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11.
The effect of Li2O on the crystallization properties of CaO-Al2O3-SiO2-Li2O-Ce2O3 slags was investigated. With increasing the Li2O content, LiAlO2 and CaCeAlO4 were the main crystalline phases. LiAlO2 formed for the charge compensating of Li+ ions to [AlO45?]-tetrahedrons, and CaCeAlO4 formed as a result of the charge balance of Ce3+ ions, Ca2+ ions, and [AlO69?]-octahedrons. Increasing the content of Li2O to 10%, the crystallization temperature was the highest, and the incubation time was the shortest. The crystallization ability was strong due to the three factors of strengthening the interaction between ions and ion groups, decreasing the polymerization degree, and increasing the melting temperature. Further increasing the content of Li2O, the crystallization performance was obviously suppressed, because the melting temperature and the force between the cations and the anion groups decreased. 相似文献
12.
Weiguo Cao Wenjuan Li Liang Zhang Jianfa Chen Shuo Yu Zhuanghong Zhou Yun Zhang Xiaobo Shen Yingxin Tan 《International Journal of Hydrogen Energy》2021,46(52):26693-26707
The explosion venting duct can effectively reduce the hazard degree of a gas explosion and conduct the venting energy to the safe area. To investigate the flame quantitative propagation law of explosion venting with a duct, the effects of hydrogen fraction and explosion venting duct length on jet flame propagation characteristics of premixed H2-air mixtures were analyzed through experiment and simulation. The experiment results under initial conditions of room temperature and 1 atm show that when hydrogen fraction was high enough, part of the unburned hydrogen was mixed with air again to reach an ignitable concentration, resulting in the secondary combustion was easier produced and the duration of the secondary flame increased. With the increase of venting duct length, the flame front distance and propagation velocity increased. Meanwhile, the spatial distribution of pressure field and temperature field, and the propagation process and mechanism of the flame venting with a duct were analyzed using FLUENT software. The variation of the pressure wave and the pressure reflection oscillation law in the explosion venting duct was captured. Therefore, in the industrial explosion venting design with a duct, the hazard caused by the coupling of venting pressure and venting flame under different fractions should be considered comprehensively. 相似文献
13.
《Ceramics International》2022,48(18):26233-26247
A new type of 3D-printable ‘one-part’ geopolymer was synthesized with fly ash (FA), granulated blast furnace slag (GBFS), steel slag (SS) and flue gas desulfurization gypsum (FGD). The effects of SS content (0–40%) on the rheological properties, 3D-printability, mechanical anisotropy and reaction kinetics of geopolymer were investigated. The yield stress and plastic viscosity monotonically decreased with the increasing SS content. Contrarily, the geopolymer with 10% of SS presented better extrudability, buildability and mechanical strength than those with 0, 20%, 30% and 40% of SS. This was mainly attributed to the conflicting influence of SS on geopolymerization, of which the OH? produced by hydration of SS raised the alkalinity of the reaction system and accelerated the dissolution of SiO44? and AlO45?, while the low reactivity prohibited the following polymerization process. Furthermore, the 3D-printed geopolymer presented more compact microstructure and less mechanical anisotropy thanks to the crosslinking of morphologically complementary products, including N(C)-A-S-H, C–S–H, AFt and CH, formed via synergistic reaction of FA-GBFS-SS-FGD system. 相似文献
14.
《Ceramics International》2022,48(8):10506-10515
The search for materials and methods capable of reducing human impacts on the environment is of utmost importance nowadays. This study's primary purpose was to analyze the technical feasibility of ceramic composites production utilizing Fundão Dam's Iron Ore Tailings (IOT), Blast Furnace Slag (BFS) from charcoal, and Foundry Sand (FS) as partial substitutes for the traditional raw materials – sand and clay – for application in building industry materials. The composites were molded in rectangular specimens and fired at temperatures of 900, 950, 1000, 1050, and 1200 °C. The developed materials were analyzed and characterized by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Thermogravimetry (TGA), and Differential Thermal Analysis (DTA). The obtained materials had flexural strength modulus of up to 12.19 MPa, water absorption ranging from 2 to 22%, linear shrinkage ranging from 0.02 to 6.50%, and apparent density ranging from 2.03 to 1.63 g/cm3. The study of the internal structure formation process revealed the formation of amorphous structures in the composites. The results demonstrated that these waste materials may be jointly used in construction materials, contributing to the reduction of natural resource extraction, besides enabling their correct disposal, minimizing environmental impacts, and improving the life quality of the surrounding communities. 相似文献
15.
Xianghui Wang Pengda Zhao Jianwei Chen Huizhong Zhao Kai He 《Ceramics International》2018,44(11):12162-12168
Al–Cr slag is the solid waste generated by the smelting of Cr metal. It presents a range of environmental hazards. This study addressed the corrosion resistance of Al–Cr slag containing chromium–corundum refractories to slags with different basicity. Herein, we provide suggestions for the use of Cr–corundum of different basicity in kilns. Al–Cr slag, brown fused Al2O3, and chrome green were used as the raw materials, with pure calcium aluminate cement being used as a binder. The brick samples, prepared using different blends of chrome green and corundum, were fired at 1600?°C, and subsequently subjected to a slag corrosion test. After corrosion by slag of different basicity, the phase composition and microstructure of the sample were analyzed by X-ray diffraction, energy dispersive spectrometer and scanning electron microscopy. There were two major findings. First, Cr–corundum brick made from Al–Cr slag has a better slag corrosion resistance than that made from Cr2O3 and brown fused Al2O3. Second, Cr–corundum brick made from Al–Cr slag has superior corrosion resistance to slag with a CaO:SiO2 ratio of 2:1. 相似文献
16.
《岩石力学与岩土工程学报(英文版)》2020,12(3):630-641
Structure is an evident determinant for macroscopic behaviors of soils. However, this is not taken into account in most constitutive models, as structure is a rather complex issue in models. For this, it is important to develop and implement simple models that can reflect this important aspect of soil behavior. This paper tried to model structured soils based on well-established concepts, such as critical state and sub-loading. Critical state is the core of the classic Cam Clay model. The sub-loading concept implies adoption of an inner (sub-loading) yield surface, according to specific hardening rules for some internal strain-like state variables. Nakai and co-workers proposed such internal variables for controlling density (ρ) and structure (ω), using a modified stress space, called tij. Herein, similar variables are used in the context of the better-known invariants (p and q) of the Cam Clay model. This change requires explicit adoption of a non-associated flow rule for the sub-loading surface. This is accomplished by modifying the dilatancy ratio of the Cam Clay model, as a function of the new internal variables. These modifications are described and implemented under three-dimensional (3D) conditions. The model is then applied to simulating laboratory tests under different stress paths and the results are compared to experiments reported for different types of structured soils. The good agreements show the capacity and potential of the proposed model. 相似文献
17.
北斗三星无源定位技术 总被引:6,自引:2,他引:4
介绍了北斗双星定位系统的特点、功能、系统组成和工作原理,说明了北斗有源定位方式在应用方面的局限性。针对北斗有源定位方式不能无线电静默,和人们对具有无线电隐蔽性的卫星定位的需求,详细介绍一种北斗三星无源定位技术:包括工作原理、实现方法、定位精度分析和目前达到的定位精度。阐述了北斗三星无源定位技术的优点和应用形势。 相似文献
18.
通过物理模型试验,研究了有植被的河道水流紊动特性.试验结果表明,在复式断面河道滩地种植柔性植被后,滩地糙率增大,水流紊动更为剧烈,河道水流紊动强度峰值由原先的滩槽交界区转移到滩地区.滩地的水流紊动强度沿程递减;滩槽交界区的水流紊动强度沿程不断增大;主槽的水流紊动强度主要与床面糙率有关,滩地植被影响了滩地水流的归槽时间,使主槽水流流速沿程增大. 相似文献
19.
20.
N-油酰基肌氨酸钠对除盐水缓蚀性能的探讨 总被引:1,自引:0,他引:1
梁劲翌 《石油化工腐蚀与防护》2006,23(1):17-20
对N-油酰基肌氨酸钠单体的缓蚀性能以及与常用除盐水缓蚀剂的协同作用作了探讨,发现在一定浓度下,单体对经过加氨调节后的高温除盐水(氨后除盐水)有良好的缓蚀作用,且与大多数除盐水缓蚀剂有良好的协同效应。在此基础上研制了一种复合药剂,并对其缓蚀、阻蚀性能作了研究。动电位极化曲线扫描图谱表明,该复合药剂属于抑制阳极腐蚀的阳极型缓蚀剂,其适用的水质条件为[Cl~-+SO_4~(2-)]不超过50 mg/L,pH不低于8.0;与阻垢剂复配,可以适用于含Ca~(2+)不超过45 mg/L的水质条件。 相似文献