Preparation and characterization of TiO2 photoelectrode codoped with aluminum and boron and its application in dye-sensitized solar cell

Nanocrystalline titania films codoped with aluminum and boron were prepared by cathodic vacuum arc deposition. In the process, titanium alloy target was used under an O2/Ar atmosphere, and sensitization of films were carried out by natural dye-sensitized complex in anhydrous ethanol. The structure, surface morphology and UV-vis spectra of titania films codoped were measured by X-ray diffraction analysis, scanning electron microscopy and ultraviolet-visible spectrometer. Theas-deposited films are found to be amorphous. The films annealed were examinedto be of anatase structure with orientation along the (101) planes, the averagecrystal size is in the range between 41 and 45 nm. SEM results show that thereare some pores in the codoped titania films, the optical properties of the dye-sensitized films were also measured which reveals that the spectral responses of films shift to the visible region. Under simulated sunlight illumination, the overall energy conversion efficiency of dye-sensitized nanocrystalline solar cell is 0.9%.     

低碳低合金铸钢力学性能的研究

利用Olympus光学显微镜、扫描电镜(SEM)及能谱分析(EDAX)探讨了等温淬火工艺对低碳低合金CrMnSi铸钢力学性能的影响,并通过XRD定量分析了相的组成.结果表明,合适的等温淬火工艺,可获得一定数量的贝氏体和残余奥氏体(约6%)的复合组织,冲击断口形貌由解理刻面变为韧窝状,铸造成形无缺口试样(10 mm×10 mm×55 mm)的冲击韧度由ακ≤30 J/cm2增加至ακ≥170 J/cm2,硬度HRC≥40,具有较高硬度和冲击韧度的配合.     

数控机床位置伺服在线调试与动态性能分析研究

介绍一种在数控机床位置伺服系统在线调试中应用系统动态性能分析方法的基本原理，给出了一种位置伺服系统动态响应曲线、动态性能分析及其主要技术指标的实例。     

THERMODYNAMICS AND PHASE EQUILIBRIUM OF Cu－Y－O，Cu－Y－S，Cu－Y－O－S LIQUID SOLUTIONS

ＴＨＥＲＭＯＤＹＮＡＭＩＣＳＡＮＤＰＨＡＳＥＥＱＵＩＬＩＢＲＩＵＭＯＦＣｕ－Ｙ－Ｏ，Ｃｕ－Ｙ－Ｓ，Ｃｕ－Ｙ－Ｏ－ＳＬＩＱＵＩＤＳＯＬＵＴＩＯＮＳ￥Ｄｕ，Ｔｉｎｇ；Ｌｉ，Ｇｕｏｄｏｎｇ（ＣｅｎｔｒａｌＩｒｏｎａｎｄＳｔｅｅｌＲｅｓｅａｒｃｈｉｎｓｔｉｔ...     

强腐蚀环境下锚索强度指标及表观特性试验研究

利用自行制做的试验装置,以配制出的强腐蚀环境土为介质,对非预应力锚索和预应力锚索的裸筋以及对有注浆缺陷的锚索试件进行了腐蚀试验,从外观腐蚀状况和腐蚀后的钢绞线力学性能的改变特性进行了研究.结果表明:从外观上看,预应力锚索试件的腐蚀程度总体上比非预应力试件的腐蚀程度要重,含注浆缺陷的锚索试件的腐蚀程度比裸筋的腐蚀程度要重...     

EVA-g-GMA的制备及其对PLA/PHBV共混物性能的影响

通过熔融聚合法先制备了乙烯-醋酸乙烯酯接枝甲基丙烯酸缩水甘油酯(EVA-gGMA),采用红外光谱仪和核磁共振对EVA-g-GMA的结构进行了表征。然后将不同质量分数的EVA-g-GMA加入到聚乳酸/聚(3-羟基丁酸酯-co-3-羟基戊酸酯)(PLA/PHBV)共混物中,对共混物的性能进行研究。结果表明:GMA成功接枝到EVA上,随着EVA-g-GMA加入量的增加,PHBV与PLA的Tg升高,结晶度逐渐下降;分散相在PLA基体中的分散逐渐均匀,粒径减小,相界面渐渐模糊;在EVA-g-GMA加入后,共混物粘度升高,断裂伸长率和冲击强度分别可达290.9%和43.5KJ·m-2,三元共混物的水蒸气阻隔性相对于PLA/PHBV略有下降。综合考虑各种因素,EVA-g-GMA的加入使得PLA/PHBV的整体性能得到极大改善。     

半固态触变挤压对ZA27合金组织和力学性能的影响

通过与常规铸造方法的比较,研究半固态触变挤压对ZA27合金变质、热处理组织和力学性能的影响。结果表明:半固态挤压态合金的密度较铸态合金提高了3%,合金经Sc变质或者半固态挤压都获得了细小而均匀的近似球状组织,而Sc变质结合半固态挤压的球状组织具有最高的圆整度;经T6热处理的半固态挤压合金由细小的初生α相和共析(α+η)组织组成,说明半固态挤压可促进ε相溶解、减少三元共晶(β+η+ε)组织的含量。力学性能测试表明,ZA27合金经半固态挤压+Sc变质+T6热处理后其抗拉强度,伸长率和布氏硬度分别达到586.01MPa,17.57%及171HB。     

Preparation of Porous Silver Nanowires-Melamine Formaldehyde Hybrid Composite Materials and Their Electromagnetic Shielding and Flame-Retardant Properties

Along with the booming development of communication technology and electronic equipment, higher requirements of flame-retardant and EMI shielding performances for electromagnetic interference (EMI) shielding materials are put forward. Herein, the ultralight and porous silver nanowires (AgNWs)-melamine formaldehyde (MF) hybrid composite with unique micro-/nanostructure is developed by a facile dip-coating method, which uses the AgNWs as 1D conductive coating and MF foam (MF foam) as 3D skeleton template. Benefiting from the unique porous micro-/nanostructure, the resultant hybrid composite displays low density, excellent EMI shielding performances, and superior flame-retardant property. The EMI shielding effectiveness (SE) and specific EMI SE (SSEt) of the hybrid composite in X-band (8.2–12.4 GHz) can be up to 77 dB and 26971.4 dB cm⁻² g⁻¹, respectively. At the same time, the hybrid composite also passes the vertical burning test and shows an increased LOI value of 40.6%. The combination of flame-retardant and EMI shielding performances for EMI shielding materials makes the AgNWs-MF hybrid composite great application potential in civil and military fields. This work provides a new guide for the design of multifunctional high-performance EMI shielding materials.     

马钢2500m~3高炉炉渣的冶金性能

在目前的原燃料条件下,为保证马钢2500m3高炉炉渣具有良好的流动性和较高的脱硫能力,炉渣的CaO／SiO2应控制在1．05至1．15之间,炉渣温度不低于1450℃．     

全固态裸露式Ag／AgCl参比电极的研制及应用

该文报道了一种树脂接界全固态裸露式Ag／Agcl参比电极,勿需电镀氯化,制备工艺简单,性能稳定,是对电解型Ag／AgCl参比电极的一大改进。可代替饱和甘汞电极作为通用型参比电极,同时可减少汞对环境所造成的二次污染,在温度大于75℃时仍能保持良好性能,突破了甘汞电极的局限。