影响热障涂层失效因素的研究现状及展望

热障涂层(TBCs)具有良好的隔热性能,是燃气轮机高温部件的关键材料,在高温服役过程中,涂层脱落会导致部件工作失效,因此为获得长寿命热障涂层,涂层的脱落失效机理是急需深入研究的问题。综述了热应力、α-Al_2O_3生长、外应力、热生长氧化层(TGO)起伏及孔隙率等缺陷对涂层应力发展的影响,探讨了微裂纹的产生、扩展及脱落的失效过程,最后展望了研究热障涂层失效及提高涂层寿命的努力方向和前景。     

EVA-g-GMA的制备及其对PLA/PHBV共混物性能的影响

通过熔融聚合法先制备了乙烯-醋酸乙烯酯接枝甲基丙烯酸缩水甘油酯(EVA-gGMA),采用红外光谱仪和核磁共振对EVA-g-GMA的结构进行了表征。然后将不同质量分数的EVA-g-GMA加入到聚乳酸/聚(3-羟基丁酸酯-co-3-羟基戊酸酯)(PLA/PHBV)共混物中,对共混物的性能进行研究。结果表明:GMA成功接枝到EVA上,随着EVA-g-GMA加入量的增加,PHBV与PLA的Tg升高,结晶度逐渐下降;分散相在PLA基体中的分散逐渐均匀,粒径减小,相界面渐渐模糊;在EVA-g-GMA加入后,共混物粘度升高,断裂伸长率和冲击强度分别可达290.9%和43.5KJ·m-2,三元共混物的水蒸气阻隔性相对于PLA/PHBV略有下降。综合考虑各种因素,EVA-g-GMA的加入使得PLA/PHBV的整体性能得到极大改善。     

燃气热循环下7YSZ热障涂层的微结构演变与阻抗谱特征

在1250℃燃气热循环条件下,测试热障涂层抗冷热冲击性能,以模拟发动机叶片的启动升温与关闭降温循环过程。采用电化学阻抗谱测试和扫描电镜(SEM)系统研究热循环过程中热生长氧化物(TGO)生长与YSZ陶瓷层微结构演变。结果表明:随着热循环次数增加,热障涂层内TGO不断生长变厚,在中频阶段的阻抗谱响应越来越显著。YSZ陶瓷层内部经历了微裂纹的萌生与扩展两个阶段。经过100次热循环后的YSZ层表现出与喷涂态涂层相似的阻抗特征,表明高温下烧结会使YSZ层产生的微裂纹在短时间内愈合。但经过300次热循环后的YSZ层表现出与喷涂态完全不同的阻抗谱,并随热循环次数增加,YSZ颗粒间隙阻抗值不断增加,表明YSZ内层产生了不可愈合的微裂纹,是导致YSZ层最终失效的主要因素。     

Mechanical and thermal properties of RE4Hf3O12 (RE=Ho,Er, Tm) ceramics with defect fluorite structure

The thermal and environmental barrier coatings (T/EBC) are technologically important for advanced propulsion engine system. In this study, RE₄Hf₃O₁₂ (RE=Ho, Er, Tm) with defect fluorite structure was investigated for potential use as top TBC layer. Dense pellets were fabricated via a hot pressing method and the mechanical and thermal properties were characterized. RE₄Hf₃O₁₂ (RE=Ho, Er, Tm) possessed a high Vickers hardness of 11 GPa. The material retained high elastic modulus at elevated temperatures up to 1773 K, which made it attractive for high temperature application. The coefficient of thermal expansion (CTE) of RE₄Hf₃O₁₂ (RE = Ho, Er, Tm) laid in the range between 7 × 10⁻⁶ K⁻¹ to 10 × 10⁻⁶ K⁻¹ from 473 K to 1673 K. In addition, the rare earth hafnates exhibited lower thermal conductivity which rendered it a good candidate material for thermal barrier applications.     

First-order indicators for the estimation of discrete fractures in porous media

Faults and geological barriers can drastically affect the flow patterns in porous media. Such fractures can be modelled as interfaces that interact with the surrounding matrix. We propose a new technique for the estimation of the location and hydrogeological properties of a small number of large fractures in a porous medium from given distributed pressure or flow data. At each iteration, the algorithm builds a short list of candidates by comparing fracture indicators. These indicators quantify at the first order the decrease of a data misfit function; they are cheap to compute. Then, the best candidate is picked up by minimization of the objective function for each candidate. Optimally driven by the fit to the data, the approach has the great advantage of not requiring remeshing, nor shape derivation. The stability of the algorithm is shown on a series of numerical examples representative of typical situations.     

冷等离子体处理对生鲜鸡胸肉杀菌效果及品质影响

目的 研究沿面介质阻挡放电(Surface Dielectric Barrier Discharge,SDBD)等离子体对生鲜鸡胸肉的杀菌作用及品质影响。方法 采用放电功率为260 W的SDBD等离子体分别处理生鲜鸡胸肉2 min和4 min,并于4 ℃贮藏12 d。每隔3 d取样,测定菌落总数、色泽、pH、汁液流失率、硫代巴比妥酸反应物(Thiobarbituric Acid Reactive Substances,TBARS)含量、挥发性盐基氮(Total Volatile Basic Nitrogen,TVB-N)含量及质构特性。结果 经SDBD等离子体处理2 min或4 min,并于4 ℃贮藏12 d后,生鲜鸡胸肉的菌落总数分别为7.16 lg(CFU/g)和6.70 lg(CFU/g),均低于对照组样品的菌落总数(7.55 lg(CFU/g))。此外,SDBD等离子体处理能够显著(P<0.05)改善冷藏期间鸡胸肉的品质参数,如pH、色泽(L^*、a^*和b^*)、汁液流失率、TVB–N含量和质构特性(硬度、弹性、咀嚼性等),但对脂质氧化具有促进作用。结论 SDBD等离子体对生鲜鸡胸肉具有良好的杀菌效果,并有效保持了其品质,在鸡胸肉保鲜上具有巨大的应用前景。     

煤介质阻挡放电脱硫的影响因素分析

依据介质阻挡放电理论,对原煤进行煤介质阻挡放电脱硫实验。实验结果表明,煤介质阻挡放电脱硫的影响因素与电极结构、介质成分和气隙距离等因素有关,如将介质放到放电间隙中间时脱硫的效果没有将介质直接放在放电极板上的脱硫效果好,加煤的情况下微放电的强度明显大于不加煤的微放电过程强度;脱硫效果呈"U"字型变化,由此推论,在一定的外界条件下,煤介质阻挡放电除硫有一个最佳的施加电压;随着电压的增加,放电脉冲的相位范围逐渐扩展。     

Cross‐talk acceptability in natural still images for different (auto)stereoscopic display technologies

Abstract— One of the most annoying distortions in (auto)stereoscopic displays is probably cross‐talk, visible as double edges, which is mainly caused by an imperfect separation of left‐ and right‐eye images. For different types of three‐dimensional (3‐D) displays, cross‐talk is caused by different origins, which could result in different levels of perceived image distortion. To evaluate the influence of (auto)stereoscopic display technology on cross‐talk perception, optical measurements and subjective assessments were performed with three different types of 3‐D displays. It is shown with natural still images that the 3‐D display technology with the lowest luminance and contrast level tolerates the highest level of cross‐talk, while still maintaining an acceptable image‐quality level.     

输出受限迟滞非线性系统的反步控制器设计

针对一类含有Bouc-Wen迟滞的输出受限非线性系统设计了反步控制器.首先分析了Bouc-Wen模型的特性并得到其上界值,然后设计了对称型障碍Lyapunov函数(barrier Lyapunov function,BLF),保证了BLF有界,从而满足了输出受限的条件,最后利用反步法设计控制器.该方法消除了迟滞引起的振荡和超调并且使得系统输出约束在设定的范围内,同时解决了迟滞和系统输出受限两个方面的影响,提高了控制精度.仿真和实验结果表明了控制方法的可行性.