Hydrothermal formation of dispersive Mg（OH）2 particles in NaOH solution

The hydrothermal modification of Mg(OH)2 crystals in NaOH solution was investigated. The aggregated Mg(OH)2 particles with irregular shape are converted to regular Mg(OH)2 hexagonal plates after hydrothermal treatment. The prolongation of reaction time from 1-4 h or the increase of temperature from 140℃ to 200℃ can promote the formation of Mg(OH)2 plates with big particle size but small cluster size. The dispersion characteristics of the hydrothermal products are improved owing to the improvement of Mg(OH)2 crystalline degree and the in-crease of I（001)/I（101） ratio. The proper hydrothermal modification condition is as follows: solid content 0. 075 g/mL,NaOH concentration 5.0 mol/L, temperature 200℃ and time 4 h. Thermodynamic analysis indicates that the increase of MgOH^ concentration at elevated temperature or the increase of OH^- concentration in concentrated NaOH solution is favorable for the hydrothermal formation of Mg(OH)2 particles.     

Melting behavior of magnesium alloy chips in thixomolding process

The samples were fabricated by 220 t thixomolded machine made by Japan Steel Works. The microstructure from the AZ91D magnesium alloy chips to the thixomolded products was investigated. Melting behavior of the chips in thixomolding process was analyzed. The evolution processing of solid phase morphology was studied, and evolution model was put forward. The results show that microstructures in outer zone of a chip and the inner zone are obviously different, and the severe distortion takes place in the brim of the chip, where the grains are observed to be bent, distorted, even broken. The severe plastic deformation region is firstly molten, then segregation area in the inner of the chip continues to melt. The liquid phase in solid phase does not formed by liquid entrapped during shearing process, but primarily induced by internal composition segregation.     

Hydrogen sorption properties of Mg-20wt.%Fe 23 Y8 composite prepared by reactive mechanical alloying

Mg-20wt.% Fe23Y8 composite was successfully prepared by reactive mechanical alloying (RMA). X-ray diffraction (XRD) measurement shows that the main phases of composite are MgH2 and Mg2FeH6. The composite exhibits excellent hydrogen abs/desorption properties and can absorb 4.36wt.% and 5.72wt.% hydrogen at 473 and 573 K in 10 min under 3.0 Mpa hydrogen pressure, respectively. The composite can desorb 5.27wt.% hydrogen at 573 K in 30 min under 0.02 Mpa hydrogen pressure. Compared with the pure MgH2, the hydrogen desorption temperature of Mg-20wt.% Fe23Y8 composite is decreased about 40 ℃. It is supposed that both the catalyst effect of Fe-Y distributed in Mg substrate and the crystal defects play the main role in improving hydrogen sorption properties of Mg-20wt.% Fe23Y8 composite.     

Nonclassical constitutive model involving void evolution of casting magnesium alloy

The void evolution equation and the elastoplastic constitutive model of casting magnesium alloy were investigated. The void evolution equation consists of the void growth and the void nucleation equations. The void growth equation was obtained based on the continuous supposition of the material matrix, and the void nucleation equation was derived by assuming that the void nucleation follows a normal distribution. A softening function related to the void evolution was given. After the softening function was embedded to a nonclassical elastoplastic constitutive equation, a constitutive model involving void evolution was obtained. The numerical algorithm and the finite element procedure related to the constitutive model were developed and applied to the analysis of the distributions of the stress and the porosity of the notched cylindrical specimens of casting magnesium alloy ZL305. The computed results show satisfactory agreement with the experimental data.     

先进的搅拌摩擦焊

搅拌摩擦焊是利用一种特殊形式的搅拌头边旋转边前进，通过搅拌头与工件的摩擦产生热量，摩擦热使该部位金属处于热塑性状态，并在搅拌头的压力作用下从其前端向后部塑性流动，从而使待焊件压焊为一个整体。它可以焊接所有牌号的铝合金以及用熔焊方法难以焊接的材料，并突破了普通摩擦焊对轴类零件的限制。由于搅拌摩擦焊是固态焊接，所以没有熔化焊时的气孔、裂纹等缺陷。搅拌摩擦焊的接头性能普遍优于熔化焊的。     

镁合金的生产及应用

主要介绍了镁及镁合金的性能及在汽车、电子等工业中的应用，并讨论了镁合金的铸造技术及发展。     

RE对Mg-8Zn-4Al-0.3Mn合金组织的影响

研究了RE对Mg-8Zn-4Al-0．3Mn铸造镁合金显微组织的影响。结果表明：Mg-8Zn-4Al-0．3Mn-χRE铸造镁合金的显微组织主要由口(Mg)基体、φ(Al2Mg5Zn2)相、r(Mg32(Al,Zn)49)相和Mg3Al4Zn2RE相组成。随RE加入量的增加，合金晶界上三元相的形态由半连续网状改变为颗粒状，三元相的分布逐渐变得弥散而均匀。晶界上针状或棒状Mg3Al4Zn2RE相的量也随着RE加入量的增加而增加。加入1．5％的RE可显著细化合金的铸态组织，晶粒大小由120～130μm减小到40-50μm。合金的显微硬度值随着RE加入量的增加而增加。     

Pre-Activation of CO2 at Cobalt Phthalocyanine-Mg(OH)2 Interface for Enhanced Turnover Rate

Cobalt phthalocyanine (CoPc) anchored on heterogeneous scaffold has drawn great attention as promising electrocatalyst for carbon dioxide reduction reaction (CO₂RR), but the molecule/substrate interaction is still pending for clarification and optimization to maximize the reaction kinetics. Herein, a CO₂RR catalyst is fabricated by affixing CoPc onto the Mg(OH)₂ substrate primed with conductive carbon, demonstrating an ultra-low overpotential of 0.31 ± 0.03 V at 100 mA cm⁻² and high faradaic efficiency of >95% at a wide current density range for CO production, as well as a heavy-duty operation at 100 mA cm⁻² for more than 50 h in a membrane electrode assembly. Mechanistic investigations employing in situ Raman and attenuated total reflection surface-enhanced infrared absorption spectroscopy unravel that Mg(OH)₂ plays a pivotal role to enhance the CO₂RR kinetics by facilitating the first-step electron transfer to form anionic *CO₂⁻ intermediates. DFT calculations further elucidate that introducing Lewis acid sites help to polarize CO₂ molecules absorbed at the metal centers of CoPc and consequently lower the activation barrier. This work signifies the tailoring of catalyst-support interface at molecular level for enhancing the turnover rate of CO₂RR.     

透明吸波体综述北大核心CSCD

吸波体是一种带有损耗特性的周期结构,能够吸收电磁波,将电磁能转化为热能,降低反射的电磁波能量。随着应用场景的特殊化,吸波体朝着特殊领域、特定功能、更具针对性的方向发展。由于各类含有光学窗口的应用环境对抗电磁干扰需求的不断提高,吸波体光学透明化成为研究的重点方向。为了对透明吸波体的发展状况有系统的认识,文章以制造材料为脉络梳理了近年来可见光透明吸波体的研究现状,包括氧化铟锡(ITO)、金属网栅、石墨烯等,综述了以它们为材料制备的透明吸波体优缺点以及发展趋势,最后对透明吸波体的未来发展进行了展望。