-embedded electrokinetic concentrator is demonstrated with a positively charged fluorescent dye and a fluorescein-labeled protein, and the results show enrichment factors of 250 and 500, respectively. The MP-AEM makes cationic electrokinetic concentration more accessible and scalable, thereby enabling further progress in a wide range of fields. 相似文献