涡流管类比逆流换热器方法的研究

结合Scheper，Lewins和Bejan的理论模型，对涡流管类比逆流换热器模型进行了深入地分析，得出了冷流分量对温度分离效应的函数关系式，为了解涡流管机理和实验中强化涡流管温度分离效应提供了理论依据。     

GL—2型Φ600mm螺旋选别攀枝花钛铁矿生产实践

攀矿选钛厂设计采用传统的螺旋选矿设备ＦＬＸ一１型φ６００ｍｍ螺旋选矿机和φ１２００ｍｍ螺旋溜槽，从选矿（铁）厂磁选尾矿物料中回收原生粒状钛铁矿积累了多年生产实践经验。而广东有色金属研究院研制的ＧＬ一２型φ６００ｍｍ螺旋选矿机具有处理能力大、分选效率高、选别粒级宽、不需冲洗水及占地面积小等特点，有取代选钛厂目前使用的螺旋选矿设备之趋势。     

空分设备的酸性腐蚀及预防

以切换式换热器空分设备为例 ,分析了空分设备酸性腐蚀的原因、可能造成的危害 ,提出了预防措施。     

绕扰流片分离流动的壁面压力测量

在风洞中用电子扫描阀进行测压实验，研究了底部间隙和锯齿高度对扰流片引起的壁面压力分布的影响。结果表明底部间隙在g／h≥1．0时对扰流片上游壁面压力分布曲线有较大影响，而对下游回流区压力分布曲线的影响主要在0≤g／h≤2．0的区域内；并且在g／^=0．2、1．0时，流动结构发生改变。另外，锯齿扰流片的当量面积与平板扰流片相等时，锯齿高度对下游底板压力分布特性的影响亦主要限于0≤x／h≤2．0的区域。     

乙苯/苯乙烯塔分离效率问题的技术分析及整改措施

分析了齐鲁分公司200kt/a乙苯/苯乙烯装置乙苯/苯乙烯塔(T-401)分离效率低的原因,即降液管设计偏小,液体在降液管内流速过快,引起液体飞溅;安装分布器使用的石棉垫片溶胀而粉碎后堵塞了分布槽;分布器上使用的垫片脱落形成缝隙而漏液;填料装得不密实,留有缝隙;二级分布槽变形等.针对存在问题提出了相应的整改措施,并考察了整改措施实施效果.结果表明,整改后该塔的分离能力满足了工艺要求,并有一定的操作弹性.     

Enantioselective extraction of mandelic acid enantiomers based on chiral ligand exchange

Based on the chiral ligand exchange, the distribution behavior of mandelic acid enantiomers, and the partition of Cu^2 at different pH values were studied in a water/alcohol two-phase system containing Cu^2 and N-ndodecyl-L-proline(A). The influences of the solvent sort, the pH value, the concentrations of Cu^2 and chiral ligand on the partition coefficient(K) and separation factor(α) were discussed. The experimental results show that the A formed has more stable ternary complex with D-mandelic acid enantiomer than with L-mandelic acid enantiomer. There is an important influence of the pH value on K and a. When the pH values are less than 3.5, the formation of binary complexes is thermodynamically unfavourable. K and a become maximum when pH values are above 3.5 and the molar ratio of the chiral ligand to Cu^2 is 2:1.     

Selective recognition in molecularly imprinted polymer and its chromatographic characterization for cinchonine

A molecularly imprinting polymer (MIP) was synthesized via bulk polymerization under different conditions using anti-ague drug cinchonine (CN) as template. Infrared spectra (IR) results show that the template CNand functional monomer α-methyl acrylic acid (MAA) formed complexes before polymerization and the structure of complexes was simulated by Hyperchem. The results indicate that there are hydrogen bond or ionic bond between functional monomer and template molecule in acetonitrile solution. The MIP made in cold-initiated photo-polymerization has higher separation performance than that in the therm-initiated polymerization. The separation of the isomers CN and cinchonidine (CD) can be successfully obtained when its separate factor α reaches 1.82. Scatchard analysis suggests that the MIP recognizing CN with two classes of binding sites. The partition coefficient Kd, 1 and apparent maximum number nmax, 1 of binding sites with high affinity are 131.43 μmol/L and 58. 90 μmol/g, respectively,while Kd, 2 and nmax, 2 of binding sites with low affinity are 2.32 mmol/L and 169.08 mmol/g, respectively.     

锆钡镧铝氟化物玻璃的分相研究

本文综述了氟化物玻璃中的分相研究。在前人研究基础上应用透射电镜，X射线能谱，电子能量损失谱及X射线衍射，差热分析等研究了锆钡镧铝氟化物玻璃中的液-液分相，发现此种现象普遍存在于该类玻璃之中。对玻璃成分与分相形貌及微观结构之间的关系、对析出晶相种类及分相与析晶的相互影响进行了研究。提出欲降低氟化物玻璃的光损耗，分相与析晶一样是不容忽视的因素。     

Application of the blind source separation method to feature extraction of machine sound signals

As the result of vibration emission in air, a machine sound signal carries important information about the working condition of machinery. But in practice, the sound signal is typically received with a very low signal-to-noise ratio. To obtain features of the original sound signal, uncorrelated sound signals must be removed and the wavelet coefficients related to fault condition must be retrieved. In this paper, the blind source separation technique is used to recover the wavelet coefficients of a monitored source from complex observed signals. Since in the proposed blind source separation (BSS) algorithms it is generally assumed that the number of sources is known, the Gerschgorin disk estimator method is introduced to determine the number of sound sources before applying the BSS method. This method can estimate the number of sound sources under non-Gaussian and non-white noise conditions. Then, the partial singular value analysis method is used to select these significant observations for BSS analysis. This method ensures that signals are separated with the smallest distortion. Afterwards, the time-frequency separation algorithm, converted to a suitable BSS algorithm for the separation of a non-stationary signal, is introduced. The transfer channel between observations and sources and the wavelet coefficients of the source signals can be blindly identified via this algorithm. The reconstructed wavelet coefficients can be used for diagnosis. Finally, the separation results obtained from the observed signals recorded in a semi-anechoic chamber demonstrate the effectiveness of the presented methods .