High‐performance porous lead/graphite composite electrode for bipolar lead‐acid batteries

In general, thicker active material bipolar electrode's specific capacity and cycle life are very poor owing to its low bonding strength between the active material and the substrate and the diffusion rate of the sulfuric acid electrolyte inside the active material. In this paper, we synthesize a novel attached and porous lead/graphite composite electrode for bipolar lead‐acid battery and can effectively solve these problems. The graphite/polytetrafluoroethylene emulsion is employed to improve the bonding strength and conductivity and the porous can provide electrolyte diffusion channels. The specific capacities of 2‐mm thick positive active material at 0.25, 0.5, 1 and 2 C can attain 75.99, 58.98, 47.97, and 33.36 mAh·g^?1. The discharge voltage platform is also relatively high and no rapid decline with increasing discharge rate. Furthermore, after 80 cycles, the specific capacity does not drop evidently. Copyright © 2017 John Wiley & Sons, Ltd.     

分析水对无烟煤挥发分测定产生的影响

根据GB／T212-2008《煤的工业分析方法》中的规定，在测定挥发分时，通过实验对比，无烟煤中水分随着煤的变质程度加深而呈规律性变化。从泥炭、褐煤、烟煤到年轻无烟煤水分逐渐减少，从年轻无烟煤到老年无烟煤的水分又逐渐增加。由于煤中水分过高和煤的氧化增重，导致挥发分测定值产生负值，影响挥发分的测定结果。     

冷发生炉煤气双蓄热在均热炉上的应用

介绍了以冷发生炉煤气为燃料，采用双蓄热的均热炉的设计上的一些技术手段及在实践中的使用效果等。     

高炉入炉焦比影响因素的分析与应用

本文统计了莱钢2#高炉生产情况,分析了制约入炉焦比的因素,制定了解决措施。通过优化,成功将炉焦比进一步降低,取得了良好效果,经济效益显著。     

焦炉煤气制尿素工艺中合成气不足的解决方案

简述了剩余焦炉煤气综合利用的途径,分析了在不同结焦时间下的合成气量分配情况,针对由于结焦时间较长低负荷工况下出现合成气量不足的情况提出了解决措施,根据提出的解决措施制定了设想工艺方案,采用UGI炉气化技术工艺造气来解决合成气不足的问题较为现实,整体工艺方案的预计投资约1000万元。     

碳化硅高温预热技术在锻造加热炉上的应用

介绍了碳化硅高温预热技术在锻造加热炉上的应用实践,分析了碳化硅高温换热器的特点及使用优势,在室式加热炉上推广应用有利于提高节能减排的效果。     

高炉水渣排汽筒在线更换改造技术

为根本解决宝钢股份炼铁厂一号、二号高炉水渣排汽筒筒体腐蚀破损问题,对4根水渣排气筒进行了更新改选,针对工程中,FRP玻璃钢管安装难度大,采取了多种辅助安装措施,确保了工程改选的顺利进行。     

Lead‐Free Polycrystalline Ferroelectric Nanowires with Enhanced Curie Temperature

Ferroelectrics are important technological materials with wide‐ranging applications in electronics, communication, health, and energy. While lead‐based ferroelectrics have remained the predominant mainstay of industry for decades, environmentally friendly lead‐free alternatives are limited due to relatively low Curie temperatures (T _C) and/or high cost in many cases. Efforts have been made to enhance T _C through strain engineering, often involving energy‐intensive and expensive fabrication of thin epitaxial films on lattice‐mismatched substrates. Here, a relatively simple and scalable sol–gel synthesis route to fabricate polycrystalline (Ba_0.85Ca_0.15)(Zr_0.1Ti_0.9)O₃ nanowires within porous templates is presented, with an observed enhancement of T _C up to ≈300 °C as compared to ≈90 °C in the bulk. By combining experiments and theoretical calculations, this effect is attributed to the volume reduction in the template‐grown nanowires that modifies the balance between different structural instabilities. The results offer a cost‐effective solution‐based approach for strain‐tuning in a promising lead‐free ferroelectric system, thus widening their current applicability.     

Short Crack R-Curves in Ferroelectric and Electrostrictive PLZT

This work describes the measurement of R -curve behavior in ferroelectric ceramics using four-point bend specimens with controlled semielliptical surface cracks. The results are compared for two compositions of lead lanthanum zirconate titanate. One exhibits ferroelastic behavior, the other electrostrictive linear elastic behavior. R -curves are measured in the crack length regime of 0.1 to 0.8 mm. The ferroelastic composition displays a toughness increase from 0.5 to 1.2 MPa·m^1/2. The linear elastic composition displays a flat R -curve. The R -curve behavior is attributed to ferroelastic toughening.     

氧化铝闪速焙烧炉用轻质喷涂料的研制

对进口的两种喷涂料进行实物剖析 ,研究了结合剂、掺和料、颗粒级配对喷涂料性能的影响 ,开发出QC - 140P、CN - 4 0P两种轻、重质喷涂料 ,替代进口产品 ,应用于氧化铝闪速焙烧炉