余热处理高强度钢筋中冷却模型的研究

本文通过研究余热处理高强度钢筋的控制冷却原理和低碳钢相变规律,建立控制冷却的数学模型。研究表明,建立的数学模型实用可靠,冷却强度可以随化学成分、终轧速度、终轧温度、自回火温度等生产条件的变化而进行逻辑分析,进而确定控冷工艺参数,生产性能合格稳定的钢筋。此外,根据生产条件的不同,冷却程序具有可移植性。     

氧化锰矿直接浸出制备硫酸锰的几个影响因素

根据云南建水锰矿一年多来的生产实践，就氧化锰矿直接浸出制备硫酸锰工业生产的几个影响因素，进行了探讨并提出了提高浸出回收率的措施。     

矿山厂--麒麟厂空白区找矿研究

通过对驰宏锌锗股份有限公司层控中低温铅锌热液矿床成矿机制的论述，论证矿山厂——麒麟厂间空白区成矿远景，指出找矿方向。     

Characterization of residual stresses from cold expansion using spatial statistics

Residual stress fields from cold expansion have been widely used to extend the fatigue life of aircraft structures. However, the spatial statistical character of these residual stress fields has not been established and has not been incorporated in current analysis methods. The objective of this study was to establish a spatial statistical method to quantify the residual stress field around a cold expanded hole. A framework called the Spatial Analysis of Residual Stress (SpARS) was developed utilizing spatial correlation, response surface modelling techniques and statistical resampling methods to characterize the residual stress field. Our results showed that tolerance bounds on residual stress can be quantified using this method. We also demonstrated the SpARS method using recently published round robin case studies. The newly developed model will be useful for aircraft structural fatigue crack growth analyses to incorporate residual stress fields for extending inspection intervals for fatigue and fracture critical structures.     

梅钢烧结配加印度果阿矿的试验研究

研究和分析了印度果阿矿在梅钢烧结现有用料结构条件下的试验情况,结合印度果阿矿的性质特征,提出果阿矿将来在梅钢应用的一些建议。通过实验室试验表明,在果阿矿配比为10％的条件下,烧结矿各项指标均较好。     

Selective Recovery of Cadmium,Cobalt, and Nickel from Spent Ni–Cd Batteries Using Adogen® 464 and Mesoporous Silica Derivatives

Spent Ni–Cd batteries are now considered an important source for many valuable metals. The recovery of cadmium, cobalt, and nickel from spent Ni–Cd Batteries has been performed in this study. The optimum leaching process was achieved using 20% H₂SO₄, solid/liquid (S/L) 1/5 at 80 °C for 6 h. The leaching efficiency of Fe, Cd, and Co was nearly 100%, whereas the leaching efficiency of Ni was 95%. The recovery of the concerned elements was attained using successive different separation techniques. Cd(II) ions were extracted by a solvent, namely, Adogen^® 464, and precipitated as CdS with 0.5% Na₂S solution at pH of 1.25 and room temperature. The extraction process corresponded to pseudo-2nd-order. The prepared PTU-MS silica was applied for adsorption of Co(II) ions from aqueous solution, while the desorption process was performed using 0.3 M H₂SO₄. Cobalt was precipitated at pH 9.0 as Co(OH)₂ using NH₄OH. The kinetic and thermodynamic parameters were also investigated. Nickel was directly precipitated at pH 8.25 using a 10% NaOH solution at ambient temperature. FTIR, SEM, and EDX confirm the structure of the products.     

无线传感器网络LEACH路由协议研究与改进

针对LEACH算法随机选取簇头,未考虑节点剩余能量及单跳与sink节点通信造成能量损耗过快的问题。引入以剩余能量及邻居节点数作为权重因子的时间等候簇头竞争模式选取簇头,并提出LEACH与蚁群算法相结合建立簇间路由机制,采用局部信息素更新,综合簇头节点的剩余能量及节点距离,为簇首与sink节点通信建立多跳路由,达到降低簇头节点能耗过快的目的。仿真实验结果表明,改进算法在降低能耗、延长网络生命周期等方面较LEACH算法有较大提高。     

焦炭还原焙烧锰矿制备硫酸锰及其机理

以非洲进口锰矿为原料,焦炭为还原剂,进行还原焙烧、硫酸浸出制备硫酸锰溶液。探究焦炭配比、焙烧温度、焙烧时间对锰还原效果的影响,确定最佳工艺参数,并对焙烧反应体系进行热力学分析及对浸出过程进行动力学分析。结果表明,最佳的焙烧条件为：焦炭配比15%、800℃焙烧60 min,锰的还原率达到97.84%。焙烧体系反应都是自发进行的,表观活化能为22.458 6 kJ/mol,且浸出过程受内扩散控制,动力学方程为：1-2x/3-(1-x)^2/3=8.48exp(-22458.6/RT)×t。     

高冰镍浸出渣还原浸出工艺研究

以湿法冶炼高冰镍过程中产生的高冰镍浸出渣为研究对象,采用二氧化硫对高冰镍渣加压还原浸出,考察了初始硫酸浓度、液固比、通气方式、浸出温度和浸出时间对高冰镍渣还原浸出过程铜、铁行为的影响;对还原浸出液采用置换沉淀和冷冻结晶的方法,对还原浸出中铜和铁进行分离回收。结果表明：在初始硫酸浓度100 g/L、液固比6 mL/g、反应时间3 h、反应温度90℃、二氧化硫分压0.15 MPa的条件下,铁和铜的浸出率分别为99.35%、77.46%,浸出液中铁几乎全部为亚铁离子;在硫酸含量20～30 g/L、温度70℃、铁粉加入量5.7 g/L、反应时间40 min的条件下,对还原浸出液进行置换沉铜,沉铜率达到了99.70%,渣含铜为67.91%。在温度—10℃、保温时间20～30 min、初始硫酸浓度100 g/L的条件下,对沉铜后液进行冷冻结晶制备硫酸亚铁,铁沉淀率达到了72.6%,七水硫酸亚铁纯度达到了92.93%。     

全数字控制无变压器式单相光伏并网逆变器

研究了一种两级式非隔离式光伏并网方案,前级采用交错并联双Boost电路,后级使用半桥逆变器。分析了无变压器式逆变器的剩余电流问题及半桥逆变器抑制剩余电流的机制。给出了Boost电感和逆变电感关键参数的设计方法。给出了数字方法实现的两级电路复合控制策略及实现方法。重点分析并提出了单定时器交错并联驱动生成策略。试验验证了控制方法的有效性和可行性。