Study of amperometric diffusion solid-state electrolyte cell operating regimes

Different operating regimes are considered for operation of an amperometric diffusion solid-state electrolyte cell for measuring the volume fraction of oxygen. The design of an oxygen sensor is described. Experimental results confirm the efficiency of the proposed diffusion solid-state electrolyte cell for measuring oxygen in the range of 98–100%. Translated from Izmeritel’naya Tekhnika, No. 10, pp. 64–65, October, 2008.     

尖晶石相型LiM_(0.2)Mn_(1.8)O_4(M=Mg、Cd)相的晶格畸变与红外吸收峰频移

通过室温固相法制备了不同元素掺杂的前驱体,并采用分步煅烧法获得了尖晶石型LiMn2O4和LiM0.2Mn1.8O4(M=Mg、Cd)相。采用XRD和FTIR技术就元素掺杂对产物晶格畸变、Mn—O键长和键能强度等微观结构参数和光谱频移现象进行分析。结果表明,不同元素掺杂导致产物产生不同程度的晶格畸变。Mg元素掺杂使晶格收缩,Mn(Ⅳ)—O和Mn(Ⅲ)—O键收缩和键能强度增加,对应吸收峰发生蓝移;Cd元素掺杂使晶格膨胀,Mn(Ⅳ)—O和Mn(Ⅲ)—O键增长和键能强度降低,对应吸收峰发生红移。     

Enhanced π–π Interactions of Nonfullerene Acceptors by Volatilizable Solid Additives in Efficient Polymer Solar Cells

Fine‐tuning of the nanoscale morphologies of the active layers in polymer solar cells (PSCs) through various techniques plays a vital role in improving the photovoltaic performance. However, for emerging nonfullerene (NF) PSCs, the morphology optimization of the active‐layer films empirically follows the methods originally developed in fullerene‐based blends and lacks systematic studies. In this work, two solid additives with different volatilities, SA‐4 and SA‐7, are applied to investigate their influence on the morphologies and photovoltaic performances of NF‐PSCs. Although both solid additives effectively promote the molecular packing of the NF acceptors, due to the higher volatility of SA‐4, the devices processed with SA‐4 exhibit a power conversion efficiency of 13.5%, higher than that of the control devices, and the devices processed with SA‐7 exhibit poor performances. Through a series of detailed morphological analyses, it is found that the volatilization of SA‐4 after thermal annealing is beneficial for the self‐assembly packing of acceptors, while the residuals due to the incomplete volatilization of SA‐7 have a negative effect on the film morphology. The results delineate the feasibility of applying volatilizable solid additives and provide deeper insights into the working mechanism, establishing guidelines for further material design of solid additives.     

无机纳米抗菌剂及其载体

综述了无机纳米抗菌剂及其载体的最近研究进展。无机纳米抗菌剂主要包括光催化型和金属型,抗菌剂载体主要有沸石、二氧化硅、磷酸盐系、壳聚糖、脂质体和聚合物等。具体介绍了金属型和光催化型这两类无机纳米抗菌剂的抗菌机理、抗菌特性及研究现状等,并概述了当下无机纳米抗菌剂载体的主要种类和特点,同时对无机纳米抗菌剂的研究方向进行了展望...     

改性聚偏氟乙烯接枝苯乙烯/丙烯酸磺酸电解质膜及其在CO传感器中的应用

以过氧化苯甲酰(BPO)作引发剂,通过溶液接枝聚合法把苯乙烯/丙烯酸同时接枝到原硅酸钠改性的聚偏氟乙烯(PVDF)膜上,磺化后得到聚偏氟乙烯接枝苯乙烯/丙烯酸磺酸(PVDF-g-PS/ PASA)膜.FTIR分析表明:苯乙烯和丙烯酸接枝到PVDF膜上;环境的相对湿度在20%～80%范围内,对PVDF-g-PS/ PASA膜电导率的影响基本不变,并达到0.0198S·cm-1,40℃保水率达99%.将膜应用于CO传感器中,传感器电流响应信号与CO气体浓度具有较好的线性关系.     

抽出式风机在治理工作面上隅角瓦斯的应用

针对漳村煤矿综采工作面上隅角瓦斯浓度高的情况,用抽出式风机处理上隅角瓦斯,较好地解决了上隅角瓦斯频繁超限事故,实现了矿井的安全生产。     

Characteristics of Ions Emitted from Laser-Induced Silver Plasma

In this work, study of laser-induced ions is presented. The plasma was produced by focusing a Nd：YAG laser, with a wavelength of 1064 nm, a pulsed width of 9-14 ns, a power of 1.1 MW and energy of 10 mJ, on silver target in vacuum （10-3 Torr= 1.3332 Pa）. The characteristics of ion streams were investigated by CR-39 detectors located at angles of 0°, 30°, 60° and 90° with respect to normal of the target. The distance between the silver target and each detector was 11 cm. The energy of silver ions was found ranging from 1.5 eV to 1.06E4 eV. There was a high concentration of ions with low energy as compared to those with high energy, showing the energy distribution amongst the ions. The flux of ions was maximum in the axial direction which was decreasing with the angle increase with respect to normal of the target, and finally became minimum in the radial direction. Hence the silver ions have shown anisotropic behaviour.     

PVC低发泡实心板挤出成型技术要点

在PVC低发泡实心板挤出成型中,控制聚合物熔体的流动和发泡是保证产品质量的关键,重点介绍了生产工艺和原理,并分析了生产中的技术要点,提出了解决的办法。     

Al4B2O9纳米棒改性制备优异综合性能的固体聚合物电解质

随着储能设备和电力驱动产品的激增,特别是电动汽车的大规模推广应用,全固态电池被认为是最有可能解决电动设备日益严峻的安全问题和高能量密度需求的策略之一.本文报道了一种Al4B2O9纳米棒改性的聚环氧乙烷(PEO)基固体聚合物电解质(ASPE),其具有高离子电导率、宽电化学窗口、良好的机械性能和阻燃性能.具体来说,因为Al...     

Tumor-Localized Administration of α-GalCer to Recruit Invariant Natural Killer T Cells and Enhance Their Antitumor Activity against Solid Tumors

Invariant natural killer T (iNKT) cells have the capacity to mount potent anti-tumor reactivity and have therefore become a focus in the development of cell-based immunotherapy. iNKT cells attack tumor cells using multiple mechanisms with a high efficacy; however, their clinical application has been limited because of their low numbers in cancer patients and difficulties in infiltrating solid tumors. In this study, we aimed to overcome these critical limitations by using α-GalCer, a synthetic glycolipid ligand specifically activating iNKT cells, to recruit iNKT to solid tumors. By adoptively transferring human iNKT cells into tumor-bearing humanized NSG mice and administering a single dose of tumor-localized α-GalCer, we demonstrated the rapid recruitment of human iNKT cells into solid tumors in as little as one day and a significantly enhanced tumor killing ability. Using firefly luciferase-labeled iNKT cells, we monitored the tissue biodistribution and pharmacokinetics/pharmacodynamics (PK/PD) of human iNKT cells in tumor-bearing NSG mice. Collectively, these preclinical studies demonstrate the promise of an αGC-driven iNKT cell-based immunotherapy to target solid tumors with higher efficacy and precision.