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991.
The atomic-bridging type negative oxide charge in SiO2 is investigated using the Fe-contaminated (001) surface of n-type Si wafers. The investigation is done on the basis of a chemical analysis and a method in which the frequency-dependent alternating current (AC) surface photovoltage (SPV) is measured. At room temperature, an AC SPV appears and gradually increases, saturating after approximately one day (with an Fe concentration on the Si surface of 4.0 × 1013 atoms/cm2). The AC SPV eventually becomes inversely proportional to frequency except at very low frequencies (< 10 Hz) corresponding to weak or strong inversion, indicating that the negative Fe induced oxide charge appears in the form of a (FeOSi)− network. Also, in Fe-contaminated n-type Si(001) surfaces thermally oxidized at between 550 and 650 °C for 60 min, strong inversion is unquestionably observed, proving that the (FeOSi)− network survives and that most of the added Fe has segregated into the region closest to the surface of the thin SiO2 film. At 850 °C and/or for long oxidation times, the AC SPV decreases and ultimately disappears, implying that the (FeOSi)− network has collapsed and may have changed into Fe2O3. A model for the metal-induced negative oxide charge in the conventional oxide charge diagram is proposed. 相似文献
992.
对于振动工程中常见的极低频、极短时、极高频(接近奈奎斯特频率)等极端频率信号,常用的离散频谱分析与校正方法存在较大误差.对极端频率信号的典型情形进行了分析,针对极端频率信号中的极低频信号,提出了一种计及负频率成分干涉影响的离散频谱校正新方法.该方法基于Blackman窗,利用局部谱峰附近的三条谱线,建立包含正负频率贡献的离散频谱校正模型,通过对模型的求解获得频率、幅值和相位校正公式.采用频段内扫描的方式对频谱校正公式进行了仿真验证,结果表明所提方法有效降低了负频率成分的干涉影响,对极低频信号的频率、幅值和相位校正有较高的精度. 相似文献
993.
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995.
Morihiro SaitoKenta Nakai Tomoyuki YamadaToshio Takenaka Makoto HirotaAkika Kamei Akimasa TasakaMinoru Inaba 《Journal of power sources》2011,196(16):6637-6643
Pure Si platelets and Ni or Cu layer-laminated Si platelets with difference thickness were prepared, and their charge/discharge properties were examined in 1 M LiClO4/EC + DEC (1:1 by volume) as alternative negative electrode materials to graphite for Li-ion batteries. The shape of thin platelets and lamination with Ni layer are significantly effective to improve the cycleability in Li-Si alloy system by relieving the stress during the alloying/de-alloying processes, reinforcing the mechanical strength and reducing the Li+ ion diffusion length. Moreover, the first irreversible capacity is minimized by reduction of the amount of Ketjen Black (KB) in the composite electrode because of electrolyte decomposition on the surface of KB. Consequently, the Si/Ni/Si-LP30 (30/30/30 nm) composite electrode with 5 wt% KB also exhibits over 700 mAh g−1 even after 50 cycles in 1 M LiPF6/EC + DEC (1:1). 相似文献
996.
Hoyt Tim; Pasupathi Monisha; Smith Bruce W.; Yeater Elizabeth A.; Kay Virginia S.; Tooley Erin 《Canadian Metallurgical Quarterly》2010,17(1):78
The disclosure of emotional events to various social intimates (disclosure targets) was measured in 2 samples (soldiers and first responders) at risk for posttraumatic stress disorder (PTSD), as well as a comparison sample of college students. These 3 groups completed survey measures of disclosure, and at risk groups also completed measures of PTSD symptoms and social support. Groups at risk for PTSD were less likely to disclose emotions related to potentially traumatic events than were college students reporting general emotional disclosure. Overall, disclosure of positive emotions was more likely than disclosure of negative emotions. Furthermore, amount of disclosure depended on the person to whom the individual disclosed. Within groups at risk for PTSD, social support was associated with lower levels of PTSD. However, this relationship was mediated by emotional disclosure to each target. Disclosure of positive emotions generally was associated with lower levels of PTSD, and disclosure of negative emotions to those with similar at-risk status was associated with greater levels of PTSD. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
997.
介绍了广钢转炉一次除尘系统的设备及工艺改进。广钢针对其转炉除尘系统存在的问题,通过加强转炉煤气回收各项措施的落实,净化了转炉烟气,提高了一氧化碳含量,实现了转炉负能炼钢。 相似文献
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999.
针对掘进局部通风中大角度转弯巷道存在通风阻力大,漏风大的问题,提出了用负压风筒解决掘进巷道大角度转弯巷道中局部通风存在的问题,成功应用在实际工作中,并在掘进工作面推广应用。 相似文献
1000.
The author offers a 40-year perspective on the observation and study of negative effects from psychotherapy or psychological treatments. This perspective is placed in the context of the enormous progress in refining methodologies for psychotherapy research over that period of time, resulting in the clear demonstration of positive effects from psychological treatments for many disorders and problems. The study of negative effects—whether due to techniques, client variables, therapist variables, or some combination of these—has not been accorded the same degree of attention. Indeed, methodologies suitable for ascertaining positive effects often obscure negative effects in the absence of specific strategies for explicating these outcomes. Greater emphasis on more individual idiographic approaches to studying the effects of psychological interventions would seem necessary if psychologists are to avoid harming their patients and if they are to better understand the causes of negative or iatrogenic effects from their treatment efforts. This would be best carried out in the context of a strong collaboration among frontline clinicians and clinical scientists. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献