从砷华生产废渣中回收铁

砷华生产废渣中Fe质量分数达45.6%,氧化焙烧脱硫后,可采用还原焙烧-磁选方法回收其中的铁。在焙烧温度550℃,焙烧时间30 min,废渣粒度97μm条件下,铁精砂回收率63.7%,其中Fe质量分数为65.2%。     

硫酸渣脱硫制备高品质铁精矿研究进展

利用硫酸渣脱硫制备高品质铁精矿具有良好的的工业利用价值,不仅可以解决烧渣的综合利用问题,而且可以解决其对环境影响的问题.本文系统介绍了硫酸渣脱硫制备高品质铁精矿的脱硫技术方法、工艺流程及最新研究进展.硫酸渣脱硫方法主要有化学法、联合法和生物法.化学法主要包括酸浸、碱浸,联合法可分为碱浸-酸浸、浮选-磁选、重选-浮选、磁化焙烧-磁选等联合工艺方法.比较了这些方法的工艺路线及存在的优缺点,提出了生物法具有良好的工业应用前景,展望了该方法未来的研究方向为：高效脱硫菌种的选育,生物脱硫液的循环使用,硫酸渣生物脱硫协同回收有价金属,生物脱硫过程基础理论及工程化技术研究等.     

辽河油田杜84块H2S成因探讨

辽河油田杜84块超稠油由蒸汽吞吐转为蒸汽辅助重力泄油（SAGD）开发后,产生了较高浓度的H₂S,导致脱硫设施投入和油气处理成本增加。通过原油、伴生气、地层水和储层矿物地球化学测试分析,H₂S产量与原油含硫量、地层水SO₄^2-浓度无明显相关性,而与储层中黄铁矿含量一致性强,黄铁矿中的硫属于生物来源,同位素范围与原油基本一致,起源于原油稠化阶段,大量形成于稠油热采阶段。高温高压热模拟实验表明,注蒸汽热力采油过程中,除含硫有机质热裂解（TDS）和硫酸盐热化学还原反应（TSR）外,黄铁矿氧化分解也是H₂S形成途径之一,当注入低矿化度蒸汽对地层水稀释后,SO₄^2-浓度下降,黄铁矿分解是H₂S的主要生成途径,H₂S的生成和分布受控于油藏地质条件、开发方式、开发时间和受热温度。     

铜冶炼烟气中含砷铜颗粒物的形成与硫酸盐化分解机理

铜冶炼余热回收锅炉中含有大量的砷铜颗粒物,其砷和铜的原位分离对环境风险控制和有价资源回收至关重要.模拟含砷铜颗粒物的形成,提出黄铁矿原位分解含砷铜颗粒物的新方法,并证实其分解机理.结果表明,在模拟余热锅炉中形成砷含量较高的颗粒物,且以砷酸铜物相为主.黄铁矿促进铜的硫酸盐化,导致砷酸铜的原位分解.在此过程中,砷以气态形式...     

某地硫酸渣选铁试验研究

近几年来,我国钢铁工业发展迅猛,铁矿石资源短缺的矛盾较为突出。硫酸渣在我国储量大,是铁矿石的重要补充资源。为此,对某地硫酸渣选铁进行了小型连选试验研究。结果表明,在无需磨矿、入选品位50．03％的情况下,采用筛分抛粗-水力旋流器抛细-单-重选工艺流程,可获得铁精矿品位66．86％、产率28．26％、尾矿铁品位43．40％、回收率37．77％的较为理想的指标。目前已在某地应用,效果较为理想。     

Calcium-activated geopolymer ceramics: Study of powder calcination and amorphous gel phases

Burnt coal cinder (BCC), the main solid waste in coal and electric power industries was used to prepare the geopolymer ceramics (GC) in this study. The optimum preparation technology of BCC-based GC and the effects of calcination and calcification on the compressive strength of BCC-based GC were studied. Through the calcification of BCC with CaO, NaAlO₂ and sodium silicate solution (SS) were separately used as the co-activator and silica additive to prepare BCC-based GC. The optimal single-factor conditions determined by the experiment were BCC:CaO:NaAlO₂:SS = 18:3:2:4 (g:g:g:mL) and the liquid–solid ratio was 0.46. The compressive strength of BCC-based GC was 32.78 MPa (28 days). It was obtained that the calcination of calcified BCC below the temperature of 1000°C can effectively remove the fixed carbon in BCC but will destroy amorphous active aluminosilicate. The microstructure study showed that BCC reacted in the ternary system of Ca–Al–Si to form a variety of amorphous products (C–(A)–S–H and (N, C) –A–S–H). Along with the three-dimensional amorphous gel structure as the dominant phase, the coexistence and interlacing of various amorphous gels made the microstructure more compact and increased the compressive strength of the BCC-based GC. GCs with various amorphous phases have been successfully prepared at low temperature, and it also provided a new idea for the utilization of low-activity silicate solid wastes.     

金属离子对铜蓝和黄铁矿浮选行为的影响

通过单矿物浮选试验和浮选溶液化学计算的方法,考察了丁基铵黑药浮选体系中Cu~(2+)、Fe~(2+)、Fe~(3+)和Ca~(2+)对铜蓝和黄铁矿可浮性的影响。结果表明,四种离子对铜蓝、黄铁矿的可浮性的影响很大,均表现出不同程度的抑制作用,尤其相同浓度下Fe~(3+)的抑制作用最为显著。此外,金属离子氢氧化物沉淀是其抑制矿物的有效组分。     

Flotation and electrochemical behaviors of chalcopyrite and pyrite in the presence of N-propyl-N′-ethoxycarbonyl thiourea

The characteristics of N-propyl-N′-ethoxycarbonyl thiourea (PECTU) were studied in the flotation experiments of chalcopyrite and pyrite compared with butyl xanthate (BX). The interaction mechanism between mineral and PECTU was investigated according to zeta potential and electrochemistry measurements in the presence of PECTU. The results proved that PECTU performed a stronger ability to capture chalcopyrite and a better selectivity against pyrite. The zeta potential of chalcopyrite was positively shifted after interacting with PECTU, which indicated that the collector PECTU was obviously adsorbed on chalcopyrite surface. The cyclic voltammetry and Tafel curves results indicated that the oxidation and corrosion rates of chalcopyrite surface were limited in the presence of PECTU, while the effect of PECTU on pyrite in weak alkaline solution can be neglected basically according to the results of zeta potential and electrochemical tests.     

超声辅助H2O2-CH3COOH脱除宁东煤中硫分和灰分研究

选取宁夏宁东两种煤样ND1和ND2作为研究对象,在超声频率为40 kHz,功率为800 W下,以H2O2-CH3COOH为助剂,分别超声作用5 min,10 min,20 min,30 min,40 min,50 min,60 min和120 min。对超声作用前后的煤样进行化学法形态硫分析、FTIR、XPS、BET、XRD和IC分析。结果表明:随着超声作用时间的延长,全硫脱除率逐渐变大,超声作用60 min后再延长时间,全硫含量变化较小。当超声作用60 min时,ND1和ND2的最大全硫脱除率分别为44.05%和55.33%,硫铁矿硫的最大脱除率分别为34.62%和51.52%,硫酸盐硫的最大脱除率分别为58.33%和57.14%,有机硫的最大脱除率分别29.06%和48.04%;超声处理后样品中含氧官能团含量增加,低价态硫向高价态转化,硫可以被氧化为硫酸根而被脱除;超声处理后样品孔径和比表面积变大,改善了固液接触效果;超声能脱除煤中的矿物质,ND1和ND2中的灰分分别由24.25%和13.96%下降至7.65%和10.98%,最大脱灰率分别为68.45%和21.34%。