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41.
This paper presents the results of an experimental investigation undertaken to evaluate different purging solutions to enhance the removal of multiple heavy metals, particularly chromium, nickel, and cadmium, from a low buffering clay, specifically kaolin, during electrokinetic remediation. Experiments were conducted on kaolin spiked with Cr(VI), Ni(II), and Cd(II) in concentrations of 1,000, 500, and 250 mg/kg, respectively, which simulate typical electroplating waste contamination. A total of five different tests were performed to investigate the effect of different electrode purging solutions on the electrokinetic remedial efficiency. A constant DC voltage gradient of 1 V/cm was applied for all the tests. The removal of heavy metals from the soil using tap water as the purging solution was very low. When 1 M acetic acid was used as the purging solution in the cathode, the removal of chromium, nickel, and cadmium was increased to 20, 19, and 13%, respectively. Using 0.1 M ethylene diamine tetraacetic acid as the purging solution in the cathode, 83% of the initial Cr was removed; however, the nickel and cadmium removal was very low. A sequentially enhanced electrokinetic remediation approach involving the use of water as a purging solution at both the anode and cathode initially, followed by the use of acetic acid as the cathode purging solution and a NaOH alkaline solution as the anode purging solution was tested. This sequential approach resulted in a maximum removal of chromium, nickel, and cadmium of 68–71, 71–73, and 87–94%, respectively. This study shows that the sequential use of appropriate electrode purging solutions, rather than a single electrode purging solution, is necessary to remediate multiple heavy metals in soils using electrokinetics. 相似文献
42.
五年来我国有色金属工业结构调整状况及对策建议 总被引:2,自引:0,他引:2
本文总结了近5年来我国有色金属工业结构调整和产业升级的基本情况,即中国有色金属工业集约化程度、技装备水平提高,生产成本下降,行业整体实力增强。而这些成绩的取得都有赖于国家积极的财政政策及“债转股”政策的推动,有赖于深化企业改革及发挥市场资源配置的作用等等。同时,针对对当前及今后有色金属工业结构调整和产业结构升级所面临的问题,提出了有关对策建议 相似文献
43.
E. Gorges L. M. Raez A. Schillings I. Egry 《International Journal of Thermophysics》1996,17(5):1163-1172
Electromagnetic levitation is a useful tool for measuring thermophysical properties of high-temperature melts such as liquid metals. Due to its noncontact nature, the undercooled regime is also accessible. Density and thermal expansion of a levitated drop can be derived from volume measurements, if its mass is known. Assuming cylindrical symmetry, the volume of a drop can be determined from its cross section. Using photography, such measurements on liquid metals have been performed in the past. Here we present an improvement of this method, which replaces the photographic camera with a CCD videocamera and subsequent digital image processing. This reduces the time effect required to obtain the results and allows one to average over disturbing surface oscillations. The specific problems of digital image processing, namely resolution and edge detection, are addressed and results on nickel are presented.Paper presented at the Fourth International Workshop on Subsecond Thermophysics, June 27–29, 1991, Köln, Germany. 相似文献
44.
Wiera Oliferuk Andrzej Korbel Maciej W. Grabski 《Materials Science and Engineering: A》1996,220(1-2):123-128
The mechanism of slip and its consequence in the process of energy storage during uniaxial tension of austenitic steel was studied. The interpretation of the energy storage process in terms of the slip development and microscopic shear band formation is presented. 相似文献
45.
Andrea Engl Benno Kunz 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,63(3):257-261
Studies took place to investigate the effects of different nutrient conditions on the biosorption ability and selectivity of heavy metals by Saccharomyces cerevisiae. After having grown in media supplemented with additional glucose, ammonium, phosphate or cysteine, the yeast was exposed to an equimolar solution of lead, cadmium, zinc and copper. Lead removal from a mixed solution was significantly higher than that of copper, followed by zinc and cadmium. Generally, yeasts from cysteine-rich media showed greatest sorption capacity whereas phosphate addition influenced zinc selectivity. In addition, glucose, fructose and sucrose as carbon sources were examined. Cultures grown in glucose had a better uptake than those cultivated with fructose at an incubation time of 30 min. 相似文献
46.
47.
Human urine - Chemical composition and fertilizer use efficiency 总被引:2,自引:0,他引:2
Stored human urine had pH values of 8.9 and was composed of eight main ionic species (> 0.1 meq L–1), the cations Na, K, NH4, Ca and the anions, Cl, SO4, PO4 and HCO3. Nitrogen was mainly (> 90%) present as ammoniacal N, with ammonium bicarbonate being the dominant compound. Urea and urate decomposed during storage. Heavy metal concentrations in urine samples were low compared with other organic fertilizers, but copper, mercury, nickel and zinc were 10–500 times higher in urine than in precipitation and surface waters. In a pot experiment with15N labelled human urine, higher gaseous losses and lower crop uptake (barley) of urine N than of labelled ammonium nitrate were found. Phosphorus present in urine was utilized at a higher rate than soluble phosphate, showing that urine P is at least as available to crops as soluble P fertilizers. 相似文献
48.
以江苏省南通市为研究区,利用采样点实测数据,借助GRNN神经网络模型并结合3S技术对农田土壤重金属的空间动态分布进行了深入研究。结果表明,GRNN神经网络模型能够智能地学习各个采样点的空间位置与该点各重金属含量之间的映射关系,并能够稳健地对各个空间插值点处的土壤重金属含量进行预测;结果显示南通市农田土壤重金属污染总体较轻,但也存在局部地区的严重污染。在运用GRNN神经网络模型进行空间插值了解重金属空间动态分布的基础上,可以根据污染的状况确定农产品的生产布局和规划。 相似文献
49.
Two commercial SCR catalysts, with a nominal W content of about 9 wt.% and a V nominal content of 0.55 and 1.8 wt.%, respectively, were contacted with different amounts of Na and K and with HCl vapours in order to simulate poisoning by species more specifically contained in exhaust gases from MSW combustion. Catalysts were characterised using XRD analysis, SEM/EDX analysis, BET and pore size distribution measurements, NH3 TPD, TG analysis. Poisoning agents do not cause loss of surface area nor pore occlusion. A significant loss of surface acidity was observed upon alkali metals poisoning whereas a decreasing of vanadium content was observed for the more concentrated catalysts upon HCl poisoning. Catalysts deactivation is proportional to the number of acid sites neutralised by alkali metals adsorbing ammonia in the temperature range typical of SCR process. HCl promotes the formation of new acid sites showing a lower activity compared to the original one. 相似文献
50.