可编程控制器应用于铁合金电炉配料系统

介绍了用于热兑法配料系统的可编程序控制器的组成、料批重量误差补正、控制方法，并介绍系统的应用程序。     

拓展青年岗位建功品牌内涵的探索与实践

新时代向国有企业共青团工作提出了新的挑战,国网安徽省电力有限公司团委坚持聚焦主责主业,把牢围绕中心、服务大局工作主线,找准共青团和青年工作的切入点和着力点,在有效组织带领青年服务大局、拓展青年岗位建功品牌的内涵等方面进行了探索实践,总结了相对完善的工作方法,形成了具有特色的青年岗位建功品牌“一团一工程”,彰显新时代国有企业共青团的定位和价值。     

T形配筋应变强化UHPC梁弯曲破坏机理

为分析应变强化UHPC梁弯曲破坏时UHPC和钢筋应变间关系,对5根梁试件进行了三分点加荷纯弯试验,试件变化参数为配筋率和钢筋种类.绘制了钢筋与应变强化UHPC的荷载-挠度曲线,将T形梁破坏过程分成3个阶段:弹性阶段、裂缝发展阶段、持荷至破坏阶段进行分析.并绘制了钢筋与应变强化UHPC的荷载-应变曲线,深入分析了在整个受弯过程中钢筋与UHPC的协同工作性.同时,结合UHPC和钢筋的应力-应变关系,将加载过程分为4个阶段,定量分析每个阶段钢筋和UHPC对抗弯承载力的贡献度.结果表明:钢筋达到屈服应变之前,钢筋与UHPC粘结可靠,保持应变一致性而共同受力;整个受弯过程中,应变强化UHPC抗拉强度提供的抗力与钢筋提供的相比占据重要比例(低配筋率时更大),建议在进行应变强化UHPC截面承载力计算时,应充分考虑UHPC抗拉强度的作用,保证承载能力计算方法的准确性.     

非饱和土大气张力通用公式与库仑土压力

推出大气张力库仑土压力的近似计算方法：假设临界破裂角为已知,可以考虑多层粘性土、坡面任意荷载、水和气压力。提出粘性土的结合水膜可靠连接面积率修正系数等于粘粒含量。推出大气张力库仑抗剪强度公式的Cm 形式,Cm 是膜的抗剪强度贡献。     

Speed of sound of ionic liquids: Database,estimation, and its application for thermal conductivity prediction

Speed of sound is an important thermodynamic property of ionic liquids (ILs) and always chosen as a source to determine other properties. A database for the speed of sound of pure ILs created by collecting experimental data from literature covering the period from 2005 to 2013 is presented. The effects of temperature and the alkyl chain length on the speed of sound are discussed and a second‐order corresponding states group contribution method is developed to estimate the speed of sound. An average absolute deviation (AAD) of 2.34% has been obtained. This method offers a simple but reliable approach to estimate the speed of sound of new ILs. Finally, the speed of sound is used to determine the thermal conductivity of ILs based on the Bridgman theory. The calculated values of thermal conductivity show a good agreement with the experimental ones with an AAD of 3.91%. © 2014 American Institute of Chemical Engineers AIChE J, 60: 1120–1131, 2014     

Ethanolysis of waste cottonseed oil over lithium impregnated calcium oxide: Kinetics and reusability studies

A series of Li/CaO catalysts has been prepared by impregnating 0.5–5.0 wt% Li in CaO by wet chemical method. Prepared Li/CaO catalysts have been characterized by powder X-ray diffraction, scanning electron and transmission electron microscopy and Brunauer–Emmett–Teller (BET) surface area studies, in order to establish the structure and surface morphology of the catalyst. Hammett indicator test study was performed to determine the basic strength of the Li/CaO catalysts. The prepared Li/CaO catalysts have been employed as a heterogeneous catalyst for the transesterification of waste cottonseed oil (having 2.8 wt% free fatty acid contents) with ethanol. Under optimal reaction conditions viz., ethanol/oil molar ratio of 12:1, catalyst to oil weight fraction of 5% and 65 °C reaction temperature, 98% fatty acid ethyl ester yield was obtained in 2.5 h of reaction duration. Under the optimized reaction conditions, the pseudo first order constant and Arrhenius activation energy were found to be 0.03 min⁻¹ and 70.0 kJ mol⁻¹, respectively. Further Li/CaO catalyst was also found to be effective for the ethanolysis and methanolysis of vegetable oils having up to 3.4 wt% free fatty acids. The use of 3-Li/CaO catalyst is advantageous considering that it not only utilizes waste cottonseed oil as a feedstock, but also renewable and nontoxic alcohol, ethanol, for the biodiesel production.     

DOPO‐Based Phosphorus‐Containing Methacrylic (Co)Polymers: Glass Transition Temperature Investigation

A two‐step synthetic procedure is designed for preparing new flame‐retardant methacrylic monomers containing 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) as a substituent side group. DOPO and methacrylate moieties are linked by linear aliphatic hydrocarbon spacers (3 to 11 carbon atoms). Copolymerization with methyl methacrylate is carried out leading to copolymers containing between 2 and 10 wt% phosphorus. All homo‐ and copolymers exhibit a unique glass transition temperature (T_g ). A new group contribution for DOPO‐based substituent is extracted that leads to reasonable estimations of T_g s of other published polymers. The Fox equation provides a good estimation of T_g s for most copolymers and for physical blends of poly(methyl methacrylate) (PMMA) and DOPO. When using monomers having three and four carbon atoms in the hydrocarbon spacer, the T_g of copolymers remains close to that of PMMA over a wide range of composition.     

企业开展矿山修复业务的几点思考

目前,中国矿山生态修复中存在诸多历史遗留问题。国家着手推动矿山治理和生态修复,已经取得了一些成效,但仍存在资金需求缺口大,修复后矿山土地使用确权、土地流转、开发利用等方面的问题。从国家政策支持、治理资金出资模式等方面对矿山修复进行了思考。