基于1H NMR测定和基团贡献法预测石油馏分的热化学性质

测定了两种原油 2 0个石油馏分的¹H NMR谱和氢、碳元素含量等结构参数 ,以及馏分的燃烧焓、蒸发焓等热化学性质 .假设每个石油馏分仅由CH₃ 、CH₂ 、CH、ACH和C这 5种简单基团构成 ,基于¹H NMR测定和元素分析结果解出石油馏分平均分子结构中的基团数目 ,再用纯有机物的基团贡献法预测石油馏分的燃烧焓、蒸发焓 ,预测值与实验数据吻合良好     

丙烯酸型亲水涂料乳胶粒表面羧基分布的研究

研究了以苯乙烯为核,丙烯酸酯类为壳的核壳乳液,采用丙烯酸为功能性单体,成膜后羧基为极性基团分布在涂膜表面达到亲水目的。讨论了功能单体丙烯酸(AA)在乳胶粒表面的分布情况及其加量对涂膜亲水性的影响,通过电导滴定发现当AA的加入量为3%时,水相中游离的丙烯酸含量为5.57%,聚合物表面的羧基含量为36.11%,涂膜的亲水性达到最佳,水接触角为51.1°。本文还讨论了核壳法和核壳翻转法对乳胶粒表面羧基分布及涂膜亲水性能的影响,两者的电导滴定曲线形状一致,由两个当量点可以计算出水相中游离的丙烯酸含量为1.47%,而乳胶粒表面羧基分布的含量为43.59%,可见,用核壳翻转法合成的乳液,乳胶粒表面羧基分布含量比普通聚合方法合成的乳胶粒表面羧基分布含量高,涂膜亲水性进一步提高,水接触角降低为44.5°。     

Laplacian group sparse modeling of human actions

Recently, many local-feature based methods have been proposed for feature learning to obtain a better high-level representation of human behavior. Most of the previous research ignores the structural information existing among local features in the same video sequences, while it is an important clue to distinguish ambiguous actions. To address this issue, we propose a Laplacian group sparse coding for human behavior representation. Unlike traditional methods such as sparse coding, our approach prefers to encode a group of relevant features simultaneously and meanwhile allow as less atoms as possible to participate in the approximation so that video-level sparsity is guaranteed. By incorporating Laplacian regularization the method is capable to ensure the similar approximation of closely related local features and the structural information is successfully preserved. Thus, a compact but discriminative human behavior representation is achieved. Besides, the objective of our model is solved with a closed-form solution, which reduces the computational cost significantly. Promising results on several popular benchmark datasets prove the efficiency and effectiveness of our approach.     

Group‐in‐a‐Box Meta‐Layouts for Topological Clusters and Attribute‐Based Groups: Space‐Efficient Visualizations of Network Communities and Their Ties

An important part of network analysis is understanding community structures like topological clusters and attribute‐based groups. Standard approaches for showing communities using colour, shape, rectangular bounding boxes, convex hulls or force‐directed layout algorithms remain valuable, however our Group‐in‐a‐Box meta‐layouts add a fresh strategy for presenting community membership, internal structure and inter‐cluster relationships. This paper extends the basic Group‐in‐a‐Box meta‐layout, which uses a Treemap substrate of rectangular regions whose size is proportional to community size. When there are numerous inter‐community relationships, the proposed extensions help users view them more clearly: (1) the Croissant–Doughnut meta‐layout applies empirically determined rules for box arrangement to improve space utilization while still showing inter‐community relationships, and (2) the Force‐Directed layout arranges community boxes based on their aggregate ties at the cost of additional space. Our free and open source reference implementation in NodeXL includes heuristics to choose what we have found to be the preferable Group‐in‐a‐Box meta‐layout to show networks with varying numbers or sizes of communities. Case study examples, a pilot comparative user preference study (nine participants), and a readability measure‐based evaluation of 309 Twitter networks demonstrate the utility of the proposed meta‐layouts.     

Anionic synthesis of poly(epichlorohydrin-g-styrene) and chemical modification of polyepichlorohydrin

Poly(epichlorohydrin-g-styrene) copolymers, P(ECH-g-S)s, have been prepared in solution by two different methods of coupling polyepichlorohydrin, PECH, with polystyrene, PS, containing a functional end group. In the first method, polystyryl carboxylic acid, PSCOOH, prepared from living polystyrene, was converted to the corresponding potassium salt which was coupled with PECH in dimethyl formamide solution usually at 60°C. In the second method, polystyryl potassium, PS^?K⁺, in tetrahydrofuran solution was end-capped with propylene sulphide to form PSCH₂CH(CH₃)S^?K⁺ which was coupled directly with PECH in tetrahydrofuran at 40°C. Grafting by the first reaction was relatively slow but occurred without significant adverse side reactions. The grafting by the second reaction was relatively fast, but side reactions occurred resulting in a cleavage of the graft copolymer. The graft copolymers were purified by fractional precipitation and extraction procedures and were characterized by infra-red and ultra-violet spectroscopy, microanalysis, gel permeation chromatography, differential scanning calorimetry, solution viscometry, dynamic mechanical testing, and electron microscopy. Solution properties of the graft copolymers in benzene-carbon tetrachloride and toluene-cyclohexane mixtures were studied. There was evidence of micelle formation in dilute solutions of the mixed solvents and microphase separation of components in the solid state. Nucleophilic substitution of chlorine atoms in PECH by phenyl acetate (C₆H₅ CH₂COO-) and thiophenoxide (C₆H₅S-) groups was performed.     

胺烷基化聚羟基酸酰胺类超分散剂的研制及应用

对胺烷基化聚羟基酸酰胺的合成方法进行研究，确立了反应条件与制得的聚羟基酸酯特征之间的一些相互关系。并为获得适当长度的聚酯链选择了最佳合成条件。同时扼要论述了这类超分散剂的结构特性，以及对于颜料粒子表面吸附作用、分散体系的稳定作用以及对涂料、油墨生产的重要意义。     

两种基于个体偏好集结的多属性群决策共识方法

针对多属性群决策中的共识问题, 提出两种使群体达成共识的方法. 假设群体决策的结果以从个体偏好通过集结得到的群体偏好为基础, 在使用算术加权集结算子和几何加权集结算子的条件下, 分别设计相应的共识达成算法, 并对算法的收敛性进行分析. 与已有方法相比, 所提出算法能够体现决策个体的差异和决策个体对群体的影响. 通过某市政图书馆空调系统安装方案的选择表明了所提出方法的合理性和可行性.

     

异种双活性基染料湿摩擦牢度再探讨

影响异种双活性基染料湿摩擦牢度主要有四个基本因素:染色基质的可染性、活性染料的化学结构、洗涤效率和助剂因素。提出了棉坏布预处理、使用助剂、提高染料的固色率和吸尽率、提升力等9项改进此类染料湿处理牢度的措施。有3篇参考文献。     

基于量子克隆的二面体群隐含子群问题量子算法的研究

基于最短向量问题的格公钥密码体制是典型的抗量子计算密码体制。格的唯一最短向量问题可转化为二面体群的隐含子群问题。有效地求解二面体群的隐含子群问题可攻破基于格的唯一最短向量问题的公钥密码体制。Kuperberg提出了二面体群隐含子群问题的半指数级量子算法。通过研究Kuperberg量子算法,利用概率量子克隆,文中提出了二面体群隐含子群问题的多项式时间量子算法。     

具有不同代理群的多代理多签名方案

目前在大多数多代理多签名(multi-proxy multi-signature,MPMS)方案中,所有的原始签名人指定同一个代理群生成代理签名。然而在很多实际应用中,每个原始签名人经常需要在自己所在的组织中选择代理群,从而导致各个原始签名人需要选择不同的代理群,代表自己生成代理签名。现有的多代理多签名方案中还没有考虑这方面的需求。提出一个可以指定不同代理群的MPMS方案。在该方案中,可以指定一个多人的验证群合作验证最终签名的合法性。为证明方案的安全性,对现有的安全模型进行改进,在计算Diffie-Hellman假设的基础上,验证所提方案是安全的。与已有方案相比,本方案更加安全和有效。