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91.
Al2O3/TiB2/SiCW陶瓷刀具加工镍基合金时的磨损机理研究 总被引:5,自引:0,他引:5
研究了Al2O3/TiB2/SiCW陶瓷刀具加工Inconel718镍基合金时的切削性能和磨损机理。结果表明;在低速切削条件下,Al2O3/TiB2/SiCW和硬质合金刀具的抗后刀面磨损的能力相差不大;而在高速切削条件下,前者的抗后刀面磨能力远高于后者。 相似文献
92.
The activities of several commercial nickel catalysts were determined by measuring their activation energies. Among these
catalysts, G95E, Resan 22, Nysosel 222 and 325, all with low activation energy, were more active than DM3 and G95H, which
had higher activation energy. However, the less active catalysts increased the linoleate selectivity of soybean oil during
hydrogenation. The yields of bothtrans isomers and winterized oil were higher for the more selectively hydrogenated oil catalyzed by the less active catalysts.
In the sensory evaluation, the fractionated solid fat that contained moretrans isomers was lower in flavor scores than the fractionated liquid oil after hydrogenation and winterization of soybean oil. 相似文献
93.
Nickel electrodes were prepared by electrodeposition in electrolytes of various anionic compositions. The deposition conditions and bath types were evaluated with special emphasis on the electrocatalytic properties for the oxygen evolution reaction (OER). Electrochemical characterizations in a 5 mol/L KOH solution at 25°C showed that the electrode deposited from the chloride bath, having a low Tafel slope of 50 mV/dec and an overpotential of 396 mV at 100 mA/cm2, is the most catalytically active among electrodes prepared in electrolytes of various anionic compositions. The electrode activity for the OER is related to the real surface areas, which depend on the anion compositions in the deposition bath and the deposition conditions. 相似文献
94.
光亮镀镍液的pH值控制得稳定否,对于镀层质量有重要的影响,本文介绍了在电镀生产过程中,对镀镍液的pH值进行自动控制的一个计算机系统,该系统在广州五羊自行车厂电镀车间投入使用后,镀件质量有了明显的提高。 相似文献
95.
报道[Ni(H2O)6](ClO4)2·2H2O的合成、晶体结构,单核镍(Ⅱ)配合物[Ni(IDB)2][C6H4(OH)COO]·ClO4·CH3CH2OH·H2O[配体IDB为N,N 二(2 苯并咪唑亚甲基)胺]的电化学性质,探讨标题配合物催化尿素水解的机理。X射线单晶衍射表明,[Ni(H2O)6](ClO4)2·2H2O晶体属单斜晶系,P2(1)/C空间群,化学式:Cl2H16O16Ni,Mr=401.74,晶胞参数:a=0.62383(12)nm,b=1.2464(3)nm,c=0.91845(18)nm,α=90°,β=106.93(3)°,γ=90°,V=0.6832(2)nm3,Z=2,F(000)=412,S=1.079,DC=1.953g/cm3,μ=1.890mm-1。最终因子R[I>2σ(I)]:R1=0.0423,wR2=0.1155;R(全部数据)∶R1=0.0506,wR2=0.1180。结构分析表明,[Ni(H2O)6](ClO4)2·2H2O的镍(Ⅱ)分别与6个H2O配位形成对称的正八面体构型。循环伏安实验说明,标题配合物在DMF溶液中在E1/2=0.884V处经历了一个准可逆的一电子氧化还原过程。 相似文献
96.
Electrochemical parameters of the nanoporous carbide-derived carbon|organic electrolyte have been studied by cyclic voltammetry and electrochemical impedance spectroscopy. The gas adsorption measurements have been used for evaluating the specific surface area, pore size distribution and porosity as the essential parameters influencing the double layer performance of carbon. The region of ideal polarizability, values of series and parallel resistance, capacitance and other important electrical double layer parameters were established. It was shown that specific capacitance of typical nanoporous carbon derived from titanium carbide is in the range of 70-90 F cm−3 or 100-130 F g−1 and it depends on the synthesis conditions. The influence of the electrolyte solvent to the capacitance was insignificant, although acetonitrile was advantageous with respect of smaller viscosity. 相似文献
97.
In this article we describe our recent efforts in the area of palladium- and nickel-catalysed aromatic substitution reactions. Main focus is on low cost and low waste production methods. The use of aromatic carboxylic anhydrides in the Heck reaction leads to a waste-free protocol. In addition these reactions are easy to work up as no ligands or bases are used. For Heck reactions where substrates or products do not tolerate high temperatures we found that use of a bulky phosphoramidite (13b) as ligand for palladium leads to a very fast reaction at low temperatures. Recycle of palladium in ligand-free Heck and Suzuki reactions is easily accomplished by treating the palladium black that precipitates at the end of the reaction on a carrier material with a small excess of I2 prior to its re-use in the next run. Use of aryl chlorides in the palladium- and nickel-catalysed formation of biaryls can be accomplished by using the nickel-catalysed coupling with arylzinc chlorides. Better still, it was possible to make use of the arylgrignard and use a catalytic amount of ZnCl2. Whereas the strength of these aromatic substitution reactions lies in their broad tolerance of functional groups, one exception was the Sonogashira reaction on 3-bromoaniline. The problem was solved by making use of in situ catalytic protection of the NH2 group with benzaldehyde. 相似文献
98.
铝电解电容器用新型宽温高压工作电解液 总被引:3,自引:0,他引:3
采用异癸二酸铵为主溶质,乙二醇和γ-丁内酯为复合溶剂,制备新型宽温(-40~105℃)、高压(400 V)铝电解电容器工作电解液,并检测了该电解液和用该电解液生产的电解电容器的性能。测试结果表明,该工作电解液25℃时电导率达到1.6 mS/cm,闪火电压为480 V,-40℃下未见晶体析出;CD 110/400 V铝电解电容器试样的漏电流≤10μA,损耗0.03,容量变化率只有-3%。经过105℃高温贮存250 h后各项电气性能不仅优于国家标准,而且能达到严格的企业标准。 相似文献
99.
100.