GCr15钢制钉模复合强韧化工艺研究

通过失效分析和脆断机理研究，对制钉模的失效原因进行了深入分析，在此基础上对复合处理工艺进行了改进；改进后复合处理的G015钢制钉模具有较高的强度和韧性，基本上避免了早期脆性断裂。     

Martensitic stabilization and defects induced by deformation in TiNi shape memory alloys

Martensitic stabilization caused by deformation in a TiNi shape memory alloy was studied.Special attention was paid to the deformed microstructures to identify the cause of martensitic stabilization.Martensitic stabilization was demonstrated by differential scanning calorimetry for the tensioned TiNi shape memory alloy.Transmission electron microscopy revealed that antiphase boundaries were formed because of the fourfold dissociation of[110]B19'super lattice dislocations and were preserved after reverse transformation due to the lattice correspondence.Martensitic stabilization was attributed to dislocations induced by deformation,which reduced the ordering degree of the microstructure,spoiled the reverse path from martensite to parent phase compared with thermoelastic transformation,and imposed resistance on phase transformation through the stress field.     

Analysis of thermodynamics and kinetics of titanium between top slag and liquid steel

Titanium is an impurity element in some special steel grades.The existence of titanium decreases the grain size and lowers the yield strength,resulting in low quality of these steels with regard to various properties.Thus,the titanium content should be reduced to the minimum.Based on the industrial production of ultra-low carbon Al-Si killed steel,this paper investigated the physical-chemical behaviors of titanium with and without desulfurization during RH refining.The influences of Ti content in hot metal,ladle slag composition,and ladle slag quantity,etc.,on the Ti content in refined liquid steel were discussed.The results show that the partition ratio of titanium between ladle slag and liquid steel is inversely proportional to the Al content to the power of 4/3,and the empirical formula regressed from practical experience can be expressed as w(TiO2)/w[Ti]=48/w[Al]4/3.Maximum partition ratio of titanium between top slag and liquid steel can be ensured by an optimum slag composition including components of FeOx and Al2O3 and an appropriate slag basicity.The contents of FetO and Al2O3 should be controlled above 6% and below 20% respectively and the slag basicity should be kept within 1.5 to 3.0.Moreover,desulfurization refining in the RH vacuum will decrease the partition ratio of titanium between ladle slag and liquid steel significantly.To keep the Ti content stably below 15×10-4% in a 300 ton ladle,the Ti content in hot metal must be lower than 500×10-4% and the thickness of ladle slag carried over from BOF slag must be less than 50 mm.     

热镀锌钢板生产概述：第五讲 热镀锌钢板生产工艺简介

钢板热镀锌自实现了工业化生产以来,由单张多板热镀锌,线外退火的钢板热镀锌到在线退火连续热镀锌,其生产工艺及设备经历了不断的革新和进步,介绍了各种镀锌方法的工艺及应用情况。     

安钢小方坯连铸高效化改造

介绍了安阳钢铁集团有限公司（以下简称安钢）二炼小方坯基本情况,高效化改造的原因,所采取的主要技术措施,以及实施高效改造后取得的效果。     

Corrosion of a stainless steel handrail

AISI 304 and 304L stainless steels are “workhores” grades of austenitic stainless steel frequently used in architectural applications, as well as in cookware, appliances, and numerous other applications where resistance to corrosion is required. This paper examines a corrosion failure (the appearance of rustlike stains on the surface) of a 304 stainless steel handrail that appears to have occurred as a result of contamination during the fabrication process.     

多弧离子镀与磁控溅射共沉积TiN/TiCN多层膜的高温抗氧化性能

TiN/TiCN多层膜的高温抗氧化性研究对于扩大其应用领域具有重要作用,但目前鲜见相关报道。采用多弧离子镀与磁控溅射技术以不同调制周期在304不锈钢表面共沉积TiN/TiCN多层膜。采用XRD、XPS、倒置显微镜及高温氧化试验研究了多层膜的高温抗氧化行为。结果表明:TiN/TiCN多层膜表面光滑平整、均匀致密,薄膜主要为具有Ti-(C,N)键的fcc-TiN结构;随着调制周期的减小,TiN/TiCN多层膜生长取向发生转变,且具有(111)晶面生长织构;随着氧化温度的升高,多层膜的显微硬度逐渐降低,氧化增重速率不断增大,且在700℃之后变化速率较快,薄膜的开始氧化温度约为750℃;随着调制周期的减小,多层膜TiN与TiCN界面层数量增多,促使晶粒细化,提高了其致密性,还隔断了缺陷贯穿薄膜的连续性,显著降低了薄膜的孔隙率,致使O原子扩散困难,增强了薄膜的高温抗氧化性能。     

钢渗铬层上金刚石薄膜的表面、界面结构及附着性

在钢渗铬层表面用化学气相沉积(CVD))法制备了金刚石薄膜.使用扫描电镜(SEM)、透射电镜(TEM)和压痕法研究了金刚石膜的表面、界面结构及附着力.用拉曼光谱分析了金刚石膜的纯度及非金刚石碳相.甲烷含量超过0.6%(体积分数)后,金刚石膜为球形纳米晶,形核密度＞107cm-2.用甲烷含量为0.6%(体积分数)沉积的金刚石膜表面的残余压应力为1.22 Gpa,而膜背面的残余压应力更高,达2.61 Gpa.压痕显示在19.6 N载荷下膜发生开裂.TEM观察发现,膜/基界面为微观非平面,有利于提高金刚石膜的附着力.     

施威德勒型单层球面网壳结构抗火的非线性有限元分析

根据ISO-834标准升温曲线与结构钢强度和刚度随温度的变化曲线,采用非线性有限元法对不同的矢跨比的施威德勒型单层球面网壳结构进行了抗火分析,得到了一些结果,可为经济、科学的结构综合防火设计提供理论依据.