对HIC试验中两种不同腐蚀介质酸碱度的探讨

HIC是腐蚀试验中常用的检测方法,用来测评材料在含硫化氢环境中对氢离子敏感性大小.其包含两种不同的腐蚀介质,不同的腐蚀介质中酸碱度是不一样的,腐蚀介质的酸碱度对试验结果有较大的影响,为此,运用电离平衡理论,计算并分析两种不同腐蚀介质电离平衡前后的氢离子浓度变化,得出动态反应平衡时氢离子浓度的关系式,从而获得介质中精确的氢离子浓度,并对腐蚀介质中相关离子进行了探讨,为进一步探究相关环境中的腐蚀机理提供了依据.     

聚合物驱流线数值试井解释模型及其应用

针对生产和关井两个阶段分别建立了考虑复杂因素影响的聚合物驱流线数值试井解释模型，两个阶段均考虑了油藏非均质性、聚合物驱、油水两相流、多井等因素的影响。该流线试井解释模型采用最新的流线方法进行一维求解，具有更高的求解速度和稳定性，同时它比现有模型更加接近于油藏真实环境，具有更高的现场实用性。     

Paste Residence Time in a Spouted Bed Dryer. II: Effect of Spout Operational Conditions

Residence time distributions for an aqueous solution of 10% sodium chloride in a spouted bed dryer of inert particles were determined using the stimulus-response technique. Glass and polyethylene beads with diameters 2.6 and 3.4 mm were used as inert bodies in a cylindrical column of 14.0 cm diameter and 60° conical base. The effects of inert bodies load, air, and paste flow rates on the mean residence times and RTD were determined following 2³ factorial designs. The RTD could be correlated to the perfect mixing cell model with R² varying from 0.8684 to 0.9815. The mean residence times in CSBD varied from 10.8 to 13.9 and 10.7 to 13.3 min for glass and polyethylene beads, respectively. For both inert particles, mean residence times increased with bed height and decreased with paste feed rates. Also, terms of interaction among the factors were significant in some cases, showing a complex behavior of paste residence times. Equations obtained by response surface regression could predict mean residence times on glass and polyethylene beads with deviations lower than ±10%.     

蒸发式空冷器的运行实践

通过了解蒸发式空冷器的工作原理和结构,在运行实践过程中,对组成设备出现的问题提出相应的解决方案,并对部分组成设备提出改进的建议,以方便检修和维护,并提出了在冬季长时间高炉休风情况下保证水温不下降过低的解决方案。     

考虑表皮的射孔水平井产能评价

射孔水平井中地层流体的流动是符合达西定律的,但水平井射孔工艺、完井方式以及井位等因素的影响,比垂直井复杂。本文将射孔后的流动看成线源,根据Newman乘积原理,用Green函数的方法得到井底压力解析解。在此基础上,将射孔时的地层压实和井壁污染用表皮来表示,并考虑井筒存储,得Laplace空间上的表达,最后用Laplace数值反演得到时空间上的解,利用该解可以有效预测水平井的产能。     

Polyethylene mixed crystal infra-red spectroscopy: The influence of matrix isotopic species on guest conformation

The chain conformation of solution-crystallized polyethylene has previously been confirmed by infra-red spectroscopy, using the CD₂ bending bandshape for samples with a minority of the deuterated species^1–3. The method of calculating the i.r. band profile from molecular conformational models is now developed to give a more accurate representation of doublet splittings and to include the singlet component. The CH₂ bending profile is calculated for samples with a deuterated matrix, and the good agreement with experimental data indicates that the same molecular model is applicable for samples with the deuterated polymer as either guest or matrix, for identical crystallization conditions. This result implies that isotopic fractionation is unimportant under these conditions.     

溶聚丁苯橡胶聚合溶液粘度的研究

研究了（乙二醇二甲醚、二乙二醇二甲醚）－正丁基锂－抽余油体系地溶聚乙苯橡胶不同聚合时间聚合溶液粘度的变化，发现聚合溶粘度与活性种的活性有关，高温严重破坏活性种的活性，计节剂量是杀死活性种活性的另一因素。同时考察了不同苯乙烯／丁二烯（S／B）体系，正丁基锂引发剂用量对聚合粘影响规律，发现S／B越大，聚合粘度越小，S／B越小，聚合粘度越大，引发剂用量减少，聚合液粘度增大。     

EMD与KOH溶液的相互影响

利用滴定分析、热失重分析以及XRD方法研究了EMD和KOH溶液混合后的变化。结果表明:碱与MnO2可以相互作用并导致体系温度的升高,碱浓度的下降,EMD中形成Mn3O4以及MnO2中结合水的损失。相互作用的结果与所加KOH溶液的浓度、EMD中的水含量、二者用量的比例关系以及体系的温度有关。     

Transient Green’s Tensor for a Layered Solid Half-Space With Different Interface Conditions

Pulsed ultrasonic techniques can be and have been used to examine the interface conditions of a bonded structure. To provide a theoretical basis for such testing techniques we model the structure as a layer on top of a half-space, both of different elastic properties, with various interface bonding conditions. The exact dynamic Green’s tensor for such a structure is explicitly derived from the three-dimensional equations of motion. The final solution is a series. Each term of the series corresponds to a successive arrival of a “generalized ray” and each is a definite line integral along a fixed path which can be easily computed numerically. Willis’ method is used in the derivation. A new scheme of automatic generation of the arrivals and ray paths using combinatorial analysis, along with the summation of the corresponding products of reflection coefficients is presented. A FORTRAN code is developed for computation of the Green’s tensor when both the source and the detector are located on the top surface. The Green’s tensor is then used to simulate displacements due to pulsed ultrasonic point sources of known time waveform. Results show that the interface bonding conditions have a great influence on the transient displacements. For example, when the interface bonding conditions vary, some of the first few head waves and regular reflected rays change polarities and amplitudes. This phenomenon can be used to infer the quality of the interface bond of materials in ultrasonic nondestructive evaluation. In addition the results are useful in the study of acoustic microscopy probes, coatings, and geo-exploration.     

带有集中质量的分布质量弹性转动横振精确解

求得了带有集中质量的分布质量弹性转轴系统横向自由振动的频率方程和振型函数的精确解析表达式，及其与不转动轴系统自由振动的频率方程和振型函数及转动角速度之间的精确解析关系