TEMPORAL AND SPATIAL DISCRETIZATION ON QUASI-3-D GROUNDWATER FINITE ELEMENT MODELLING TO AVOID SPURIOUS OSCILLATION

In this article, the finite element solution of quasi-three-dimensional (quasi-3-D) groundwater flow was mathematically analyzed. The research shows that the spurious oscillation solution to the Finite Element Model (FEM) is the results choosing the small time step ?t or the large element size L and using the non-diagonal storage matrix. The mechanism for this phenomenon is explained by the negative weighting factor of implicit part in the discretized equations. To avoid spurious oscillation solution, the criteria on the selection of ?t and L for quasi-3-D groundwater flow simulations were identified. An application example of quasi-3-D groundwater flow simulation was presented to verify the criteria. The results indicate that temporal discretization scale has significant impact on the spurious oscillations in the finite-element solutions, and the spurious oscillations can be avoided in solving practical quasi-3-D groundwater flow problems if the criteria are satisfied.     

难选高硫低品位硫化铅锌矿分选工艺研究与探讨

某难选高硫低品位硫化铅锌矿石,主要有价元素Pb、Zn、Fe和S含量分别为2.45%、2.76%、26.76%和30.63%,主要赋存矿物分别是方铅矿、铁闪锌矿和黄铁矿,含量分别为2.97%、4.76%和54.65%;矿石中方铅矿和铁闪锌矿含量较低,而黄铁矿含量超过55%,有用矿物含量差异极大;有用矿物间关系密切,存在相互共生和相互包裹,属于难选硫化铅锌矿石。为确定合理工艺流程,进行了全优先浮选、铅硫部分混合浮选及等可浮选等方案的对比试验研究。结果表明,全优先浮选得到的铅精矿Pb品位和锌精矿Zn品位均很低,通过该流程很难得到合格的铅精矿和锌精矿,主要原因为大量黄铁矿难以有效抑制,同时添加大量石灰调整pH对矿浆环境产生不利影响;铅硫部分混合浮选得到的铅精矿Pb品位偏低,但Zn回收率偏低,造成该问题主要原因为部分铁闪锌矿与黄铁矿存在连生未解离,同时大量铅硫混合精矿经再磨后黄铁矿难抑制;而等可浮选即铅硫等可浮+铅硫分离—锌硫等可浮+锌硫分离工艺流程可得到铅精矿Pb品位60.41%、Pb回收率82.38%,锌精矿Zn品位48.75%、Zn回收率81.59%的良好指标,该流程对大量黄铁矿进行了分段...     

Smaller,Stronger, More Stable: Peptide Variants of a SARS-CoV-2 Neutralizing Miniprotein

Based on the structure of a de novo designed miniprotein (LCB1) in complex with the receptor binding domain (RBD) of the SARS-CoV-2 spike protein, we have generated and characterized truncated peptide variants of LCB1, which present only two of the three LCB1 helices, and which fully retained the virus neutralizing potency against different SARS-CoV-2 variants of concern (VOC). This antiviral activity was even 10-fold stronger for a cyclic variant of the two-helix peptides, as compared to the full-length peptide. Furthermore, the proteolytic stability of the cyclic peptide was substantially improved, rendering it a better potential candidate for SARS-CoV-2 therapy. In a more mechanistic approach, the peptides also served as tools to dissect the role of individual mutations in the RBD for the susceptibility of the resulting virus variants to neutralization by the peptides. As the peptides reported here were generated through chemical synthesis, rather than recombinant protein expression, they are amenable to further chemical modification, including the incorporation of a wide range of non-proteinogenic amino acids, with the aim to further stabilize the peptides against proteolytic degradation, as well as to improve the strength, as well the breadth, of their virus neutralizing capacity.     

测试条件对聚氯乙烯树脂稀溶液粘数的影响

聚氯乙烯树脂稀溶液粘数是聚氯乙烯树脂的一项重要指标,它的高低决定着产品的不同用途。本实验测试了几种不同测试条件如测试温度、黏度计毛细管直径、溶剂浓度等对聚氯乙烯树脂稀溶液粘数结果所产生的影响,通过实验数据的理论分析和计算,对原因进行了具体的分析。这些分析结果的获得对提高粘数分析的准确性,对于指导实际生产,规范检验操作,修订检验标准都有着重要的意义。     

边际油田群的综合开发

本文回顾了国内外海上边际油田群的开发状况,从减少开发投资和提高油田群开发的经济性出发,提出了适合边际油田综合开发的技术和开发策略,简要介绍了边际油田群综合开发的最新研究动态。     

塔里木盆地志留系热液碎屑岩储层:证据、矿物组合及油气地质意义

根据岩心观察、扫描电镜、能谱分析、显微薄片观察及流体包裹体测温显示的岩石宏观与微观特征、矿物组合、自生矿物形成温度等,认为塔里木盆地存在热液碎屑岩储层.热液碎屑岩岩石学证据主要体现在塔中地区中1井志留系柯坪塔格组碎屑岩中发育的基性侵入岩夹层、热液角砾岩、热炙烤现象及热液溶蚀孔洞等;在塔里木盆地中部的塔中地区和顺托果勒地区柯坪塔格组可识别出3种热液矿物组合.综合前人研究成果,认为热液的侵入主要发生于二叠纪,造成储集岩孔隙流体离子环境紊乱,溶解作用的发生促进了次生孔隙发育,并沉淀了热液矿物,总体上改善了碎屑岩储层,是塔里木盆地柯坪塔格组碎屑岩储层不可忽视的影响因素.热液侵入对已形成的古油藏产生破坏作用,并在志留系沥青砂岩生成过程中产生重要作用.     

降低克劳斯硫磺中有机物含量的技术措施

结合川西北矿区净化厂实际,讨论了硫磺中有机物的来源,认为降低酸气中烃类和含胺量,适当提高硫回收装置燃烧温度,并控制克劳斯一级反应器和亚露点克劳斯反应器温度３４０℃左右时,能有效降低硫磺中有机物含量。     

事故氯处理装置的改进

山东华阳农药化工集团氯碱厂烧碱生产装置扩能的同时,事故氯处理装置由石灰水吸收事故氯改造为碱液吸收。改造后高效、安全、环保。     

碳富勒烯在水中的运动阻力特性研究

采用分子动力学(MD)方法,模拟了Cn(n=60,180,240,540),以及C60@C240富勒烯在水中的速度衰减过程,得到了它们的阻力-速度与阻力-雷诺(Re)数关系曲线;进而将MD模拟的阻力结果和低Re数宏观流体力学中球的Stokes阻力解进行了对比。研究表明,低Re数下,富勒烯在水中的阻力要比传统流体力学中球的Stoke解高两个数量级;富勒烯在水中的阻力可通过Stokes解乘以(110.38-1.48／Re)近似估算。     

进口硫磺对我国磷复肥工业发展战略的影响

根据近几年我国进口硫磺量的迅速增长,2005年进口量达830万t,占全球硫磺产量的1/5,导致国际硫磺价格猛涨,1997年硫磺到岸价在35~45美元/t,2005年已达94.4美元/t以上,分析国际硫磺价格猛涨对我国磷复肥发展的巨大影响,而我国2006~2007年还将增加硫磺制酸能力540万t。为此,提出几点应对策略,新建硫酸装置应采取一炉两用的原料路线,并提出必须大力挖掘国内硫资源。