半导体芯片银凸点微电极生长技术

银点微电极生长技术主要用于ISS181系列高压超高速开关二极管的电极成型,是一项制约ISS181封装国产化的瓶颈技术。该项目研究采用了自主开发的流动独立供液、独立供电,整体控制工艺,用于100 mm芯片电极成型,保证银凸点微电极高度40 靘,误差?5%。做到微区银点生长有效控制,大面积一致性好。在流量8 L/min,电压6.5 V,占空比10%的条件下,得到了最佳结果。     

Conductive adhesive with transient liquid‐phase sintering technology for high‐power device applications

A highly reliable conductive adhesive obtained by transient liquid‐phase sintering (TLPS) technologies is studied for use in high‐power device packaging. TLPS involves the low‐temperature reaction of a low‐melting metal or alloy with a high‐melting metal or alloy to form a reacted metal matrix. For a TLPS material (consisting of Ag‐coated Cu, a Sn96.5‐Ag3.0‐Cu0.5 solder, and a volatile fluxing resin) used herein, the melting temperature of the metal matrix exceeds the bonding temperature. After bonding of the TLPS material, a unique melting peak of TLPS is observed at 356 °C, consistent with the transient behavior of Ag₃Sn + Cu₆Sn₅ → liquid + Cu₃Sn reported by the National Institute of Standards and Technology. The TLPS material shows superior thermal conductivity as compared with other commercially available Ag pastes under the same specimen preparation conditions. In conclusion, the TLPS material can be a promising candidate for a highly reliable conductive adhesive in power device packaging because remelting of the SAC305 solder, which is widely used in conventional power modules, is not observed.     

ZnO对BaSm_2Ti_4O_(12)陶瓷性能的影响

讨论了Zn O对Ba Sm2Ti4O12介质陶瓷烧结机制和微波介电性能的影响。结果表明:Zn O添加能推动Ba Sm2Ti4O12微波介质陶瓷的烧结,可至少将其烧结温度降低至1 280℃。当添加过多的Zn O时,Zn2+会进入晶格,可能导致晶格畸变,由此造成颗粒间产生微小孔隙及晶格内形成许多缺陷,降低了材料的εr和Q×f值。含0.5 wt%Zn O的Ba Sm2Ti4O12试样在1 280℃烧结时,综合介电性能最好:εr=76.46,Q×f=6 334 GHz。     

烧结温度对羟基磷灰石靶的影响

为研究烧结温度对羟基磷灰石靶的影响规律,把纯度为99%的羟基磷灰石粉末压制成圆盘形靶后,在氩气中分别在600℃、700℃和800℃高温下进行烧结。用X射线衍射仪和X射线光电子能谱仪对未烧结和不同温度下烧结的羟基磷灰石靶进行检测。检测结果表明：烧结温度对羟基磷灰石靶的结晶度和组成元素没有显著影响。但是随着烧结温度的升高,羟基磷灰石靶的平均粒径和钙磷比值都增大。800℃高温烧结的羟基磷灰石靶将具有更好的生物相容性、生物活性和稳定性。     

Recent Progress in Applications of the Cold Sintering Process for Ceramic–Polymer Composites

Ceramic–polymer composites are of interest for designing enhanced and unique properties. However, the processing temperature windows of sintering ceramics are much higher than that of compaction, extrusion, or sintering of polymers, and thus traditionally there has been an inability to cosinter ceramic–polymer composites in a single step with high amounts of ceramics. The cold sintering process is a low‐temperature sintering technology recently developed for ceramics and ceramic‐based composites. A wide variety of ceramic materials have now been demonstrated to be densified under the cold sintering process and therefore can be all cosintered with polymers from room temperature to 300 °C. Here, the status, understanding, and application of cold cosintering, with different examples of ceramics and polymers, are discussed. One has to note that these types of cold sintering processes are yet new, and a full understanding will only emerge after more ceramic–polymer examples emerge and different research groups build upon these early observations. The general processing, property designs, and an outlook on cold sintering composites are outlined. Ultimately, the cold sintering process could open up a new multimaterial design space and impact the field of ceramic–polymer composites.     

微波烧结钛酸锶钡陶瓷材料的介电性能

采用碳酸盐固相合成法制备Ba0.6Sr0.4TiO3(BST)粉体,应用微波烧结技术将粉体烧结成陶瓷。对样品的介电性能进行了测试,研究分析了材料的介电性能,并与传统制备工艺获得的样品进行了性能对比。结果表明:微波烧结成瓷温度和时间较传统制备工艺大大降低,分别为1 300℃和30 min,可以获得晶粒尺寸5μm以下的BST陶瓷;材料的εr变化不大,但tanδ大幅降低。     

BaTiO_3系PTCR热敏电阻器用烧结助剂的研究

研究了烧结助剂的作用，实验结果表明：如只引入半导化元素，不引入烧结助剂，则室温电阻率ρ２５很大，甚至是绝缘体。由于烧结助剂的加入，既改善了ＰＴＣＲ热敏电阻陶瓷的烧结性，又改善了其ρ２５、耐电压Ｖｂ、ＰＴＣ效应等特性，从而使产品的各种特性易于重复。烧结助剂昔日多用ＡＳＴ，现在常用ＳｉＯ２，其加入量ｘ宜小于２％。ＳｉＯ２的纯度、杂质等化学特性，与粒子形状、粒度分布、晶系等物理特性，对ＰＴＣＲ热敏电阻器的电性能有很大的影响。据此提出了ＢａＴｉＯ３系ＰＴＣＲ热敏电阻器用ＳｉＯ２的技术标准。     

ZnO压敏电阻器生产工艺的改进

压敏电阻器的生产工艺是影响产品质量的重要因素之一。通过试验，对生产工艺中，影响ＺｎＯ压敏电阻器直流老化性能的因素，如原材料细度、烧成气氛、成型密度、热处理温度和时间、掺杂等进行了研究，并据此确定了最佳工艺条件。     

对凡口矿深部开采顺序的探讨

通过对凡口矿的矿床赋存规律 ,影响深部开拓的几个技术问题和目前的生产现状等的分析 ,提出上部、深部同时开采 ,上部由上至下、深部由下至上的开采顺序 ,可使该矿今后的生产经营更加灵活。     

内蒙古新城子火山盆地遥感解译及铀成矿预测

内蒙古新城子火山盆地位于大兴安岭南端及扎兰屯火山岩型铀成矿远景带南端,盆地内中生代火山活动频繁且强烈,主要发育火山岩型铀矿。笔者利用Landsat ETM及高分一号遥感数据,对研究区进行了系统构造解译及蚀变信息提取,结合已有地质资料,初步确定了研究区以NE、NW、近EW、近NS向4组线性构造为构造格架。最终根据构造、铀矿化、遥感蚀变等信息圈定3处找矿远景区,期望为该区下一步铀矿地质找矿工作提供依据。