Light-sensitive elastomers modified by 4-(N-dimethylmaleimido)-benzenesulphenyl chloride

New light-sensitive polymers were prepared by modification of four different elastomers with 4-(N-dimethylmaleimido)-benzenesulphenyl chloride (DMI-BSCI). Polydienes modified by DMI-BSCI form block copolymers. These polymers show a strong increase of the glass transition temperature T_g whereby the T_g increase of modified poly(octenamer) is much smaller. Higher modified polydienes have two T_g. Modified poly(octenamers) show a melting temperature dependence T_m on the content of trans double bonds which is characteristic of statistical copolymers. The ratio of rate constants with which trans- and cis-structures in poly(octenamer) are occupied by DMI-BSCI, is

$\text{k}{}_{\mathrm{trans}}\text{k}{}_{\mathrm{cis}}\text{= 0.34}$

     

PROBING HIDDEN POLYMERIC INTERFACES USINGIR-VISIBLE SUM-FREQUENCY GENERATION SPECTROSCOPY

Understanding the molecular-level processes underlying interfacial phenomena is important in the area of adhesion. We briefly introduce IR-visible sum-frequency generation spectroscopy (SFG) using a total-internal-reflection geometry for the study of polymer-air, polymer-solid, and polymer-polymer interfaces. The following examples, predominantly of work done in our lab, illustrating differences in molecular structure and dynamic properties at interfaces are presented: the air- and solid-interface structure of an amorphous polystyrene (PS) and a semicrystalline polymer with side-chain crystallinity, poly(octadecyl acrylate) (PA-18); structure of a polymer-polymer interface between thin films of a semicrystalline polymer with side-chain crystallinity, poly(vinyl-N-octadecylcarbamate- co-vinyl acetate), and an amorphous PS; thermal order-to-disorder transitions of the air and solid interface of PA-18, and the interface of this polymer with PS; and dynamic surface-relaxation studies of a rubbed PS film.     

Numerical Study on Neck Injury Under Different Postures in Vehicle Side Impact

Neck injury is a severe problem in traffic accidents. While most studies are focused on the neck injury in rear and front impacts, few are conducted in side impact. This study focuses on the difference of neck injury under different postures and the difference of 7 cervical vertebras under the same posture using the method of prescribed structure motion(PSM). The analytical results show that the maximum changes of mean force and mean moment of 7 cervical vertebras under 8 different postures are 20% and 47% respectively. The variation of each cervical vertebra is different under different neck postures. Up cervical vertebras (C1-C4) and low cervical vertebras (C5-C7) suffer different forces and moments under the same neck posture. Generally speaking, No.6 (neck right leaning 40°) is the posture with lowest neck injury risk.     

一种多元复合地基复合模量的计算方法

多元复合地基的沉降计算依赖于其复合模量的取值.目前多元复合地基复合模量计算均未考虑桩对桩间土的侧向挤密作用,因而其沉降计算结果与实际值相差较大.而考虑桩体与桩间土的侧向挤压作用,依据线弹性变形理论,推求的多元复合地基的复合模量公式应用于工程实例,结果表明,该方法是合理可行的,并且存在着参数易于确定、方法简便、机理清楚的特点.     

涤棉织物单面防水泡沫涂层工艺

通过泡沫整理法对涤棉织物进行单面防水整理,使其单面防水的同时反面具有良好的吸湿透气性能。复配了稳定型泡沫防水涂层剂,并探讨了该涂层工艺的最佳焙烘温度和时间。实验结果表明,最佳整理剂配方为防水剂与10%SDS溶液以2∶1混合,并添加CMC 10g/L,HEC 0.5g/L,PTF 5g/L,焙烘温度160℃,时间3min,效果最佳;织物带液率由传统整理的45%降至为26%,节约原料55%。     

分布视频编码中基于帧间相关性的自适应关键帧选取算法

针对分布式视频编码(DVC)系统中固定周期关键帧选取(PKFS)方法忽视了帧间相关性的缺陷,提出了一种自适应关键帧选取(AKFS)算法。利用图像特征点检测与匹配的方法,将相邻图像的非匹配点作为帧间相关性的近似,把累积或平均非匹配点数超过阈值的帧判定为关键帧。在此基础上,提出改进的帧内插方案,以适应不同长度序列组的边信息生成;将零运动强度的关联帧合并为一帧图像参与编解码,进一步提高了系统的压缩效率。实验结果表明,对于不同运动特性的序列,本文提出的算法可以明显提升边信息帧的重建质量,使系统的率失真性能提高0.9～2.0 dB,并有效降低了编码传输码率。     

永磁同步风电系统网侧变换器控制策略研究

永磁同步风电系统使用两电平电压型双PWM变换器向电网输送电能.由于变换器直流侧负载扰动引起直流母线电压波动,影响输入电网电能质量.为了减小负载扰动对直流母线电压的影响,提出一个基于相似反对称结构理论的网侧变换器控制方法.以相似反对称结构为闭环期望结构,采用逆推法设计网侧控制器.对系统在负载扰动作用下的稳定性进行分析.用Matlab进行仿真,结果表明该控制器能控制输入电网电能功率因数,提高直流母线电压的稳定性,缩短调节时间,提高系统的鲁棒性,为优化输电网的电能质量提供了依据.     

信息熵角度下的深度学习旁路安全评估框架

基于深度学习的建模类旁路密码分析（Deep Learning Side Channel Analysis/Attack,DLSCA）对于各种旁路攻击场景的密码破解效果都十分显著,但是DLSCA仍存有安全评估问题。基于AES对称加密算法的能量分析,通过信息熵角度分析准确率等传统机器学习性能指标无法评估DLSCA深度神经网络（Deep Neural Network,DNN）模型训练程度的原因。定义密钥信息量,分别阐释密钥信息量与旁路安全评估、DNN模型训练阶段性能评估的关系,建立深度学习模型与旁路分析二者的联系,提出以密钥信息量为核心的DLSCA安全评估框架。     

考虑坝基岩体抗剪强度各向异性的重力坝抗滑稳定分析方法

为研究节理岩体抗剪强度各向异性特征对重力坝抗滑稳定性的影响,利用结构面网络模拟技术,计算节理岩体在主滑动方向上沿不同角度剪切的连通率与相应的抗剪强度参数,对Mohr-Coulomb强度准则进行各向异性修正。在此基础上,结合极限分析法,提出了一种考虑岩体抗剪强度各向异性特征的重力坝抗滑稳定分析方法。将该方法应用于向家坝泄12坝段的深层抗滑稳定分析,并与传统方法的计算结果进行对比。结果表明:该方法与传统方法获得的临界滑裂面位置比较接近,但其抗滑稳定安全系数明显小于传统方法,且临界滑裂面的剪出段倾角与坝基岩体连通率的最大值方向基本一致,和实际情况相符。该方法充分考虑了岩体抗剪强度各向异性的影响,对合理评价重力坝的抗滑稳定性具有重要的工程和现实意义。     

印尼地区嵌岩灌注桩竖向承载特性现场试验

为更加深入研究不同竖向荷载作用下大直径嵌岩灌注桩的承载特性与荷载传递规律,以印尼地区某工程为依托,对3根直径为800 mm的嵌岩灌注桩进行单桩竖向抗压静载试验与桩身应力测试。试验结果表明:3根试桩的Q-s曲线均为缓变型,沉降量均不超过17 mm,回弹率较大,介于54.8%~70.9%之间,残余沉降较小,承载力较高,均满足设计要求。桩身轴力随桩顶荷载的增加逐渐增大,随深度逐渐递减;桩侧摩阻力的发挥具有异步性,随着荷载的增大,桩侧摩阻力逐渐发挥,在嵌岩段桩侧摩阻力最大,但仍未充分发挥;桩端阻力随桩顶荷载的增加近似呈线性增大,在最大荷载作用下,桩端阻力占比约55%,表现出摩擦端承桩的特性。研究结果对国内桩基规范的完善以及当地桩基规范的制订具有较重要的意义。